Oxygen and hydrogen isotope fractionation in serpentine-water and talc-water systems from 250 to 450 °C, 50 MPa

Oxygen and hydrogen isotope fractionation factors in the talc-water and serpentine-water systems have been determined by laboratory experiment from 250 to 450 °C at 50 MPa using the partial exchange technique. Talc was synthesized from brucite + quartz, resulting in nearly 100% exchange during reaction at 350 and 450 °C. For serpentine, D-H exchange was much more rapid than ¹⁸O-¹⁶O exchange when natural chrysotile fibers were employed in the initial charge. In experiments with lizardite as the starting charge, recrystallization to chrysotile enhanced the rate of ¹⁸O-¹⁶O exchange with the coexisting aqueous phase. Oxygen isotope fractionation factors in both the talc-water and serpentine-water systems decrease with increasing temperature and can be described from 250 to 450 °C by the relationships: 1000 ln  = 11.70 × 10⁶/T² − 25.49 × 10³/T + 12.48 and 1000 ln  = 3.49 × 10⁶/T² − 9.48 where T is temperature in Kelvin. Over the same temperature interval at 50 MPa, talc-water D-H fractionation is only weakly dependent on temperature, similar to brucite and chlorite, and can be described by the equation: 1000 ln = 10.88 × 10⁶/T² − 41.52 × 10³/T + 5.61 where T is temperature in Kelvin. Our D-H serpentine-water fractionation factors calibrated by experiment decrease with temperature and form a consistent trend with fractionation factors derived from lower temperature field calibrations. By regression of these data, we have refined and extended the D-H fractionation curve from 25 to 450 °C, 50 MPa as follows: 1000 ln  = 3.436 × 10⁶/T² − 34.736 × 10³/T + 21.67 where T is temperature in Kelvin. These new data should improve the application of D-H and ¹⁸O-¹⁶O isotopes to constrain the temperature and origin of hydrothermal fluids responsible for serpentine formation in a variety of geologic settings.     

Amplitudes of long-period PcP and the core-mantle boundary

The amplitudes of the core reflection PcP are sensitive to the wave velocities and densities in the neighborhood of the core-mantle boundary (CMB). We study the amplitude ratio of the long-period phases PcP and P from two South American deep-focus earthquakes with favorable fault-plane solution, depth and magnitude, as recorded by WWNSS and CSN stations in North America.Comparison is made with long-period PcP/P amplitude ratios, derived from theoretical seismograms for a variety of CMB models. Models from previous studies, which were mainly derived from short-period PcP observations and which are characterized by discrete layers above the CMB, are almost all inconsistent with the long-period data. The data also discriminate against low nonzero S velocities below the CMB. Simple first-order-discontinuity models of the CMB, for instance according to the Jeffreys-Bullen earth model or according to recent models based mainly on free oscillations, explain the data reasonably well.Model improvements are attempted by varying the P-velocity gradient above the CMB. The best amplitude fit is obtained for a rather strong decrease in P velocity with depth in this zone which, however, gives no acceptable traveltime fit for PcP. The scatter in body-wave amplitudes is considerable even for long-period waves and may prevent the correct assessment of that part of the amplitude variation of a phase with distance that is due to the variation of velocities and densities with depth alone.     

Ecological-geochemical assessment of the state of the Volga source of water supply to Moscow

Long-term observational data (1992?C2009) on heavy metal (Cu, Zn, Pb, Cr, Ni, V, Mo, Co, Fe, and Mn) content of different links in the Ivankovo Reservoir ecosystem are used to consider the regularities in the distribution and behavior of heavy metals in the system anthropogenic pollution sources-reservoir and its drainage area, thus enabling the assessment of the pollution level of the Volga Source of water supply to Moscow.     

Meridional transport of sensible heat in contrasting monsoon activity: Spherical harmonic analysis

Spherical harmonic analysis is made of the grid point values of geopotential heights at 700 mb and 300 mb levels for the months April to August for the years 1967 and 1972. The year 1967 is a good monsoon year and 1972 is a bad monsoon year in India. Meridional transport of sensible heat is obtained in wave number domain using spherical harmonic coefficients at 500 mb level form=1 to 10 andn–m=0 to 10, wherem represents the wave number round the globe andn–m gives the numbers of zero points from north pole to south pole excluding the poles themselves.Large northward transports of sensible heat in the month of May and in the monsoon months at the subtropics are characteristic of bad monsoon. Wave 1 transports sensible heat southward (forn–m=0) and wave 2 transports sensible heat northward (forn–m=4). Strengthening of wave 1 is conducive to good monsoon year and strengthening of wave 2 is conducive to bad monsoon year. These are the same features obtained in Fourier analysis. The contrasting features exist in waves 1 and 2 both in good and in bad monsoon and are better defined in the present analysis than in the Fourier analysis of the earlier study. However, waves 1 and 2 reveal clearer contrast in the present analysis than in the Fourier analysis. Bad monsoon activity is associated with large divergence of heart at subtropics and large convergence of heat at extra tropics.     

