The 18.6 yr nodal modulation in the tides of Southern European coasts

The nodal modulation of the diurnal (K₁ and O₁) and semi-diurnal (M₂ and K₂) tidal constituents at the coasts of the Mediterranean Sea and the eastern Atlantic is estimated and its spatial variability mapped. Fourteen hourly tide gauge records each spanning more than 18 years are considered in this analysis. Ten tide gauges are located in the Mediterranean Sea and four in the Bay of Biscay. The nodal modulation of the most energetic tidal constituent (M₂) reaches up to 5 cm at the eastern Atlantic coasts, while within the Mediterranean Sea its modulation is in general less than 1.1 cm. The largest K₂ nodal modulation found is 3.7 cm in the eastern Atlantic coasts. In the Mediterranean Sea, smaller modulation amplitudes, ranging between 0.4 and 1.4 cm are found. The K₁ tide constituent has the largest amplitude nodal modulation within the Mediterranean Sea of 1.9 cm in the north Adriatic Sea, which is also larger than the modulation of this constituent at the eastern Atlantic coasts. The O₁ tide constituent has the highest amplitude nodal modulation (1.4 cm) at the eastern Atlantic coasts. In the Mediterranean Sea the maximum value is 1 cm in the north Adriatic Sea.     

Evaluation of a Movie Theater Advertisement Campaign to Promote Behaviors that Prevent Spread of Aquatic Invasive Species

One of the primary causes of the spread of aquatic invasive species (AIS) is boaters and anglers who move between bodies of water. Engaging with recreational boaters and anglers to encourage preventative behaviors is crucial for managing the spread of AIS. The use of cinema advertising for disseminating pro-environmental messages is a relatively novel and understudied outreach strategy. To explore this approach, an AIS-related public service announcement was placed in the preshow advertising at a movie theater in north central Wisconsin. Movie patrons were surveyed as they left the theater to determine demographic, AIS awareness, advertising exposure, and recall information. The results of this study suggest movie theater advertising is a potentially efficacious medium for pro-environmental outreach efforts.     

Deep pooling of low degree melts and volatile fluxes at the 85°E segment of the Gakkel Ridge: Evidence from olivine-hosted melt inclusions and glasses

We present new analyses of volatile, major, and trace elements for a suite of glasses and melt inclusions from the 85°E segment of the ultra-slow spreading Gakkel Ridge. Samples from this segment include limu o pele and glass shards, proposed to result from CO₂-driven explosive activity. The major element and volatile compositions of the melt inclusions are more variable and consistently more primitive than the glass data. CO₂ contents in the melt inclusions extend to higher values (167–1596 ppm) than in the co-existing glasses (187–227 ppm), indicating that the melt inclusions were trapped at greater depths. These melt inclusions record the highest CO₂ melt concentrations observed for a ridge environment. Based on a vapor saturation model, we estimate that the melt inclusions were trapped between seafloor depths (～ 4 km) and ～ 9 km below the seafloor. However, the glasses are all in equilibrium with their eruption depths, which is inconsistent with the rapid magma ascent rates expected for explosive activity. Melting conditions inferred from thermobarometry suggest relatively deep (25–40 km) and cold (1240°–1325 °C) melting conditions, consistent with a thermal structure calculated for the Gakkel Ridge. The water contents and trace element compositions of the melt inclusions and glasses are remarkably homogeneous; this is an unexpected result for ultra-slow spreading ridges, where magma mixing is generally thought to be less efficient based on the assumption that steady-state crustal magma chambers are absent in these environments. All melts can be described by a single liquid line of descent originating from a pooled melt composition that is consistent with the aggregate melt calculated from a geodynamic model for the Gakkel Ridge. These data suggest a model in which deep, low degree melts are efficiently pooled in the upper mantle (9–20 km depth), after which crystallization commences and continues during ascent and eruption. Based on our melting model and the assumption that CO₂ is perfectly incompatible, we show that the highest CO₂ concentrations of the melt inclusions (～ 1600 ppm) are consistent with the calculated CO₂ concentrations of primary undegassed melts. The highest measured CO₂/Nb ratio (443) of Gakkel Ridge melt inclusions predicts a mantle CO₂ content of 134 ppm and would result in a global ridge flux of 2.0 × 10¹² mol CO₂/yr.     

