Refractive Flow and Treatment Systems: Conceptual, Analytical, and Numerical Modeling

Refractive flow and treatment (RFT) systems are designed for passive or low-maintenance in situ ground water remediation for rock or soil of low to moderate permeability. An RFT system captures and refracts contaminated ground water and conveys it to an in situ permeable treatment zone without the need for pumping. Flow to the treatment zone is through one or more high-permeability collection cells, and flow from the treatment zone back into the adjacent native media is through one or more high-permeability dispersal cells.
Conceptual, analytical, and numerical modeling demonstrates the potential for RFT systems to be successful. Analytical modeling shows that the most important factor for this success is that RFT system components be engineered to have comparatively high hydraulic conductivities. A numerical model, capable of representing site-specific conditions, is required for actual RFT system design.     

East Asian winter monsoon: results from eight AMIP models

 This study evaluates simulations of the East Asian winter monsoon in eight GCMs that participated in the Atmospheric Model Intercomparison Project (AMIP). In addition to validating the mean state of the winter monsoon, the cold surge and its transient properties, which includes the frequency, intensity, preferred propagation tracks, and the evolution patterns of the surges, are examined. GCM simulated temporal distribution of the Siberian high and cold surges is also discussed. Finally, the forcing of the cold surges on the tropical surface wind and convection, along with their interannual variation is analyzed. The mean state of the winter monsoon is generally portrayed well in most of the models. These include the climatological position of the Siberian high, the 200 hPa divergent center, and the large-scale wind patterns at the surface and the 200 hPa. Models display a wide range of skill in simulating the cold surge and its transient properties. In some of the models, the simulated cold surge trajectory, intensity, frequency, propagation patterns and source regions are in general agreement with those from the observed. While in others, the models cannot adequately capture these observed characteristics. The temporal distribution of the Siberian high and cold surges were realistically reproduced in most GCMs. Most models were able to simulate the effect of the cold surges on the tropical surface wind, although a few models unrealistically generated subtropical southerly wind in the mid-winter. The relationship between cold surges and the tropical convection was not satisfactorily simulated in most models. The common discrepancies in the winter monsoon simulation can be attributed to many factors. In some models, the reason is directly related to the improper location of the large-scale convective center near the western Pacific. The satisfactory simulations of the monsoon circulation and the cold surges are partly due to the topographical characteristics of the East Asian continent, i.e., the Tibetan Plateau to the west and the oceans to the east. The correct simulation of the interannual variation of the surface wind near the South China Sea (SCS) and the maritime continent is a demanding task for most of the models. This will require adequate simulations of many aspects, including tropical convection, the Siberian cold dome, the extratropical-tropical linkage, and the air-sea interaction. The discrepancies noted here furnish a guide for the continuing improvement of the winter monsoon simulations. Improved simulations will lead to an adequate delineation of the surface wind and convection near the maritime continent, which is essential for portraying the winter monsoon forcing in a coupled model. Received: 10 March 1997/Accepted: 4 June 1997     

A simple closure mechanism for a compact,large-diameter,gravity corer

A simple and reliable corer closure mechanism is described, which has three principal advantages over published designs for similar automatic gravity corers. First, it allows the use of large diameter tubes (at least 80 mm internal diameter), reducing core shortening effects. Second, it allows free passage of water during descent minimising bow wave effects. Third, it is compact enough for convenient use through seasonal ice cover.     

Dissolved vanadium in rivers and estuaries

New measurements of dissolved vanadium in a variety of rivers and estuaries are presented here. The data indicate that the average concentration of dissolved vanadium in major rivers entering the ocean is 15 nmol/kg. Weathering rate and type of source rock, rather than solution chemistry or anthropogenic influences, appear to be the important factors in determining fluvial dissolved vanadium concentrations. Laboratory experiments suggest that in oxic waters vanadium is found predominantly in its most oxidized, anionic form (V(V)). Complexation with organic matter and formation of large colloidal species appear to be unimportant. Adsorption also appears to be a less important influence for vanadium than for some other trace elements such as zinc.In estuaries, vanadium behaves as a bioactive element, showing a close correspondence with the distribution of phosphate. The extent of estuarine vanadium removal is presently uncertain but may be low due to rapid remineralization of this element. Based on the river flux, the oceanic residence time for dissolved vanadium is estimated to be 100,000 years.     

The geochemistry of antimony and its use as an indicator element in geochemical prospecting

The geochemistry of antimony is reviewed, and the use of the element as an indicator in geochemical prospecting for various types of mineral deposits is outlined.Antimony is widely diffused in many types of mineral deposits, particularly those containing sulphides and sulphosalts. In these and other deposits, antimony commonly accompanies Cu, Ag, Au, Zn, Cd, Hg, Ba, U, Sn, Pb, P, As, Bi, S, Se, Te, Nb, Ta, Mo, W, Fe, Ni, Co, and Pt metals. Under most conditions antimony is a suitable indicator of deposits of these elements, being particularly useful in geochemical surveys utilizing primary halos in rocks, and secondary halos and trains in soils and glacial materials, stream and lake sediments, natural waters, and to a limited degree vegetation. Some of the natural antimony compounds (e.g. stibine, dimethylstibine) are volatile, but methods utilizing gaseous antimony halos for geochemical prospecting have not yet been developed.     

Migration‐as‐development repackaged? The globalizing imperative of the Singaporean state's diaspora strategies

Diaspora strategizing is becoming an important field of public policy in countries that seek to advance development through migration. Diaspora strategies present a way of complicating interpretations of development, as countries that represent different levels of development seek to mobilize diaspora networks nonetheless. While Singapore's diaspora strategies prioritize diaspora knowledge networks, it bears the stamp of the country's colonial history, postcolonial priorities and developmental state apparatus. We suggest that these factors result in a distinctive diaspora strategy characterized by a centralized and technocratic approach more similar to diaspora strategies found in emerging economies. Earlier research on diaspora strategies has been concerned with assessing successes or failures, but a more critical scholarship that questions the logics and outcomes of diaspora strategizing is emerging. We bring the Singaporean case into dialogue with four such critiques: first, the intellectual foundations of diaspora‐centred development; second, the hyperextension of state infrastructure for emigration and stakeholder alignment; third, the selective mobilization of the idea of diaspora; and fourth, the evidence base upon which diaspora‐centred development is predicated. Our goal is to further critical interrogation into the logics, efficacy and sustainability of diaspora strategizing. We situate our analyses in the international literature on diaspora knowledge mobilization.