The U–Pb SHRIMP age of zircons from diorites of the Tomino–Bereznyaki ore field (South Urals,Russia): evolution of porphyry Cu–epithermal Au–Ag system

The Tomino–Bereznyaki ore field lies in the western part of the East Urals volcanic megazone (20–30 km southwest of Chelyabinsk). The commercial Tomino porphyry (Mo, Au)–Cu deposit is localized in the east of the field, within a small mesoabyssal intrusion of quartz–diorite composition. The epithermal Au–Ag Bereznyaki deposit is confined to subvolcanic dioritic porphyrites in the west of the field. The western and eastern parts of the ore field have a tectonic boundary. Granitoids belong to a single volcanoplutonic complex of K–Na-quartz–diorite composition. The U–Pb concordant age of zircons from the ore-bearing dioritic porphyrite of the Tomino and Bereznyaki deposits is 428 ± 3 Ma (MSWD = 0.9) and 427 ± 6 Ma (MSWD = 1.1), respectively. A Silurian absolute age has been established for the Urals porphyry Cu ore-magmatic system for the first time. The diorites and acid metasomatites of both deposits contain a unique three-mica assemblage (Mu, Pa, and Mu0.36Pa0.64). The metasomatized diorites are of similar isotope-petrogeochemical compositions; they have close total REE contents (24–52 ppm) and REE patterns. Their Zr–Hf, Nb–Ta, and La–Ce diagrams show similar trends. The obtained data indicate the close time of formation of the porphyry and epithermal deposits and their probable genetic unity. The vertical evolution of the porphyry Cu column from meso- and hypabyssal to subvolcanic level includes the isotope (Sr, S, and O) crust–mantle interaction. The deposits formed at different depths expose on the modern surface as a result of the block tectonic processes in the ore field.     

Synthesis and characterization of reusable nano-order SO<Subscript>3</Subscript>H-KIT-5 as a heterogeneous catalyst for eco-friendly synthesis of 1,4-dihydropyridines

A novel nanocatalyst silica-bonded sulfuric acid supported on KIT-5 as an organic–inorganic hybrid with high activity was prepared successfully. The KIT-5 with high surface area was reacted with chlorosulfonic acid via simple and rapid method. This efficient and reusable heterogeneous catalyst sulfuric acid nanocatalyst catalyzed one-pot synthesis of β-dicarbonyl compounds, aldehyde and ammonium acetate in the presence of 0.05 g of nanocatalyst at room temperature via solvent-free conditions to afford excellent yields of 1,4-dihydropyridines. This nanocatalyst was fully characterized by XRD, SEM–EDXS and Map analyses. The morphology of the catalyst surface by SEM images shows all porous of KIT-5 after the reaction was filled with the SO₃H groups. The average size determines around 22–24 nm. This catalyst can be reused five times without any significant loss of activity, too. The ease of separation, high activity, high surface area and reaction under open air condition are the main advantages of this catalyst.     

The late Tonian Zhaunkar granite complex of the Ulutau sialic massif,Central Kazakhstan

The crystallization age of Zhaunkar granites (829 ± 10 Ma) was determined by U–Pb zircon dating. Taking into account the data obtained earlier on the granite age (791 ± 7 Ma) in the Aktas Complex and the syenite age (673 ± 2 Ma) in the Karsakpai Complex, the Ulutau sialic massif is assumed to be composed of three igneous complexes formed during the Tonian–Cryogenian periods of the Neoproterozoic.     

Iron (III)-silica interactions in aqueous solution: insights from X-ray absorption fine structure spectroscopy

The influence of aqueous silica on the hydrolysis of iron(III) nitrate and chloride salts in dilute aqueous solutions (m_Fe ∼ 0.01 mol/kg) was studied at ambient temperature using X-ray absorption fine structure (XAFS) spectroscopy at the Fe K-edge. Results show that in Si-free iron nitrate and chloride solutions at acid pH (pH < 2.5), Fe is hexa-coordinated with 6 oxygens of H₂O- and/or OH-groups in the first coordination sphere of the metal, at an Fe-O distance of 2.00 ± 0.01 Å. With increasing pH (2.7 < pH < 13), these groups are rapidly replaced by bridging hydroxyls (-OH-) or oxygens (-O-), and polymerized Fe hydroxide complexes form via Fe-(O/OH)-Fe bonds. In these polymers, the first atomic shell of iron represents a distorted octahedron with six O/OH groups and Fe-O distances ranging from 1.92 to 2.07 Å. The Fe octahedra are linked together by their edges (Fe-Fe distance 2.92-3.12 Å) and corners (Fe-Fe distance ∼3.47 ± 0.03 Å). The Fe-Fe coordination numbers (N_edge = 1-2; N_corner = 0.5-0.7) are consistent with the dominant presence of iron dimers, trimers and tetramers at pH 2.5 to 2.9, and of higher-polymerized species at pH > 3.At pH > 2.5 in the presence of aqueous silica, important changes in Fe(III) hydrolysis are detected. In 0.05-m Si solutions (pH ∼ 2.7-3.0), the corner linkages between Fe octahedra in the polymeric complexes disappear, and the Fe-Fe distances corresponding to the edge linkages slightly increase (Fe-Fe_edge ∼ 3.12-3.14 Å). The presence of 1 to 2 silicons at 3.18 ± 0.03 Å is detected in the second atomic shell around iron. At basic pH (∼12.7), similar structural changes are observed for the iron second shell. The Fe-Si and Fe-Fe distances and coordination numbers derived in this study are consistent with (1) Fe-Si complex stoichiometries Fe₂Si_1-2 and Fe₃Si_2-3 at pH < 3; (2) structures composed of Fe-Fe dimers and trimers sharing one or two edges of FeO₆-octahedra; and (3) silicon tetrahedra linked to two neighboring Fe octahedra via corners. At higher Si concentration (0.16 m, polymerized silica solution) and pH ∼ 3, the signal of the Fe second shell vanishes indicating the destruction of the Fe-Fe bonds and the formation of different Fe-Si linkages. Moreover, ∼20 mol.% of Fe is found to be tetrahedrally coordinated with oxygens in the first coordination shell (R_Fe-O = 1.84 Å). This new finding implies that Fe may partially substitute for Si in the tetrahedral network of the silica polymers in Si-rich solutions.The results of this study demonstrate that aqueous silica can significantly inhibit iron polymerization and solid-phase formation, and thus increase the stability and mobility of Fe(III) in natural waters. The silica “poisoning” of the free corner sites of iron-hydroxide colloids should reduce the adsorption and incorporation of trace elements by these colloids in Si-rich natural waters.     

