Distribution of moderately volatile trace elements in fine-grained chondrule rims in the unequilibrated CO3 chondrite, ALH A77307

The concentrations of Ni, Cu, Zn, Ga, Ge, and Se in five, fine-grained chondrule rims in the highly unequilibrated CO3 chondrite ALH A77307 (3.0) have been determined for the first time by synchrotron X-ray fluorescence (SXRF) microprobe at Brookhaven National Laboratory. These elements are especially useful for tracing the role of condensation and evaporation processes which occurred at moderate temperatures in the solar nebula. Understanding the distribution of moderately volatile elements between matrix and chondrules is extremely important for evaluating the different models for the volatile depletions in chondritic meteorites. The data show that the trace element chemistry of rims on different chondrules is remarkably similar, consistent with data obtained for the major and minor elements by electron microprobe. These results support the idea that rims are not genetically related to individual chondrules, but all sampled the same reservoir of homogeneously mixed dust. Of the trace elements analyzed, Zn and Ga show depletions relative to CI chondrite values, but in comparison with bulk CO chondrites all the elements are enriched by approximately 1.5 to 3.5 x CO. The abundance patterns for moderately volatile elements in ALH A77307 chondrule rims closely mimic those observed in the bulk chondrite, indicating that matrix is the major reservoir for these elements. The close matching of the patterns for the volatile depleted bulk chondrite and enriched matrix is especially striking for Na, which is anomalously depleted in ALH A77307 in comparison with average CO chondrite abundances. The depletion in Na is probably attributable to the effects of leaching in Antarctica. With the exception of Na, the volatile elements show a relatively smooth decrease in abundance as a function of condensation temperature, indicating that their behavior is largely controlled by their volatility.     

Association of orogenic activity with the Ordovician radiation of marine life

The Ordovician radiation of marine life was among the most substantial pulses of diversification in Earth history and coincided in time with a major increase in the global level of orogenic activity. To investigate a possible causal link between these two patterns, the geographic distributions of 6576 individual appearances of Ordovician vician genera around the world were evaluated with respect to their proximity to probable centers of orogeny (foreland basins). Results indicate that these genera, which belonged to an array of higher taxa that diversified in the Middle and Late Ordovician (trilobites, brachiopods, bivalves, gastropods, monoplacophorans), were far more diverse in, and adjacent to, foreland basins than they were in areas farther removed from orogenic activity (carbonate platforms). This suggests an association of orogeny with diversification at that time.     

在应用计算机解释印度拉贾斯坦邦西部贾伊萨梅尔地区比尔马尼亚盆地地质特征中地质数据的分析

最近十年来研究的地质数据包括比尔马尼亚盆地岩相的地层、岩性、岩石、粒度和地球化学资料。这些数据已进入专用的“Ｆｏｘｓｅｄｂａ”数据表以建立比尔马尼亚盆地的数据总库。采用Ｈａｒｗａｒｄ制图法在ｘ－ｙ轴（粒度参数和地球化学数据）上作图。该盆地各种岩相的环境解释模式都配备有“图象”软件。最后,上述资料被用来解释所推断的比尔马尼亚盆地各种岩相的沉积环境。该盆地的沉积充填物含硅质碎屑、碳酸盐和磷块岩相的混合组合,指示变幻不定的沉积环境,即有若干具间歇海进事件的沉积海退事件。结果,磷块岩主要形成一种浅水正化学沉积和异化学沉积的复杂组合。     

Results of TV imaging of Phobos (Experiment VSK-Fregat)

From February to March 1989 the Phobos 2 spacecraft took 37 TV images of Phobos at a distance of 190-1100 km. These images complement Mariner-9 and Viking data by providing higher-resolution coverage of a large region West of the crater Stickney (40-160 degrees W) and by providing disk-resolved measurements of surface brightness at a greater range of wavelengths and additional phase angles. These images have supported updated mapping and characterization of large craters and grooves, and have provided additional observations of craters' and grooves' bright rims. Variations in surface visible/near-infrared color ratio of almost a factor of 2 have been recognized; these variations appear to be associated with the ejecta of specific large impact craters. Updated determinations of satellite mass and volume allow calculation of a more accurate value of bulk density, 1.90 +/- 0.1 g cm-3. This is significantly lower than the density of meteoritic analogs to Phobos' surface, suggesting a porous interior perhaps containing interstitial ice.     