First Data on the Isotopic Age of Zircons from Rocks of the Roseta Ultramafic Massif,Southern Margin of the São Francisco Craton (Brazil)

Doklady Earth Sciences - The results of isotope U–Pb dating of zircons from lherzolite and vein olivine orthopyroxenite composing the Roseta ultramafic massif are presented. The zircons...     

Multidimensional statistical technique for detection of low contrast geochemical anomalies

In this article we propose an advanced technique for detecting low contrast geochemical anomalies using a set of features. There are three principal elements in this technique: (1) a statistical measure of the contrast of the anomaly, denoted as τ; (2) selection of a background population; and (3) reduction of the dimensionality of the feature space. In the frame of the model, which describes the statistical distribution of geochemical background as a multidimensional normal distribution of logarithms of concentrations, the index, τ, is a powerful test statistic for the hypothesis of abnormality of an observation. Maps of τ anomalies can be rigorously interpreted on the basis of statistical inferences. Under all equal conditions this technique allows the detection of geochemical anomalies with at least the same contrast (if the chemical elements in a background population are correlated, then even the better) as using selective extractions of metals from soil or other techniques for data processing. The advantages of the proposed technique are demonstrated both theoretically and on examples of rare-metal and copper–nickel mineral deposits.     

Superposition of gold mineralisation on pre‐existing carbonate alteration: Structural evidence from the Mulgarrie gold deposit,Yilgarn Craton

Carbonate alteration at the Mulgarrie gold mine in the Eastern Goldfields of Western Australia, is represented by porphyroblasts, veins and pervasive, texturally destructive, carbonatisation. Two foliations, S_1M and S_2M, were produced by two separate deformation events at the mine‐scale, D_1M and D_2M. D_1M and D_2M both occurred in response to regional D₂ tectonism. Carbonate alteration was the product of two separate episodes of fluid ingress: the earlier produced magnesite and the latter Fe‐dolomite. Both periods of carbonate alteration occurred pre‐ to early syn‐D_2M, when mafic to ultramafic komatiitic rocks reacted with fluids that moved along regional faults and pre‐date the alteration associated with regional peak metamorphism. Gold at Mulgarrie overprints pre‐ and late syn‐D₂ quartz veins in zones of massive carbonate alteration, suggesting it has a late‐ to post‐D₂ timing. This late timing agrees with the generally accepted syn‐D₃ (and younger) age for gold mineralisation in the Eastern Goldfields. We suggest that carbonate alteration at Mulgarrie is not a product of the hydrothermal event responsible for the gold mineralisation. Rather, the different relative timing of magnesite, Fe‐dolomite and gold indicates there were two carbonate‐producing fluid systems and a fluid transporting the gold overprinted these. Similarly, early carbonate alteration may play a role in localising auriferous vein deposits throughout the Yilgarn and other Archaean cratons.     

Power spectrum of brightness temperature fluctuations derived from solar eclipse observations at 2.8 GHz

In this paper we report on the MEM power spectrum analysis of brightness temperature fluctuations observed at 2.8 GHz during the total solar eclipse of 16 February 1980. The observed periodicities range from 3.5 min to 64 min. These periodicities may arise due to spatial and/or temporal variations in the solar radio emission. The observed periodicities imply presence of scale sizes ranging from 70,000 to 600,000 km assuming that the brightness fluctuations arise because of spatial variation only. On the other hand, if these fluctuations are due to temporal variation, the observed periodicities correspond well to predicted modes of solar global oscillations.     

Mantle(?) xenoliths in the carbonatites of northern Transbaikalia

The composition and nature of high-Cr minerals in lithic clasts from the carbonatites of the Veseloe occurrence, northern Transbaikalia, were considered. In order to determine their source, the Cr-bearing phases were compared with chromite, magnetite, and rutile from ultrabasic rocks, mantle xenoliths, and eclogites. It was suggested that the xenoclasts studied were formed at great depths, whereas the carbonatites were directly derived from the mantle rather than formed by the crustal differentiation of a silicate-carbonate melt.