Microplastics as contaminants in the marine environment: a review

Since the mass production of plastics began in the 1940s, microplastic contamination of the marine environment has been a growing problem. Here, a review of the literature has been conducted with the following objectives: (1) to summarise the properties, nomenclature and sources of microplastics; (2) to discuss the routes by which microplastics enter the marine environment; (3) to evaluate the methods by which microplastics are detected in the marine environment; (4) to assess spatial and temporal trends of microplastic abundance; and (5) to discuss the environmental impact of microplastics. Microplastics are both abundant and widespread within the marine environment, found in their highest concentrations along coastlines and within mid-ocean gyres. Ingestion of microplastics has been demonstrated in a range of marine organisms, a process which may facilitate the transfer of chemical additives or hydrophobic waterborne pollutants to biota. We conclude by highlighting key future research areas for scientists and policymakers.     

The formation age of ores from the Pebble Cu-Au-Mo giant deposit (Alaska,United States)

Zircons from the porphyry-like quartz-diorite boss of the Pebble Cu-Au-Mo deposit (southwest Alaska) have been examined. By their appearance and internal structure (cathode luminescence and electron probing), the zircons have been subdivided into four genetic groups: (1) xenogenic detrital (mainly rounded); (2) magmatogene (protolith crystal in the center and growth zone at the edge); (3) hydrothermally altered (with new-formed regeneration edges in growth zones); (4) metamict-altered (unconsolidated center of the crystal and sectoring in growth zones). Based on SHRIMP U-Pb dating for the principal heterogeneous elements in every group, the following stages of ore formation have been identified for the Pebble deposit: (a) crystallization of quartz diorite-porphyry bosses (95–92 Ma, the concordant age is 94.7 ± 1.5 Ma); (b) late magmatic metasomatic alterations with copper-molybdenum mineralization (92–85 Ma, the concordant age is 90.15 ± 0.78 Ma); (c) postmagmatic argillization with epithermal gold-sulfide mineralization (82–80 Ma, the concordant age is 82.9 ± 2.7 Ma).     

Earthquake awareness and perception of risk among the residents of Istanbul

Awareness and perception of risk are among the most crucial steps in the process of taking precautions at individual level for various hazards. In this study, we investigated the factors affecting better knowledge and greater risk perception about earthquakes among residents of Istanbul. A field survey was carried out, and a total of 1,123 people were interviewed in two districts of Istanbul with different seismic risk levels and from three (low, moderate and high) socio-economic levels (SEL). The findings showed that although the level of knowledge regarding earthquakes and preparedness for them was promising, it could be improved. The results indicated that future preparedness programmes should target people with lower educational and socio-economic levels. The media were the leading source of information among the respondents. Location of the home was a strong influence on individuals having above average earthquake knowledge and even more on high risk perception. Socio-economic parameters (educational level, economic status, SEL of the sub-district and tenure of the home), gender and attitude score were other factors influencing greater risk perception with regard to earthquakes.     

3.3 Millimeter limb brightening measurements during the 30 June 1973 total solar eclipse

Solar limb brightening measurements at a wavelength of 3.3 mm were made during the 30 June 1973 total solar eclipse from a site at Lake Rudolf, Kenya. The results show that at this wavelength there is a limb brightening of about 20%, occurring within one half arc min of the limb.     

Influence of Inelastic Collisions with Hydrogen Atoms on Non-LTE Oxygen Abundance Determinations

We present the results of our modeling of the O I line formation under non-LTE conditions in the atmospheres of FG stars. The statistical equilibrium of O I has been calculated using Barklem’s quantum-mechanical rates of inelastic collisions with hydrogen atoms. We have determined the non-LTE oxygen abundance from atomic O I lines for the Sun and 46 FG stars in a wide metallicity range, ?2.6 < [Fe/H] < 0.2. The application of accurate atomic data has led to an increase in the departures from LTE and a decrease in the oxygen abundance compared to the use of Drawin’s theoretical approximation. The change in the non-LTE abundance from the infrared O I 7771-5 Å triplet lines is 0.11 dex for solar atmospheric parameters and diminishes in absolute value with decreasing metallicity. We have revised the [O/Fe]–[Fe/H] relationship derived by us previously. The change in [O/Fe] is small in the [Fe/H] range from ?1.5 to 0.2. For stars with [Fe/H] < ?1 the [O/Fe] ratio has increased so that [O/Fe] = 0.60 at [Fe/H] = ?0.8 and rises to [O/Fe] = 0.75 at [Fe/H] = ?2.6.