Partial amorphization of experimentally shocked plagioclase: A spectroscopic study

Shock amorphization of plagioclase, from partial to complete, has been used to evaluate the degree of shock in meteorites. Important information on the shock amplitude can be derived from the measurement of the refractive index in plagioclase, either from mineral separates or in petrographic thin sections. However, this technique is time‐consuming, and associated sample preparations are considered destructive and are not always possible for precious and rare meteorite samples. In addition, plagioclase amorphization is commonly inhomogeneous at the sample scale and a statistically meaningful number of grains must be considered. Here, we apply several nondestructive spectroscopic techniques, such as Raman spectroscopy, photoluminescence, and cathodoluminescence, to plagioclase experimentally shocked at 28 GPa, and thus in the transition regime between crystalline plagioclase and fully amorphous material. Most of the plagioclase was transformed into diaplectic glass at 28 GPa, yet some grains exhibit heterogeneously distributed crystalline domains. This confirms that intrinsic and extrinsic factors lead to local variations in the intensity of the shock pressure within individual plagioclase crystals of homogeneous composition. The amorphization of plagioclase can qualitatively (and potentially also quantitatively) be investigated by spectroscopic techniques, highlighting such local variations in the shock efficiency.     

Surface salinity and nutrient variations during the Littorina Stage in the Fårö Deep,Baltic Sea

Early to late Holocene sediments from core F80, Fårö Deep, Baltic Sea, are investigated for their palynomorph composition and dinoflagellate cyst record to map variations in sea‐surface‐water salinity and palaeoproductivity during the past 6000 years. The F80 palynomorph assemblages are subdivided into four Assemblage Zones (AZs) named A to D. The transition from the stratigraphically oldest AZ A to B reflects a marked increase in palaeoproductivity and a gradual increase in surface‐water salinity over the ～1500 years between the Initial Littorina (former Mastogloia Sea Stage) and Littorina Sea Stage. A period with maximum sea‐surface salinity is recorded within the overlying AZ C from 7200 to 5200 cal. a BP, where the process length of Operculodinium centrocarpum indicates that average salinities were probably the highest (～15–17 versus 7.5 psu today) since the last glaciation. The change from AZ C to D correlates with a shift from laminated to non‐laminated sediments, and the dinoflagellate cyst assemblages suggest that the surface‐ and the deep‐water environment altered from c. 5250 cal. a BP, with less productivity in the surface water and more oxygenated conditions in the deep water. Here we demonstrate that past regional changes in surface salinity, primary productivity and deep‐water oxygenation status in the Baltic Sea can be traced by mapping overall palynomorph composition, dinoflagellate cyst assemblages and variations in the process length of O. centrocarpum in relation to periods of laminated/non‐laminated sedimentation and proportion of organic‐matter in the sediments. An understanding of past productivity changes is particularly important to better understand present‐day environmental changes within the Baltic Sea region.     

Evidence of multiple thermokarst lake generations from an 11 800‐year‐old permafrost core on the northern Seward Peninsula,Alaska

Permafrost degradation influences the morphology, biogeochemical cycling and hydrology of Arctic landscapes over a range of time scales. To reconstruct temporal patterns of early to late Holocene permafrost and thermokarst dynamics, site‐specific palaeo‐records are needed. Here we present a multi‐proxy study of a 350‐cm‐long permafrost core from a drained lake basin on the northern Seward Peninsula, Alaska, revealing Lateglacial to Holocene thermokarst lake dynamics in a central location of Beringia. Use of radiocarbon dating, micropalaeontology (ostracods and testaceans), sedimentology (grain‐size analyses, magnetic susceptibility, tephra analyses), geochemistry (total nitrogen and carbon, total organic carbon, δ¹³C_org) and stable water isotopes (δ¹⁸O, δD, d excess) of ground ice allowed the reconstruction of several distinct thermokarst lake phases. These include a pre‐lacustrine environment at the base of the core characterized by the Devil Mountain Maar tephra (22 800±280 cal. a BP, Unit A), which has vertically subsided in places due to subsequent development of a deep thermokarst lake that initiated around 11 800 cal. a BP (Unit B). At about 9000 cal. a BP this lake transitioned from a stable depositional environment to a very dynamic lake system (Unit C) characterized by fluctuating lake levels, potentially intermediate wetland development, and expansion and erosion of shore deposits. Complete drainage of this lake occurred at 1060 cal. a BP, including post‐drainage sediment freezing from the top down to 154 cm and gradual accumulation of terrestrial peat (Unit D), as well as uniform upward talik refreezing. This core‐based reconstruction of multiple thermokarst lake generations since 11 800 cal. a BP improves our understanding of the temporal scales of thermokarst lake development from initiation to drainage, demonstrates complex landscape evolution in the ice‐rich permafrost regions of Central Beringia during the Lateglacial and Holocene, and enhances our understanding of biogeochemical cycles in thermokarst‐affected regions of the Arctic.     

