Predicting copper toxicity in estuarine and marine waters using the Biotic Ligand Model

The Biotic Ligand Model (BLM) has proven efficient in predicting the toxicity of a variety of metals to freshwater organisms. Consequently, the US EPA has proposed its use for calculating freshwater copper criteria. This study evaluates the BLM for use in estuarine and marine waters. Studies were conducted using the bivalve, Mytilus sp. and 48-h embryo-larval development chronic estimator test methods. These are the most sensitive taxa and test in the US EPA saltwater copper criteria database. Samples from five locations around the USA were tested. There is a strong relationship between measured and BLM predicted copper EC50s (log transformed data, r² = 0.76, p < 0.001, n = 44). The BLM predicted within a factor ±2 of measured EC50s in 41 of 44 cases. However, the BLM tends to predict lower EC50s when measured EC50s are approximately 10 μg Cu/L. This may be due to limitations of the metal-dissolved organic matter interaction model.     

Geochemical processes controlling the spatial distribution of selenium in soil and water,west central South Dakota,USA

Selenium (Se) is essential in the human diet, but has a low threshold for toxic concentration. It is recommended that nutrients such as Se should be consumed through foods as part of a normal diet. Se concentrations in crops and meat depend on the amount of labile Se in the soil where crops and forage are grown. Therefore, managing agriculture for optimal Se in grain crops and forage requires an understanding of the distribution and mobility of Se. Elevated concentrations of Se occur in waters, soils, and forage 120 km west of Pierre in west central South Dakota, USA. The research site lies in an elevated, dissected plain where soils developed on gently dipping Pierre Shale. Soils were sampled along catena transects and waters collected from soil, ponds, and shallow borings in areas of known elevated forage and crop Se. Soil extracts from saturated-paste extraction and acid (aqua regia and hydrofluoric acid) extraction were analyzed. Selenate was the dominant Se species in both acid and saturated-paste extracts; selenite and organic Se were below detection (<0.2 ppb) in the same soil extracts. On average, 98% of soil Se was not water-soluble. The distribution of total Se shows much less spatial variation than water-soluble Se in the areas sampled. Se shows correlation with organic carbon in soils and waters, suggesting its association with organic carbon. Ca shows some correlation to Se in acid extracts, but not in saturated-paste extracts or in waters. Total Se shows no significant correlation to Na, Mg, and total S in the soils. Se in saturated-paste extracts and water samples shows good correlations with Na, Mg, and SO₄, suggesting that evaporitic Na–Mg–sulfate minerals may temporarily concentrate water-soluble Se in shallow soils. The dissolution and precipitation of these Na–Mg–sulfate salts together with pH and oxidation–reduction conditions apparently control water-soluble Se distribution and mobilization in shallow subsurface environments.     

Characterising the distribution of near-shore submarine groundwater discharge along a coastline using 222Rn and electrical conductivity

The spatial and temporal distribution of near-shore fresh submarine groundwater discharge (SGD) was characterised from the coastal aquifers of the Willunga Basin, South Australia, an extensive aquifer system that supports an important viticultural region. Measurements of electrical conductivity (EC) and ²²²Rn (radon) activity were collected at 19 sites along the coastline during the Southern Hemisphere spring (2011) and summer (2013). At each site, samples were collected from the surf zone as well asporewater from beach sediment in the intertidal zone. Surf-zone radon activity ranged from <5 to 70mBq L^–1, and intertidal porewater radon ranged over two orders of magnitude (220–36 940 mBq L^–1) along the Willunga Basin coastline during both surveys. Overall, surf-zone and porewater EC was lower in the spring 2011 survey than in the summer 2013 survey. Porewater EC was similar to that of coastal water at most sites along the coastline, except at three sites where porewater EC was found to be lower than coastal water during both surveys, and three sites where evaporated seawater was observed in the summer survey. Based on the patterns in radon and EC along the coastline, two sites of localised fresh SGD were identified, in addition to a groundwater spring that is known to discharge to the coast. The results indicate that near-shore fresh SGD occurs as localised seeps rather than diffuse seepage along the entire coastline. The apparent absence of groundwater discharge at most locations is also consistent with current evidence suggesting that extensive groundwater pumping within the basin has resulted in seawater intrusion across much of the coastline. These observations also suggest that previous studies are likely to have over-estimated SGD rates from the Willunga Basin because they assumed that SGD occurred along the entire coastline.     

Mineralogy and geochemistry of lateritic soil profiles in Kerala, India

Lateritic soils near Calicut, Kerala, contain halloysite of intermediate hydration, kaolinite, goethite, gibbsite and quartz. The presence of halloysite is responsible for relatively high plasticity and cation-exchange capacity. Fe-hydroxide colloids along with halloysite contribute to significant phosphate uptake by this soil. Composition of local groundwater is consistent with weathering of sodic plagioclase to gibbsite, kaolinite and metastable halloysite.     

A comparison of methods of strain determination in rocks from southwest Dyfed (Pembrokeshire) and adjacent areas

A variety of methods devised in the last twelve years for measuring two-dimensional strain ratios have been applied to the same deformed oolitic limestone from southwest Dyfed. Their relative merits are discussed. A graphical method for studying relative locations of marker objects is described and its application to a variety of rocks illustrated. It is shown to have theoretical and practical advantages, while giving values of two-dimensional strain ratios comparable with those of other methods.     

Recognition of the Cambrian Timan–Severnaya Zemlya orogen and timing of geological evolution of the North Kara sedimentary basin based on detrital zircon dating

New data on the ages of detrital zircons from folded basement rocks and cover sediments of the Severnaya Zemlya archipelago and Izvestiy TSIK islands have been obtained. The basement age is defined as Cambrian (pre-Ordovician). The Ordovician and Silurian sandstones were mainly formed by erosion of the basement rocks. The Devonian sandstones were formed by debris sourced from the Caledonian orogen. The Carboniferous–Early Permian molasse was formed simultaneously with the erosion of the Carboniferous granitoids and weathering of the Ordovician volcanic arc rocks and the Cambrian basement. The North Kara basin was formed in the Ordovician as a back-arc basin. It experienced its main compression deformations at the boundary of the Devonian and Carboniferous and in the Carboniferous.     

Tectonic evolution of the Siberian Platform during the Vendian and Phanerozoic

This paper presents characteristics of the structural regions surrounding the Siberian Platform and discusses the Vendian-present time evolution of the Siberian Paleocontinent with the Siberian Craton making up its nucleus. It shows that the paleocontinent underwent significant intraplate compressional deformations with vertical movements and formation of inversion structural features within broad areas. Such epochs of deformation took place at the Riphean-Vendian time boundary, during the Late Paleozoic, Late Triassic, Early Cretaceous, and during the Late Cenozoic. The principal rifting events took place during the Middle-Late Devonian. The paper presents paleotectonic reconstructions of East Siberia at several key time intervals.     

The Metric Impact of Reduction Optics in Digital Cameras

The recently released Nikon E2 still video camera incorporates reduction optics technology which enables a full conventional 35mm image to be recorded on a 2/3 inch (17mm) CCD array. This paper investigates the metric impact of reduction optics through application of the technique of multisensor system self-calibration. The influence of the JPEG image compression facility contained within the E2 is also assessed in an overall evaluation of the camera for vision metrology applications which demand relatively high object point triangulation accuracies.