Halogen systematics in the Mallik 5L-38 gas hydrate production research well,Northwest Territories,Canada: Implications for the origin of gas hydrates under terrestrial permafrost conditions

The authors report here halogen concentrations in pore waters and sediments collected from the Mallik 5L-38 gas hydrate production research well, a permafrost location in the Mackenzie Delta, Northwest Territories, Canada. Iodine and Br are commonly enriched in waters associated with CH₄, reflecting the close association between these halogens and source organic materials. Pore waters collected from the Mallik well show I enrichment, by one order of magnitude above that of seawater, particularly in sandy layers below the gas hydrate stability zone (GHSZ). Although Cl and Br concentrations increase with depth similar to the I profile, they remain below seawater values. The increase in I concentrations observed below the GHSZ suggests that I-rich fluids responsible for the accumulation of CH₄ in gas hydrates are preferentially transported through the sandy permeable layers below the GHSZ. The Br and I concentrations and I/Br ratios in Mallik are considerably lower than those in marine gas hydrate locations, demonstrating a terrestrial nature for the organic materials responsible for the CH₄ at the Mallik site. Halogen systematics in Mallik suggest that they are the result of mixing between seawater, freshwater and an I-rich source fluid. The comparison between I/Br ratios in pore waters and sediments speaks against the origin of the source fluids within the host formations of gas hydrates, a finding compatible with the results from a limited set of ¹²⁹I/I ratios determined in pore waters, which gives a minimum age of 29 Ma for the source material, i.e. at the lower end of the age range of the host formations. The likely scenario for the gas hydrate formation in Mallik is the derivation of CH₄ together with I from the terrestrial source materials in formations other than the host layers through sandy permeable layers into the present gas hydrate zones.     

Geochemical Process of Gas Hydrate Formation in the Nankai Trough Based on Chloride and Isotopic Anomalies in Interstitial Water

Abstract: Interstitial water expelled from gas hydrate-bearing and -free sediments in the Nankai Trough are analyzed in terms of Cl-, SO₄²-, δ¹⁸O and δD. The baselines for the Cl- concentration and δ¹⁸O value are close to seawater values (530 mM and 0%), indicating that the interstitial water is of seawater origin. The δD values decrease with depth, implying isotopic exchange of hydrogen between upwelling biogenic methane depleted in D and interstitial water. The Cl- concentrations in gas hydrate-bearing sediments are anomalously low, while the δ¹⁸O and δD values are both high, suggesting that the water forming these gas hydrates was poor in Cl- and enriched in ¹⁸O and D during gas hydrate formation. Calculation of the gas hydrate saturations using Cl "and δ¹⁸O anomalies gives results of up to 80 % in sand, and shows that the δ¹⁸O baseline is not consistent with the Cl" baseline. The δ¹⁸O baseline increases by +1% in gas hydrate-free clay and silt. This is considered to be caused by clustering of water molecules after gas hydrate dissociation in response to the upward migration of the base of gas hydrate stability, as indicated by the presence of a double bottom-simulating reflector at this site. The water clusters enriched in ¹⁸O are responsible for the increase in the δ¹⁸O baseline with normal Cl". The abrupt shallowing of the base of gas hydrate stability may induce the dissociation of gas hydrates and the accumulation of gases in the new stability zone, representing a geological process that increases gas hydrate saturation.     

Preface

Editorial Board for the Special Issue on "Gas Hydrate in Nankai Trough, Japan"
Takashi U chida (JAPEX Research Center, Japan Petroleum Exploration Co., Ltd.), Amane W aseda (JAPEX Research Center, Japan Petroleum Exploration Co., Ltd.), Naotatsu S hikazono (Department of Applied Chemistry, Keio University), Yutaka A oki (JGI Inc.) and Yoshihiro T suji (Technology Research Center, Japan Oil,
Gas and Metals National Corporation)     

Geochemical Features of Vein Anhydrite from the Kakkonda Geothermal System, Northeast Japan