Devonian graptolites from southwestern Europe: a review with new data

Lower Devonian graptolite faunas have been recognized in the Normandy and southeastern regions of the Armorican Massif, France; the Pyrenees and Catalonian Coastal Ranges regions and northern Minorca, Balearic Islands, Spain; the southern Hesperian Massif (Ossa Morena Zone) of the Iberian Peninsula; and from southeastern Sardinia, Italy. All but one the of the graptolite faunas collected throughout this large region are from Lochkovian age strata, representing the Monograptus uniformis, Monograptus praehercynicus, and Monograptus hercynicus biozones corresponding to the lower, middle and upper Lochkovian, respectively, and mostly represented by monospecific or low diversity assemblages. Although many individual sections contain representatives of two of the biozones, relatively few reveal all three. A single, poorly preserved faunule, collected in the Ossa Morena region of Spain from strata dated by brachiopods as Pragian–early Emsian may represent the only known graptoloid fauna of post-Lochkovian age. Almost all graptolites have been recovered from condensed successions of black shales and limestone nodules, similar to those of other proto-Tethyan (i.e. outer shelf, with dominantly pelagic faunas) regions such as Thuringia, Bohemia, the Carnic Alps and northwestern Africa. The two exceptions are an occurrence in a shallow-water, coarser clastic sequences at the Carteret locality in Normandy and in deep water turbidites on the island of Minorca. Graptolites are not known from any other thick, shallow water clastic sequences, although whether this is because of paleo environmental exclusion or simply lack of recovery to date is unknown. Other fossil evidence (e.g. chitinozoans), however, indicates continuous marine sedimentation from the Silurian to Devonian. © 1996 John Wiley & Sons, Ltd.     

Mechanisms of compaction of quartz sand at diagenetic conditions

The relative contribution of cracking, grain rearrangement, and pressure solution during experimental compaction of quartz sand at diagenetic conditions was determined through electron and optical microscopy and image analysis. Aggregates of St. Peter sand (255±60 μm diameter grain size and porosity of approximately 34%) were subjected to creep compaction at effective pressures of 15, 34.5, 70, and 105 MPa, temperatures of 22 and 150°C, nominally dry or water-saturated (pore fluid pressure of 12.5 MPa) conditions, and for times up to one year. All aggregates displayed transient, decelerating creep, and volume strain rates as low as 2×10⁻¹⁰ s⁻¹ were achieved. The intensity of fracturing and degree of fragmentation increase with volume strain and have the same dependence on volume strain at all conditions tested, indicating that impingement fracturing and grain rearrangement were the main mechanisms of compaction throughout the creep phase. The increase in fracture density and decrease in acoustic emission rate at long times under wet conditions reflect an increase in the contribution of subcritical cracking. No quantitative evidence of significant pressure solution was found, even for long-term creep at 150°C and water-saturated conditions. Comparison of our findings to previous work suggests that pressure solution could become significant at temperatures or times somewhat greater than investigated here.     

Alteration and chemical U-Th-total Pb dating of heterogeneous high-uranium zircon from a pegmatite from the Aduiskii massif,middle Urals,Russia

Mineralogy and Petrology - The U-Th-Pb isotope system in the accessory mineral zircon may be disturbed, as for instance by the secondary loss of radiogenic lead. The recognition of such alteration...