Oxygen isotope fractionation factors between anhydrite and water from 100 to 550°C

Oxygen isotope exchange between anhydrite and water was studied from 100 to 550°C, using the partial equilibrium method. The exchange rate was extremely low in NaCl solution. In the lower-temperature range, acid solutions were used to produce sufficient reaction to determine the oxygen isotope fractionation factors. The fractionation factors obtained in the present study are definitely different from those given by Lloyd [8]. They are similar to those for the HSO₄^?-water system studied by Mizutani and Rafter [19], and are consistently 2‰ higher than those of the barite-water system by Kusakabe and Robinson [5]. The temperature dependence of the oxygen isotope fractionation factors was calculated by the least squares method in which the weight was taken to be inversely proportional to the experimental error. The fractionation is given by:10³lnαanhydrite-water=3.21×(10³/T)²?4.72Available δ¹⁸O values of natural anhydrite were used to test the validity of this expression. It is shown that this newly revised geothermometer can be successfully applied to natural hydrothermal anhydrite.     

New interpretation of the Franciscan mélange at San Simeon coast,California: tectonic intrusion into an accretionary prism

Many concepts and interpretations on the formation of the Franciscan mélange have been proposed on the basis of exposures at San Simeon, California. In this paper, we show the distribution of chaotic rocks, their internal structures and textures, and the interrelationship between the chaotic rocks and the surrounding sandstones (turbidites). Mélange components, particularly blueschists, oceanic rocks, including greenstone, pillow lava, bedded chert, limestone, sandstone, and conglomerate, have all been brecciated by retrograde deformation. The Cambria Slab, long interpreted as a trench slope basin, is also strongly deformed by fluidization, brecciation, isoclinal folding, and thrusting, leading us to a new interpretation that turbiditic rocks (including the Cambria Slab) represent trench deposits rather than slope basin sediments. These rocks form an accretionary prism above mélanges that were diapirically emplaced into these rocks first along sinistral-thrust faults, and then along dextral-normal faults. Riedel shear systems are observed in several orders of scale in both stages. Although the exhumation of the blueschist blocks is still controversial, the common extensional fractures and brecciation in most of the blocks in the mélanges and further mixture of various lithologies into one block with mélange muddy matrix indicate that once deeply buried blocks were exhumed from considerable depths to the accretionary prism body, before being diapirically intruded with their host mélange along thrust and normal faults, during which retrograde deformation occurred together with retrograde metamorphism. Recent similar examples of high-pressure rock exhumation have been documented along the Sofugan Tectonic Line in the Izu forearc areas, in the Mineoka belt in the Boso Peninsula, and as part of accretionary prism development in the Nankai and Sagami troughs of Japan. These modern analogues provide actively forming examples of the lithological and deformational features that characterize the Franciscan mélange processes.     

Street-scale storm surge load impact assessment using fine-resolution numerical modelling: a case study from Nemuro,Japan

Natural Hazards - Due to gradual sea level rise and changes in the climate system, coastal vulnerability to storm surge hazards is expected to increase in some areas. Studies regarding the effect...     

The Kellwasser events in the Upper Devonian Frasnian to Famennian transition in the Toc Tat Formation,northern Vietnam

Upper Devonian carbonates of the Toc Tat Formation in the Si Phai Pass area of Dong Van District, northern Vietnam were deposited in carbonate platform, slope, and basin environments. These carbonates yield abundant conodonts indicative of the Palmatolepis nasuta, Pa. linguiformis and Pa. triangularis zones, the Frasnian–Famennian stage boundary being identified by the first occurrence of Pa. triangularis. Two positive carbon isotope excursions are recognized, the lower excursion peaking in the interval of the lower to middle Pa. nasuta Zone, whilst the upper excursion peaks just above the local Frasnian–Famennian boundary. Based on the biostratigraphy, these excursions equate to the Lower and Upper Kellwasser events. Locally, tentaculitoid taxa (Nowakia, Styliolina, Homoctenus, and Metastyliolina?) are abundant in the interval of the Pa. nasuta Zone, but show a drastic decline in abundance before the Lower Kellwasser Event, and only two taxa survived into the Famennian.     

Out‐of‐plane stability of buckling‐restrained braces including moment transfer capacity

Buckling‐restrained braces (BRBs) are widely used as ductile seismic‐resistant and energy‐dissipating structural members in seismic regions. Although BRBs are expected to exhibit stable hysteresis under cyclic axial loading, one of the key limit states is global flexural buckling, which can produce an undesirable response. Many prior studies have indicated the possibility of global buckling of a BRB before its core yields owing to connection failure. In this paper, BRB stability concepts are presented, including their bending‐moment transfer capacity at restrainer ends for various connection stiffness values with initial out‐of‐plane drifts, and a unified simple equation set for ensuring BRB stability is proposed. Moreover, a series of cyclic loading tests with initial out‐of‐plane drifts are conducted, and the results are compared with those of the proposed equations. © 2013 The Authors. Earthquake Engineering & Structural Dynamics published by John Wiley & Sons Ltd.     

