Progressive metamorphism of the Taitao ophiolite; evidence for axial and off-axis hydrothermal alterations

We estimated metamorphic conditions for the  6 Ma Taitao ophiolite, associated with the Chile triple junction. The metamorphic grade of the ophiolite, estimated from secondary matrix minerals, changes stratigraphically downwards from the zeolite facies, through the prehnite–actinolite facies, greenschist facies and the greenschist–amphibolite transition, to the amphibolite facies. The metamorphic facies series corresponds to the low-pressure type. The metamorphic zone boundaries are subparallel to the internal lithological boundaries of the ophiolite, indicating that the metamorphism was due to axial hydrothermal alteration at a mid-ocean ridge.

Mineral assemblages and the compositions of veins systematically change from quartz-dominated, through epidote-dominated, to prehnite-dominated with increasing depth. Temperatures estimated from the vein assemblages range from  230 °C in the volcanic unit to  380 °C at the bottom of the gabbro unit, systematically  200 °C lower than estimates from the adjoining matrix minerals. The late development of veins and the systematically lower temperatures suggest that the vein-forming alteration was due to off-axis hydrothermal alteration.

Comparison between the Taitao ophiolite with its mid-ocean ridge (MOR) affinity, and other ophiolites and MOR crusts, suggests that the Taitao ophiolite has many hydrothermal alteration features similar to those of MOR crusts. This is consistent with the tectonic history that the Taitao ophiolite was formed at the South Chile ridge system near the South American continent (Anma, R., Armstrong, R., Danhara, T., Orihashi, Y. and Iwano, H., 2006. Zircon sensitive high mass-resolution ion microprobe U–Pb and fission-track ages for gabbros and sheeted dykes of the Taitao ophiolite, Southern Chile, and their tectonic implications. The Island Arc, 15(1): 130–142).     

Detection and Evaluation of Gas Hydrates in the Eastern Nankai Trough by Geochemical and Geophysical Methods

Abstract: Interstitial waters extracted from the sediment cores from the exploration wells, “BH‐1” and “MITI Nankai Trough”, drilled ～60 km off Omaezaki Peninsula in the eastern Nankai Trough, were analyzed for the chloride and sulfate concentrations to examine the depth profiles and occurrence of subsurface gas hydrates. Cored intervals from the seafloor to 310 mbsf were divided into Unit 1 (～70 mbsf, predominated by mud), Unit 2 (70–150 mbsf, mud with thin ash beds), Unit 3 (150–250+ mbsf, mud with thin ash and sand), and Unit 4 (275–310 mbsf, predominated by mud). The baseline level for Cl “concentrations was 540 mM, whereas low chloride anomalies (103 to 223 mM) were identified at around 207 mbsf (zone A), 234–240 mbsf (zone B), and 258–265 mbsf (zone C) in Unit 3. Gas hydrate saturation (Sh %) of sediment pores was calculated to be 60 % (zone A) to 80 % (zones B and C) in sands whereas only a few percent in clay and silt. The total amount of gas hydrates in hydrate‐bearing sands was estimated to be 8 to 10 m³ of solid gas hydrate per m², or 1.48 km³ CH₄ per 1 km². High saturation zones (A, B and C) were consistent with anomaly zones recognized in sonic and resistivity logs. 2D and high‐resolution seismic studies revealed two BSRs in the study area. Strong BSRs (BSR‐1) at ～263 mbsf were correlated to the boundary between gas hydrate‐bearing sands (zone C) and the shallower low velocity zone, while the lower BSRs (BSR‐2) at～289 mbsf corresponded to the top of the deeper low velocity zone of the sonic log. Tectonic uplift of the study area is thought to have caused the upward migration of BGHS. That is, BSR‐1 corresponds to the new BGHS and BSR‐2 to the old BGHS. Relic gas hydrates and free gas may survive in the interval between BSR‐1 and BSR‐2, and below BSR‐2, respectively. Direct measurements of the formation temperature for the top 170 m interval yield a geothermal gradient of ～4.3d?C/ 100 m. Extrapolation of this gradient down to the base of gas hydrate stability yields a theoretical BGHS at～230 mbsf, surprisingly ～35 m shallower than the base of gas hydrate‐bearing sands (zone C) and BSR‐1. As with the double BSRs, another tectonic uplift may explain the BGHS at unreasonably shallow depths. Alternatively, linear extrapolation of the geothermal gradient down to the hydrate‐bearing zones may not be appropriate if the gradient changes below the depths that were measured. Recognition of double BSRs (263 and 289 mbsf) and probable new BGHS (～230 mbsf) in the exploration wells implies that the BGHS has gradually migrated upward. Tectonically induced processes are thought to have enhanced dense and massive accumulation of gas hydrate deposits through effective methane recycling and condensation. To test the hypothetical models for the accumulation of gas hydrates in Nankai accretionary prism, we strongly propose to measure the equilibrium temperatures for the entire depth range down to the free gas zone below predicted BGHS and to reconstruct the water depths and uplift history of hydrate‐bearing area.     