Abstract. Cathodoluminescence (CL) color, rare earth element (REE) content, sulfur and oxygen isotopes and fluid inclusions of anhydrite, which frequently filled in hydrothermal veins in the Kakkonda geothermal system, were investigated to elucidate the spatial, temporal and genetical evolution of fluids in the deep reservoir. The anhydrite samples studied are classified into four types based on CL colors and REE contents: type-N (no color), type-G (green color), type-T (tan color) and type-S (tan color with a high REE content). In the shallow reservoir, only type-N anhydrite is observed. In the deep reservoir, type-G anhydrite occurs in vertical veins whereas type-T and -N in lateral veins. Type-S anhydrite occurs in the heat-source Kakkonda Granite. The CL textures revealed that type-G anhydrite deposited earlier than type-T in the deep reservoir, implying that fracture system was changed from predominantly vertical to lateral.
Studies of fluid inclusions and δ³⁴S and δ¹⁸O values of the samples indicate that type-N anhydrite deposited from diluted fluids derived from meteoric water, whereas type-G, -T and -S anhydrites deposited from magmatic brines derived from the Kakkonda Granite with the exception of some of type-G with recrystallization texture and no primary fluid inclusion, which deposited from fossil seawater preserved in the sedimentary rocks. Type-G, -T and -S anhydrites exhibit remarkably different chondrite-normalized REE patterns with a positive Eu anomaly, with a convex shape (peak at Sm or Eu) and with a negative Eu anomaly, respectively. The difference in the patterns might result from the different extent of hydrothermal alteration of the reservoir rocks and contribution of the magmatic fluids.     

Large-Eddy Simulation of Turbulent Organized Structures within and above Explicitly Resolved Cube Arrays

Large-eddy simulations have been performed for fully developed turbulent flow within and above explicitly resolved simple cube arrays. The results from our model, hereafter LES-CITY, are shown to agree with laboratory experiments. We investigated the systematic influence of cube density on turbulent flow characteristics by performing numerical experiments for cube areal densities from 0 to 44%. The following results were obtained: (1) The dispersive momentum flux was quite large within the canopy layer due to a mean stream re-circulation, whereas it was smaller above the canopy. The spatial variation of temporally averaged momentum in the roughness sub-layer was 20% or less of the total kinematic surface drag. (2) The temporally and spatially-averaged flow structure confirmed the existence of conventionally described canyon flow regimes; isolated, interfacial, and wake. However, the intermittency of the canyon flow for all cube densities was quite large and the stream patterns were never persistent. (3) Turbulent organized structures (TOS) similar to those observed in turbulent surface-layer flows were simulated, which are characterized by longitudinally-elongated low speed streaks and the corresponding shorter streamwise vortices. The streaks in sparse and dense canopy flows were likely to be aligned to the street line and to the roof lines, respectively. Such heterogeneity of TOS partially accounts for the large spatial variation of momentum flux. (4) In contrast to the mixing layer analogy of vegetation flows, the TOS and the resulting turbulent statistics of urban flow above the canopy resembled those in surface layers. The recirculation within the canopy significantly influenced the turbulent statistical properties.     

Ethnic groups’ response to the 26 December 2004 earthquake and tsunami in Aceh, Indonesia

The 26 December 2004 earthquake and tsunami unfairly hit the different ethnic groups of Aceh, Indonesia. About 170,000 Acehnese and Minangkabau people died in the Northern tip of Sumatra while only 44 Simeulue people passed away in the neighbouring Simeulue island located near the earthquake epicentre. Such a difference in the death toll does not lie in the nature of the hazard but in different human behaviours and ethnic contexts. The present study draws on a contextual framework of analysis where people’s behaviour in the face of natural hazards is deeply influenced by the cultural, social, economic and political context. Questionnaire-based surveys among affected communities, key informant interviews and literature reviews show that the people of Simeulue detected the tsunami very early and then escaped to the mountains. On the other hand, Acehnese and Minangkabau people, respectively in the cities of Banda Aceh and Meulaboh, did not anticipate the phenomenon and were thus caught by the waves. The different behaviours of the victims have been commanded by the existence or the absence of a disaster subculture among affected communities as well as by their capacity to protect themselves in facing the tsunami. People’s behaviours and the capacity to protect oneself can be further tracked down to a deep tangle of intricate factors which include the armed conflict that has been affecting the province since the 1970s, the historical and cultural heritage and the national political economy system. This paper finally argues that the uneven impact of the 26 December 2004 earthquake and tsunami in Aceh lies in the different daily life conditions of the ethnic groups struck by the disaster.