Application of a square wave potentiometry technique for electroreductive sulfur removal from a thiophenic model fuel

Thiophene-containing solutions were electroreductively desulfurized by a dynamic method. Initially, cyclic voltammetry was utilized to study thiophene electroadsorption from aqueous solution onto a platinum electrode surface and also to investigate the thiophene electroreductive behavior. Then, the solution was desulfurized via a square wave potentiometry method. The objective of this study was to find the optimal conditions. In this regard, the best adsorption potential, electroreduction potential, and square wave frequency were found to be ?0.54 V, ?0.95 V, and 1 Hz, respectively. Finally, a model fuel (containing 294 part per millions thiophene) was desulfurized by the square wave potentiometry method. Gas chromatography and Fourier transform infrared spectroscopy were used to examine the feed and product solutions. Gas chromatographic measurements revealed that sulfur content decreased to 55 part per millions. Based on the acquired results, electroreductive desulfurization could be designated as an efficient superseded for the commercial hydrodesulfurization process. However, more studies must perform to overcome technical limitations of electroreductive desulfurization technique and to guarantee its reliability.     

Heat capacity,compressibility and thermal expansion coefficient of ilmenite-type MgGeO3

The accuracy of differential scanning calorimetry (DSC) on a heat capacity measurement was evaluated using MgO. The result indicated that the deviation of the result in comparison to literature values was less than 0.4% at temperatures above 300 K and 2.1% below this temperature. Since this experiment proved the reliability of DSC, heat capacity, compressibility, and thermal expansion of ilmenite-type MgGeO₃ were measured by means of DSC, a diamond anvil high pressure device, and a high-temperature X-ray camera, respectively. The heat capacity was approximated by C _p = a + b·T + c·T ^?2 at high temperatures and by the Debye function at low temperatures. The compressibility was well-represented by the Murnaghan-Birch equation of 2nd order. The thermal expansion coefficient was constant up to 1073 K.     

Physical Libration of the Moon: An Extended Problem

Astronomy Reports - The work is devoted to the study of the physical libration of the Moon. Interest in the traditional topic related to the rotation of the Moon is stirred up by the activity of...     

Interaction of the Atmosphere and Lithosphere in the Minute Range of Periods

Doklady Earth Sciences - The interaction between the atmosphere and the lithosphere in the minute range of periods is considered. The technique of assessment of the influence of atmospheric...     

Geochemical Indicators of “Camouflaged” Pyroclastic Material in the Upper Jurassic–Lower Cretaceous Deposits of the Eastern Russian Platform

Doklady Earth Sciences - Based on the results of studying the lithological–geochemical features of the Upper Jurassic–Lower Cretaceous mudrocks and black shales in the Eastern Russian...     

Baroclinic seiches in rotating basins of variable depth in the case of two-layer density stratification

We solve a plane problem of linear baroclinic seiches in closed rotating basins of variable depth with two-layer density stratification. In the long-wave approximation, we get a boundary-value problem for a system of ordinary differential equations and propose a numerical procedure for finding internal seiches. The analytic solutions of the problem are obtained for a basin of constant depth. The numerical analysis of seiches is performed for the distributions of depth corresponding to the zonal and meridional sections of the Black Sea and model basins including the cases of a shelf zone and an underwater ridge. It is shown that the baroclinic seiches become more intense in shallow-water regions and that the intense longshore currents caused by Earth’s rotation are formed in the shelf zones and over the underwater ridges.