Measurement of advective soil gas flux: results of field and laboratory experiments with CO2

A multi-channel, steady-state flow-through (SSFT), soil-CO₂ flux monitoring system was modified to include a larger-diameter vent tube and an array of inexpensive pyroelectric non-dispersive infrared detectors for full-range (0–100 %) coverage of CO₂ concentrations without dilution. Field testing of this system was then conducted from late July to mid-September 2010 at the Zero Emissions Research and Technology project site located in Bozeman, Montana, USA. Subsequently, laboratory testing was conducted at the Pacific Northwest National Laboratory in Richland, WA, USA using a flux bucket filled with dry sand. In the field, an array of 25 SSFT and 3 non-steady-state (NSS) flux chambers was installed in a 10 × 4 m area, the long boundary of which was directly above a shallow (2-m depth) horizontal injection well located 0.5 m below the water table. Two additional chambers (one SSFT and one NSS) were installed 10 m from the well for background measurements. Volumetric soil moisture sensors were installed at each SSFT chamber to measure mean moisture levels in the top 0.15 m of soil. A total flux of 52 kg CO₂ day^?1 was injected into the well for 27 days and the efflux from the soil was monitored by the chambers before, during, and for 27 days after the injection. Overall, the results were consistent with those from previous years, showing a radial efflux pattern centered on a known “hot spot”, rapid responses to changes in injection rate and wind power, evidence for movement of the CO₂ plume during the injection, and nominal flux levels from the SSFT chambers that were up to sevenfold higher than those measured by adjacent NSS chambers. Soil moisture levels varied during the experiment from moderate to near saturation with the highest levels occurring consistently at the hot spot. The effects of wind on measured flux were complex and decreased as soil moisture content increased. In the laboratory, flux-bucket testing with the SSFT chamber showed large measured-flux enhancement due to the Venturi effect on the chamber vent, but an overall decrease in measured flux when wind also reached the sand surface. Flux-bucket tests at a high flux (comparable to that at the hot spot) also showed that the measured flux levels increase linearly with the chamber-flushing rate until the actual level is reached. At the SSFT chamber-flushing rate used in the field experiment, the measured flux in the laboratory was only about a third of the actual flux. The ratio of measured to actual flux increased logarithmically as flux decreased, and reached parity at low levels typical of diffusive-flux systems. Taken together, the results suggest that values for advective CO₂ flux measured by SSFT and NSS chamber systems are likely to be significantly lower than the actual values due to back pressure developed in the chamber that diverts flux from entering the chamber. Chamber designs that counteract the back pressure and also avoid large Venturi effects associated with vent tubes, such as the SSFT with a narrow vent tube operated at a high chamber-flushing rate, are likely to yield flux measurements closer to the true values.     

METEOROLOGICAL ANALYSIS OF DAILY MAXIMUM GROUND-LEVEL OZONE FOR THE NIAGARA REGION

Ground-level ozone has become a problem of major concern in urban airsheds in Canada, owing to its adverse effects on humans and crops. As a secondary pollutant, its formation is dependent on the presence of certain precursor gases in conjunction with appropriate meteorological conditions. Several studies have examined the relationship between maximum concentrations and key meteorological variables at the regional scale during episodic conditions. This study sought to understand this relationship at the local scale using surface and upper-air meteorological data for the Niagara Region. In the methodological approach, factor analysis and linear regression methods were used to determine the best combination of variables that would explain the highest percentage of variance in daily maximum ground-level ozone associated with different event categories. Each event category had a combination of unique meteorological characteristics. Factor analysis yielded seven factors that together constituted 20 of the original 59 variables in the data set. In the application of a series of regression analyses, the thermal factors of the lower atmosphere emerged as the most important variables, followed by variables related to persistence and advection characteristics. The daily maximum temperature was the single most important variable and accounted for the largest percentage of the variance explained, whereas the persistence factor was of secondary importance. The overall results suggest that a small number of surface variables based on the local meteorology of the Niagara Region can be used to estimate daily maximum ground-level ozone.     