Fission–track Ages and Magnetic Susceptibility of Cretaceous to Paleogene Volcanic Rocks in Southeastern Sikhote Alin, Far East Russia

Abstract: Seven zircon fission-track ages and 30 magnetic susceptibilities were measured on welded pyroclastic rocks from the Bogopol and Sijanov Groups of the Cretaceous to Paleogene volcanic rocks in the southeastern part of the eastern Sikhote Alin volcano-plutonic belt, Far East Russia. The fission-track ages range from 42. 7 Ma to 64. O Ma which indicate that both the groups are of Early Paleogene time. Two thirds of the samples from the Bogopol Group have high magnetic susceptibility values, more than 3 A- 10^-3 SI unit, which imply that they are of the magnetite–series, whereas the samples from the Sijanov Group show 3 A- 10^-3 to 8 A- 10^-5 SI unit which suggest this group of probably the ilmenite-series.
The Paleogene age and high magnetic susceptibility of the Bogopol Group are quite similar to the Paleogene igneous rocks of the San'in belt, Southwest Japan. This suggests, taking accounts of the opening of the Japan Sea, that the eastern Sikhote Alin volcano-plutonic belt continued to the San'in Belt, and that the Paleogene igneous rocks along the Japan Sea coast of Northeast Japan were situated along the volcanic front of the eastern Sikhote Alin volcano-plutonic belt.     

Genesis and Mixing/Mingling of Mafic and Felsic Magmas of Back-Arc Granite: Miocene Tsushima Pluton, Southwest Japan

The Middle Miocene Tsushima granite pluton is composed of leucocratic granites, gray granites and numerous mafic microgranular enclaves (MME). The granites have a metaluminous to slightly peraluminous composition and belong to the calc‐alkaline series, as do many other coeval granites of southwestern Japan, all of which formed in relation to the opening of the Sea of Japan. The Tsushima granites are unique in that they occur in the back‐arc area of the innermost Inner Zone of Southwest Japan, contain numerous miarolitic cavities, and show shallow crystallization (2–6 km deep), based on hornblende geobarometry. The leucocratic granite has higher initial ⁸⁷Sr/⁸⁶Sr ratios (0.7065–0.7085) and lower ε_Nd(t) (?7.70 to ?4.35) than the MME of basaltic–dacitic composition (0.7044–0.7061 and ?0.53 to ?5.24), whereas most gray granites have intermediate chemical and Sr–Nd isotopic compositions (0.7061–0.7072 and ?3.75 to ?6.17). Field, petrological, and geochemical data demonstrate that the Tsushima granites formed by the mingling and mixing of mafic and felsic magmas. The Sr–Nd–Pb isotope data strongly suggest that the mafic magma was derived from two mantle components with depleted mantle material and enriched mantle I (EMI) compositions, whereas the felsic magma formed by mixing of upper mantle magma of EMI composition with metabasic rocks in the overlying lower crust. Element data points deviating from the simple mixing line of the two magmas may indicate fractional crystallization of the felsic magma or chemical modification by hydrothermal fluid. The miarolitic cavities and enrichment of alkali elements in the MME suggest rapid cooling of the mingled magma accompanied by elemental transport by hydrothermal fluid. The inferred genesis of this magma–fluid system is as follows: (i) the mafic and felsic magmas were generated in the mantle and lower crust, respectively, by a large heat supply and pressure decrease under back‐arc conditions induced by mantle upwelling and crustal thinning; (ii) they mingled and crystallized rapidly at shallow depths in the upper crust without interaction during the ascent of the magmas from the middle to the upper crust, which (iii) led to fluid generation in the shallow crust. The upper mantle in southwest Japan thus has an EMI‐like composition, which plays an important role in the genesis of igneous rocks there.     

