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341.
This case study considers the early development and recent changes that have occurred in the vicinity of Joo Chiat Road, Singapore, which can be described as a ‘linear activity corridor’ linking the districts of Geylang, Katong and Marine Parade, immediately east of Singapore’s urban core. Singapore’s Urban Redevelopment Authority (URA) has declared Joo Chiat to be a ‘Conservation Area’, reflecting local-born Peranakan and Eurasian cultures, with similar status to other more central historic sites such as Chinatown, Kampong Glam, Little India and Emerald Hill. But the story of Joo Chiat has evolved along a somewhat different trajectory from the more prominent, tourism-related, heritage areas, with a multiplicity of interactions operating at the margins of the planning process. This has led to the spatial infusion of potentially discordant, globally related, ‘entertainment and recreational’ activities into an area of established urban identity and multiple attachments. When a policy of police containment was found to be inadequate in protecting local residents from undesirable impacts, changes were eventually brought about through a combination of neighbourhood activism and local political initiative. Through detailed land use inspections, press reports and strategic interviews, backed up by secondary sources, the study highlights the impingement of marginalised, potentially disruptive ‘global’ elements into a local heritage conservation area, and the importance of strong neighbourhood identity and community involvement as active components in the process of conflict resolution.  相似文献   
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We report new stepped heating He, Ar, CO2 and water data on a petrogenetically diverse suite of lavas from the Manus back-arc basin, where a plume component has previously been identified. The aim of this study is to evaluate the superimposed effects of degassing and contamination in order to identify mantle source characteristics. CO2 abundances and carbon isotopes in both the vesicle ([CO2] up to 180ppm; δ13C as low as -33.6 ‰) and glass ([CO2] up to 270ppm; δ13C as low as -34.3 ‰) phases reveal that samples have been modified by varying degrees of degassing. High water concentration samples (back-arc basin basalts (BABB) and arc type samples) show the highest degrees of degassing (i.e. lower δ13C values and lower CO2 contents). The results are modelled for both the glass and vesicle phases using batch and fractional degassing models. Parental melt compositions can be constrained to show the following CO2 concentration trend: arc-type > BABB s.r. (southern rift) > MORB-2, E-MORB, X-BABB (extreme BABB), BABB > MORB-1 and MORB-smt. 4He/40Ar∗ ratios of samples (14.6-1100) are consistent with residual volatiles from a degassed source. Variations in CO2/3He values are likely due to degassing, followed by contamination from a crustal source (either the subducting Solomon Sea Plate or the pre-existing crust through which the lavas erupt), as evidenced by high K2O/TiO2 ratios and low δ13C. The CO2/3He of the Manus plume is best estimated by the MORB-smt and MORB-1 samples at 3.1 ± 0.6 x 109. This value is similar to previous estimates of plume CO2/3He values, which are either equal to or slightly greater than the upper mantle average of 2 x 109.  相似文献   
344.
Analyses of 31 minerals (biotite, potash feldspar and plagioclase), occurring in 12 acidic volcanic rocks and 5 granodiorites from a Tuscan igneous series, gave the following mineral-groundmass (l) partition coefficients (D-values) for Tl: DKf-l, 0.75; Dbio-l, 1.82; Dpl-l, 0.13.Values for Rb (previously published) are similar for DKf-l but smaller for Dbio-l. Model calculations for crystallizing acid magma, using obtained D-values, confirm the observed trends of increased abundances of Tl, Rb in residual liquids and indicate and expected increase in Rb/Tl.In acid plutonic rocks, most of the Tl is in biotite; in equivalent lavas it is in the groundmass.  相似文献   
345.
Chemical studies of various modern and fossil spore walls of gymnosperms, angiosperms, pteridosperms, fungi and algae show the majority to contain sporopollenin now known to be derived from carotenoid esters by an oxidative polymerisation process. Chemical studies on microfossil walls and associated insoluble organic matter (kerogen) present in sediments up to 3,400 to 3,700 m.y. old suggest that these may have a common identity with sporopollenin of modern spore exines.  相似文献   
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We present trace element and Sr–Nd–Hf–Pb isotopecompositions for clinopyroxenes from anhydrous spinel peridotiteand garnet ± spinel pyroxenite xenoliths of Pan-Africanlithospheric mantle from Jordan, including the first high-precisiondouble-spike Pb isotope measurements of mantle clinopyroxene.Clinopyroxenes from the peridotites are variably Th–U–LILE–LREEenriched and display prominent negative Nb, Zr and Ti anomalies.MREE–HREE abundances can generally be modelled as partialmelting residues of spinel lherzolite with primitive-mantle-likecomposition after extraction of 5–10% melt, whereas theenrichments in Th–U–LILE–LREE require a Pan-Africanor later metasomatic event. The large range of Nd, Sr, Pb andHf isotope ratios in both peridotites and pyroxenites (e.g.Nd 1·4–17·5; 206Pb/204Pb 17·2–20·4;Hf 0·6–164·6) encompasses compositionsmore radiogenic than mid-ocean ridge basalt (MORB), and Pb isotopescover almost the entire range of oceanic basalt values. Hf valuesare some of the highest ever recorded in mantle samples andare decoupled from Nd in the same samples. Marked correlationsbetween Sr–Nd–Pb isotopes, LILE–LREE enrichmentsand HFSE depletion suggest that the metasomatizing agent wasa carbonatitic-rich melt and isotopic data suggest that metasomatismmay have been related to Pan-African subduction. The metasomaticmelt permeated depleted upper mantle (<16 kbar) during Pan-Africansubduction at 600–900 Ma, and the variably metasomatizedmaterial was then incorporated into the Arabian lithosphericmantle. There is no evidence for recent metasomatism (<30Ma) related to the Afar plume like that postulated to have affectedsouthern Arabian lithospheric