Volcanism in the Sumisu Rift, I. Major element, volatile, and stable isotope geochemistry

A bimodal volcanic suite with KAr ages of 0.05–1.40 Ma was collected from the Sumisu Rift using alvin. These rocks are contemporaneous with island arc tholeiite lavas of the Izu-Ogasawara arc 20 km to the east, and provide a present day example of volcanism associated with arc rifting and back-arc basin initiation. Major element geochemistry of the basalts is most similar to that of basalts found in other, more mature back-arc basins, which indicates that back-arc basins need not begin their magmatic evolution with lavas bearing strong arc signatures.Volatile concentrations distinguish Sumisu Rift basalts from island arc basalts and MORB. H₂O contents, which are at least four times greater than in MORB, suppress plagioclase crystallization. This suppression results in a more mafic fractionating assemblage, which prevents Al₂O₃ depletion and delays the initiation of Fe₂O_3^(tot) and TiO₂ enrichment. However, unlike arc basalts,Fe^3+/ΣFe ratios are only slightly higher than in MORB and are insufficient to cause magnetite saturation early enough to suppress Fe₂O_3^(tot) and TiO₂ enrichment. Thus, major element trends are more similar to those of MORB than arcs.H₂O, CO₂ and S are undersaturated relative to pure phase solubility curves, indicating exsolution of an H₂O-rich mixed gas phase. HighH₂O/S, highδD, and low (MORB-like)δ³⁴S ratios are considered primary and distinctive of the back-arc basin setting.     

Age determination of marine sediments in the western North Pacific by as partic acid chronology

The ages of fossil planktonic foraminifera,Pulleniatina obliquiloculata, in sediments (core 3bPC) from the western North Pacific were determined by aspartic acid chronology, which uses the racemization reaction rate constant of aspartic acid (k_Asp). Aspartic acid racemization-based ages (Asp ages) ranged from 7,600 yrBP at the surface, to 307,000 yrBP at a depth of 352.9 cm in the sediments. This sediment core was also dated by the glacial-interglacial fluctuation of δ¹⁸O chronology, and the ages determined by both chronologies were compared. The ages derived from aspartic acid chronology and δ¹⁸O stratigraphy were more or less consistent, but there appeared to be some differences in age estimates between these two dating methods at some depths within the core. In the core top sediments, the likely cause for the age discrepancy could be the loss of the surface sediment during sampling of the core. At depths of 66.3 and 139 cm within the core, Asp ages indicated reduced sedimentation rates duringca. 60,000-80,000 yrBP andca. 140,000–190,000 yrBP. The maximum age differences in both chronologies are 33,000 yr and 46,600 yr during each of these periods. These anomalous reductions in sedimentation rates occurring during these periods could possibly be related to some geological events, such as an increased dissolution effect of the calcium carbonate in the western North Pacific. Another possible reason for these age differences could be the unreliability in δ¹⁸O ages of core 3bPC as they were estimated by δ¹⁸O ages of another core, 3aPC.     

Methane in Izena Cauldron,Okinawa Trough

Methane in the deep water of Izena Cauldron (maximum depth: ca. 1650 m) at the east side of mid-Okinawa Trough was studied by casting a CTD system with 12 Niskin bottles for water sampling at 11 stations inside and outside the cauldron. The water contained much methane up to 706 nmoles/l. The depths of maximum concentration varied widely from station to station, indicating the existence of a considerable number of vents emitting methane and heat. The waters containing less methane formed a straight line in theT-S diagram, while those containing more methane were more largely deviated from the line. The temperature anomaly was virtually proportional to the methane concentration, suggesting that the oxidation rate of methane inside the cauldron is negligibly small and methane can be used as a tracer of the cauldron water. The relation and the estimated vertical diffusivity gave the following fluxes. The emissions of methane and heat out of the bottom below 1450 m turn out to be 1400 moles/day and 7×10¹⁰ cal/day, respectively. The total emission rates inside the cauldron are presumed to be about twice the above values. The turnover time of methane has been estimated to be 240 days, which is also that of heat generated from the bottom and probably that of the bottom water.     

High inorganic phosphate concentration in coral mucus and its utilization by heterotrophic bacteria in a Malaysian coral reef

Inorganic nutrient contents of mucus released by Acropora corals and its utilization by heterotrophic bacteria at several different hour intervals in the coral mucus were investigated at a coral reef in Malaysia. The dissolved inorganic phosphate (DIP) concentration was 135‐fold higher than in the ambient seawater, probably due to inorganic P release from the coral gut cavity. We experimentally confirmed that heterotrophic bacteria rapidly (within 8 h) consumed ca. 80% of the initial concentration of DIP derived from coral mucus. High DIP concentration in coral mucus may enhance heterotrophic bacterial production and associated carbon flow in the microbial loop of reef ecosystems.