Times for (Un)sustainability? Challenges and opportunities for developing behaviour change policy. A case-study of consumers at home and away

This paper examines the assertion that individuals with seemingly high levels of commitment to the environment at home may also be those engaged in less sustainable leisure and tourism behaviours, including a high dependency on air travel. This potential difference in environmental commitments between different consumption settings is placed within the context of recent policy developments that have seen the rise of segmentation as a commonly applied technique used to understand and encourage pro-environmental behaviours through the notion of ‘sustainable lifestyles’ and social marketing campaigns. Using data derived from a questionnaire of consumers in the UK, three distinctive, empirically-defined ‘lifestyle’ groups are identified, based on the respondents’ environmental behaviours. Significant differences emerged in reported environmental commitments according to their consumption setting. Those with higher levels of commitment in and around the home also tended to be those who flew furthest and most frequently, whilst those with moderate-to-high commitments ‘at home’ often failed to transfer these activities to their holiday environments. The paper concludes by arguing that both academics and policy-makers need to address the role of different consumption settings in which behaviours are undertaken and the ways in which these relate to underlying social practices within these settings.     

Boundary-layer flow structures associated with particle reentrainment

Measurements of near-surface longitudinal and vertical wind velocity components associated with particle reentrainment from a flat surface have been examined in a wind tunnel. Sparsely covered particle beds were used to assure that observed reentrainment events resulted primarily from the action of fluid forces. Characteristic velocity patterns were found to be associated with a majority of particle reentrainment events examined. These characteristics have been categorized and examined as ensemble averages. The flow pattern most frequently observed during particle reentrainment was termed Ejection-Sweep (E-S) and is very similar to organized fluid motions previously observed in laboratory flows and in the atmospheric boundary layer. A simple two-tiered E-S pattern recognition scheme is described which strives to identify particle reentrainment events objectively based on flow characteristics alone. The first step is to identify potential E-S patterns using criteria which identify a characteristic longitudinal acceleration, and the second step is to use threshold values of pattern characteristics to accept or reject these first-tier patterns. Pattern recognition results are presented in terms of the ability to identify reentrainment events versus false identifications, and show an exponential growth in false identifications with an increasing number of reentrainment events identified.     

Retrieval of turbulent pressure fluctuations at the ground surface beneath a forest

The relationship between surface pressure fluctuations and the velocity field associated with turbulent coherent structures is examined for flow within and above a deciduous forest. Measurements were taken with tower-mounted sonic anemometer/thermometers at six heights, Lyman-alpha humidiometers at three heights, and a pressure sensor at the forest floor. We find a strong, near-linear relationship between the mean square turbulent velocity and the standard deviation of the high-pass-filtered pressure fluctuations. Lagged cross-correlations between vertical velocity fluctuations and those of pressure show maximum correlations of ± 0.5 but with a phase offset. Examination of surface pressure during the passage of coherent structures, which are characterized by a transition from ejection to sweep, reveals a period of overpressure about 20 s in duration roughly centered on the time of passage of the scalar microfront at the top of the canopy. Pressure patterns associated with coherent structures appear to be largely responsible for the form of the correlations stated above.Pressure patterns calculated from an integrated Poisson equation, using observed velocity and temperature signals during coherent structures, match the main features of the observed pressure. Retrieval of the pressure fluctuations in this manner reveals that the mean wind shear/turbulence interaction term is dominant, but that important contributions arise from two other terms in the equation. Buoyancy effects are negligible. We show that the surface pressure signal is mainly created by the velocity field near the top of the forest, and present evidence to suggest that features of the sub-crown air movement result directly from this pressure field.     

Surface aerosol measurements at Barrow during AGASP-II

Measurements at Barrow during the second Arctic Gas and Aerosol Sampling Program (AGASP-II), conducted in April 1986, showed no rapid long-range transport from lower-latitude source regions to Barrow, and only limited vertical transport from above the boundary layer to the surface. New aerosol size distribution measurements in the 0.005–0.1 m diameter size range using a Nuclepore-filter diffusion battery apparatus showed a median diameter of about 0.01 m during times of high condensation nucleus (CN) concentrations. Aerosol black carbon concentrations exceeding 400 ng m^–3 were detected at the surface and were more strongly correlated with CN concentrations than with aerosol scattering extinction (_sp), suggesting that aerosol carbon was generally associated with small particles rather than large particles. Measurements at Barrow during AGASP-I, conducted in March–April 1983, showed a series of aerosol events detected at the ground that were caused by rapid long-range transport paths to the vicinity of Barrow from Eurasia. These events were strongly correlated with aerosol loading in the vertical column (optical depth).