Kinematic analysis of ultrahigh-pressure–high-pressure metamorphic rocks in the Chaglinka–Kulet area of the Kokchetav Massif, Kazakhstan

Abstract The central part of the Kokchetav Massif is exposed in the Chaglinka–Kulet area, northern Kazakhstan. The ultrahigh-pressure–high-pressure (UHP–HP) metamorphic belt in this area is composed of four subhorizontal lithological units (Unit I–IV) metamorphosed under different pressure–temperature (P–T) conditions. The coesite- and diamond-bearing Unit II, which consists mainly of whiteschist and eclogite blocks, is tectonically sandwiched between the amphibolite-dominant Unit I on the bottom and the orthogneiss-dominant Unit III on the top. Total combined thickness of these units is less than 2 km. The rocks of the UHP–HP metamorphic belt are affected by at least four deformational events post-dating peak metamorphism: (i) The earliest penetrative deformation is characterized by non-coaxial ductile flow in a NW–SE direction. The shear sense indicators in oriented samples from Unit I provide consistent top-to-the-northwest motions and those from Unit III provide top-to-the-southeast, south or south-west motions; (ii) Upright folds with subhorizontal enveloping surface refold earlier foliations including shear-indicators throughout the metamorphic belt; (iii) The third stage of deformation is denoted by large-scale bending around a subvertical axis; and (iv) Late localized fault (or shear) zones cut all earlier structures. The fault zones have subvertical shear planes and their displacements are essentially strike-slip in manner. The subhorizontal structure and opposite shear directions between Unit I and Unit III during the earlier deformation stage suggest north-westward extrusion of UHP Unit II.     

Persistent organochlorine residues in green mussels from coastal waters of South India

Green mussels (Perna viridis) collected from nine locations along the South Indian coast were used as bioindicator to assess the organochlorine contamination (HCHs, DDTs, and PCBs) in the coastal environment of South India. Concentrations of ΣHCH and ΣDDT were found to be similar, ranging from 3 to 39 ng g⁻¹ on wet wt basis. On the other hand, PCB levels were apparently lower, varying from <1.0 to 7.1 ng g⁻¹ wet wt. The residue pattern of organochlorines in mussels are principally similar to those in Indian human samples, reported earlier. The coastal marine pollution by HCH in India ranks among the highly contaminated areas in the world.     

Alkalinization and acidification of stream water with changes in atmospheric deposition in a tropical dry evergreen forest of northeastern Thailand

Field surveys on atmospheric deposition and stream water chemistry were conducted in an evergreen forest in northeastern Thailand characterized by a tropical savanna climate with distinct dry and wet seasons. Atmospheric deposition of ion constituents by throughfall and stemflow was shown to increase in the beginning and end of the wet season, reflecting the precipitation pattern. The pH and electrical conductivity of stream water increased with alkalinity and base cation concentrations due to mineralization of organic matter by the first rain and retention of anions in soil during the start of the wet season. After initial alkalinization, the pH and alkalinity declined rapidly with the highest SO₄^2? concentration displayed in the middle towards the end of the wet season. The magnitude of peaks in SO₄^2? concentration (13.5–60.6 μmol_c/L) reflects deposition during the first 2 months of the wet season (March and April) in respective years (60.8–170 mol_c/ha). Release of SO₄^2? with H⁺, which is retained in soil during the early wet season, may cause acidification later in the season. The deposition and concentration of SO₄^2? declined over 6 years. However, the pH of stream water declined with increasing concentrations of SO₄^2? and other major ions. The release of materials accumulated in the ecosystem was facilitated by the decrease in SO₄^2? concentration/deposition and increased precipitation in the middle–late wet season. The retention‐release cycle of SO₄^2? largely contributed to both seasonal and interannual variations in stream water chemistry in the tropical savanna climate studied.     