mantle. Hf isotopes in the mantleclinopyroxenes are unaffected by metasomatism, and even somestrongly overprinted lithologies record ancient (>1·2Ga) pre-metasomatic Lu–Hf signatures of the depleted uppermantle that was the protolith of the Arabian lithospheric mantle.The ‘resistance’ of the Lu–Hf isotopic systemto later metasomatic events resulted in the development of extremelyheterogeneous Hf isotopic signatures over time that are decoupledfrom other isotopic systems. No mantle sample in this studyexactly matches the chemical and isotopic signature of the sourceof Jordanian intraplate basalts. However, the xenolith compositionsare broadly similar to those of the source of Arabian intraplatebasalts, suggesting that the numerous Cenozoic intraplate volcanicfields throughout Arabia may be the product of melting uppermantle wedge material fertilized during Pan-African subductionand incorporated into the Arabian lithospheric mantle. We proposea model whereby the proto-Arabian lithospheric mantle underwenta major melting event in early Proterozoic–late Archeantimes (at the earliest at 1·2 Ga). Island-arc volcanismand major crust formation occurred during the Pan-African orogeny,which liberated fluids and possibly small-degree melts thatmigrated through the mantle creating zones of enrichment forcertain elements depending upon their compatibility. Immobileelements, such as Nb, were concentrated near the base of themantle wedge providing the source of the Nb-rich Jordanian volcanicrocks. More mobile elements, such as LILE and LREE, were transportedup through the mantle and fertilized the shallow mantle sourceof the Jordanian xenoliths. Following subduction, the mantlewedge became fossilized and preserved distinct enriched anddepleted zones. Lithospheric rifting in the Miocene triggeredpartial melting of spinel-facies mantle in the lower lithosphere,which mixed with deeper asthenospheric garnet-facies melts asrifting evolved. These melts entrained segments of variablycarbonatite-metasomatized shallow lithospheric mantle en routeto the surface. KEY WORDS: Arabian lithospheric mantle; Jordan; mantle xenoliths; Sr–Nd–Hf–Pb isotopes  相似文献   
349.
Control over water supply and distribution is critical for agriculture in drylands where manipulating surface runoff often serves the dual purpose of erosion control. However, little is known of the geomorphic impacts and legacy effects of rangeland water manipulation infrastructure, especially if not maintained. This study investigated the geomorphic impacts of structures such as earthen berms, water control gates, and stock tanks, in a semiarid rangeland in the southwestern USA that is responding to both regional channel incision that was initiated over a century ago, and a more recent land use change that involved cattle removal and abandonment of structures. The functional condition of remnant structures was inventoried, mapped, and assessed using aerial imagery and lidar data. Headcut initiation, scour, and channel incision associated with compromised lateral channel berms, concrete water control structures, floodplain water spreader berms, and stock tanks were identified as threats to floodplains and associated habitat. Almost half of 27 identified lateral channel berms (48%) have been breached and 15% have experienced lateral scour; 18% of 218 shorter water spreader berms have been breached and 17% have experienced lateral scour. A relatively small number of 117 stock tanks (6%) are identified as structurally compromised based on analysis of aerial imagery, although many currently do not provide consistent water supplies. In some cases, the onset of localized disturbance is recent enough that opportunities for mitigation can be identified to alter the potentially damaging erosion trajectories that are ultimately driven by regional geomorphic instability. Understanding the effects of prior land use and remnant structures on channel and floodplain morphologic condition is critical because both current land management and future land use options are constrained by inherited land use legacy effects. Published 2017. This article is a U.S. Government work and is in the public domain in the USA  相似文献   
350.
The Irtysh River is the main water resource of Eastern Kazakhstan and its upper basin is severely affected by spring floods each year, primarily as a result of snowmelt. Knowledge of the large-scale processes that influence the timing of these snow-induced floods is currently lacking, but critical for the management of water resources in the area. In this study, we evaluated the variability in winter–spring snow cover in five major sub-basins of the Upper Irtysh basin between 2000 and 2017 as a possible explanatory factor of spring flood events, assessing the time of peak snow cover depletion rate and snow cover disappearance from the moderate-resolution imaging spectroradiometer (MODIS) MOD10A2 data set. We found that on average, peak snow cover retreat occurs between 22 March and 14 April depending on the basin, with large interannual variations but no clear trend over the MODIS period, while our comparative analysis of longer-term snow cover extent from the National Oceanic and Atmospheric Administration Climate Data Record data set suggests a shift to earlier snow cover disappearance since the 1970s. In contrast, the annual peak snow cover depletion rate displays a weak increasing trend over the study period and exceeded 5,900 km2/day in 2017. The timing of snow disappearance in spring shows significant correlations of up to 0.82 for the largest basin with winter indices of the Arctic Oscillation (AO) over the region. The primary driver is the impact of the large-scale pressure anomalies upon the mean spring (MAM) air temperatures and resultant timing of snow cover disappearance, particularly at elevations 500–2,000 m above sea level. This suggests a lagged effect of this atmospheric circulation pattern in spring snow cover retreat. The winter AO index could therefore be incorporated into long-term runoff forecasts for the Irtysh. Our approach is easily transferable to other similar catchments and could support flood management strategies in Kazakhstan and other countries.  相似文献   
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