Distribution and mode of occurrences of radionuclides in phosphogypsum from the Aqaba and Eshidiya fertilizer plants, Jordan

Phosphogypsum is a waste by-product of the phosphate fertilizer industry that has relatively high concentrations of some U decay-series radionuclides such as ^226Ra and ^210Pb. The distribution and environmental mobility of radionuclides in phosphogypsum are an important concern because this gypsum by-product is used for wallboard, in agriculture and as a soil amendment. This study determined the distribution of ^226Ra, ^210Pb, within phosphogypsum stacks of varying age and among three size fractions （coarse： 〈0.212 mm; medium： 0.212-0.053 mm; fine： 〈0.053 mm）, in phosphogypsum derived from Aqaba and Eshidiya fertilizer plants. The results indicated that ^226Ra and ^210Pb were generally uniformly distributed in phosphogypsum stacks and showed no significant difference in the concentration of these elements with the age of stack. In the Aqaba phosphogypsum ^226Ra was slightly 10% enriched in the coarse fraction, while ^210Pb was 10% enriched in the free size fraction. In the Eshidiya phosphogypsum ^226Ra and ^210Pb contents were both relatively enriched （10%） in the fine size fraction.     

THE INFLUENCE OF FERTILIZERS, NaHCO3,SOIL TYPE ON CHEMISTRY OF FLOODED SOILS AND RICE PLANT GROWTH

1 INTRODUCTIONQuality of chemical properties of flooded soils isgenerally determined by salinity and alkalinity,bothof these acts as inhibiting factors of plant growth.Thecorrelation of electrical conductivity and other analysisindex has been reported by …     

Hydrogeochemical controls on surface and groundwater chemistry in naturally acidic, porphyry-related mineralized areas, southern Rocky Mountains

In southern Rocky Mountains, catchments characterized by acidic, metalliferous waters that are relatively unaffected by human activity usually occur within areas that have active or historical mining activity. The US Geological Survey has utilized these mineralized but unmined catchments to constrain geochemical processes that control the surface- and ground-water chemistry associated with near surface acid weathering as well as to estimate premining conditions. Study areas include the upper Animas River watershed, Lake City, Mt. Emmons, and Montezuma in Colorado and Questa in New Mexico. Although host-rock lithologies range from Precambrian gneisses to Cretaceous sedimentary units to Tertiary volcanic complexes, mineralization is Tertiary in age and associated with intermediate to felsic composition, porphyritic plutons. Pyrite is ubiquitous. Variability of metal concentrations in water is caused by two main factors： mineralogy and hydrology. Parameters that potentially affect water chemistry include： host-rock lithology, intensity of hydrothermal alteration, sulfide mineralogy and chemistry, gangue mineralogy, length of flow path, precipitation, evaporation, and redox conditions. Springs and headwater streams have pH values as low as 2.5, sulfate up to 3700 mg/L and high dissolved metal concentrations （for example： Al up to 170 mg/L; Fe up to 250 mg/L; Cu up to 3.5 mg/L and Zn up to 14 mg/L）. With the exception of evaporative waters, the lowest pH values and highest Fe and Al concentrations occur in water draining the most intense hydrothermally altered areas consisting of the mineral assemblage quartz-sericite-pyrite. Stream beds tend to be coated with iron floc, and some reaches are underlain by ferricrete. When iron-rich ground water interacts with oxygenated waters in the stream or hyporheic zone, ferrous iron is oxidized to ferric iron, which is less soluble, leading to the precipitation of iron oxyhydroxides.     

青藏高原北羌塘半岛湖新生代粗面玄武岩橄榄石电子探针和激光探针分析

利用电子探针和激光探针剥蚀系统（LA-ICP-MS），对北羌塘新第三纪粗面玄武岩中的橄榄石主元素和微量、稀土元素进行了系统分析。结果表明，本区橄榄石Fo平均为88，属贵橄榄石种属。相对富集Ni、Co和重稀土，而强烈亏损轻稀土及Rb、Sr、Ba、Zr等大离子亲石元素。其稀土元素配分型配分型式与粗面玄武岩全岩稀土配分型式呈互补状态。     

藏南地壳速度结构与地壳物质东西向“逃逸”──以佩枯错-普莫雍错宽角反射剖面为例

根据佩枯错-普莫雍错480余公里长地震剖面上纵、横波波场特征识别的来自Moho界面反射及壳内界面反射震相, 通过正演拟合解释藏南地区近东西向剖面地壳纵、横波速度与泊松比结构. 结果显示: 该区地壳厚度东西向变化显著, 分别以定日西、定结东为界呈现“块体三分”格局, 西段Moho界面埋深为71 km, 中段约76 km, 东段约74 km; 上地壳底部深度20~30 km左右处存在一低速层, 其厚度沿东西向急剧变化, 即从西段的20 km减薄至东段的6 km左右; 地壳内纵、横波速度变化剧烈, 在东西方向上呈现出跳跃式周期性变化. 下地壳物质低波速与3条近南北向活动正断层的存在可能是伴随印度与欧亚板块碰撞、下地壳物质“拆沉”、地壳增厚与物质东西向“逃逸”耦合作用的结果.