Transport process of sand grains from fluvial to deep marine regions estimated by luminescence of feldspar: example from the Kumano area,central Japan

Using the concept of bleaching in optical dating, a new index of sediment sample bleaching percentage (BLP‐2) was developed and applied to evaluate sand grain transport from riverine to deep‐marine environments. As bleached grains in modern sediments have no optically stimulated luminescence (OSL)/infrared stimulated luminescence (IRSL) signal, bleached and unbleached feldspar grains are distinguished by IRSL intensity. The BLP‐2 distribution of present deposits around the Kumano area, on the Pacific coast of central Japan, suggests that sand grains in surface turbidites obtained from the bottom of the Kumano Trough are of flood/storm origin rather than seismogenic origin. The distribution of BLP‐2 tentatively suggests sand grain erosion–transport–depositional processes; for example, origin and transport agencies of shelf sand, and influence of coastal erosion on the beach deposit. Although the present BLP analysis is not yet supported by a rigorous statistical test, it is useful to distinguish recent deposition and remobilization of sand grains. Furthermore, if the depositional age and the luminescence age of sand grains are accurately estimated, sand grain transport processes of old (late Quaternary) sediments may be estimated by the methodology similar to that of the present study.     

Chronological and paleoceanographic constraints of Miocene to Pliocene ‘mud sea’ in the Ryukyu Islands (southwestern Japan) based on calcareous nannofossil assemblages

The Cenozoic sedimentary succession in Okinawa‐jima, including the upper Miocene to Pleistocene siliciclastic deposits (Shimajiri Group) and the Pleistocene reef to shelf deposits (Ryukyu Group), suggests a drastic paleoceanographic change from a ‘mud sea’ to a ‘coral sea.’ To delineate the paleoceanographic evolution of the mud sea, we quantified the stratigraphic distribution of the calcareous nannofossil assemblages from the Shimajiri Group in a 2119.49 m‐deep well (Nanjo R1 Exploratory Well) drilled in southern Okinawa‐jima (Ryukyu Islands, southwestern Japan). Four late Miocene and Pliocene datum planes were found in the studied interval: the first occurrence of Amaurolithus spp. (7.42 Ma), the last occurrence of Discoaster quinqueramus (5.59 Ma), the first occurrence of Ceratolithus rugosus (5.12 Ma), and the last occurrence of Reticulofenestra pseudoumbilicus (3.70 Ma). The calcareous nannofossil assemblages from the Tomigusuku Formation and the lower part of the Yonabaru Formation are characterized by a lower total number of coccoliths and abundant Sphenolithus abies that is associated, at times, with common Discoaster spp. Overall, these suggest the existence of oligotrophic conditions between 5.3 and >8.3 Ma. The total number of coccoliths increased and small Reticulofenestra spp. became more common in the middle part of the Yonabaru Formation, suggesting that eutrophic conditions were present between 3.5 and 5.3 Ma. The rare occurrence of calcareous nannofossils in the upper part of the Yonabaru Formation indicates a return to oligotrophic conditions at 3.5 Ma. Micropaleontological evidence suggests that these oceanographic changes were likely caused by local tectonic movement (shallowing of the sedimentary basin in which the Shimajiri Group was deposited).     

Stratigraphic records of tsunamis along the Japan Sea,southwest Hokkaido,northern Japan

The stratigraphy of tsunami deposits along the Japan Sea, southwest Hokkaido, northern Japan, reveals tsunami recurrences in this particular area. Sandy tsunami deposits are preserved in small valley plains, whereas gravelly deposits of possible tsunami origin are identified in surficial soils covering a Holocene marine terrace and a slope talus. At least five horizons of tsunami events can be defined in the Okushiri Island, the youngest of which immediately overlies the Ko‐d tephra layer (1640 AD) and was likely formed by the historical Oshima‐Ohshima tsunami in 1741 AD. The four older tsunami deposits, dated using accelerator mass spectrometry ¹⁴C, were formed at around the 12th century, 1.5–1.6, 2.4–2.6, and 2.8–3.1 ka, respectively. Tsunami sand beds of the 1741 AD and circa 12th century events are recognized in the Hiyama District of Hokkaido Island, but the older tsunami deposits are missing. The deposits of these two tsunamis are found together at the same sites and distributed in regions where wave heights of the 1993 tsunami (Hokkaido Nansei‐oki earthquake, Mw = 7.7) were less than 3 m. Thus, the 12th century tsunami waves were possibly generated near the south of Okushiri Island, whereas the 1993 tsunami was generated towards the north of the island. The estimated recurrence intervals of paleotsunamis, 200–1100 years with an average of 500 years, likely represents the recurrence interval of large earthquakes which would have occurred along several active faults offshore of southwest Hokkaido.