Exoplanet atmospheres with EChO: spectral retrievals using EChOSim

We demonstrate the effectiveness of the Exoplanet Characterisation Observatory mission concept for constraining the atmospheric properties of hot and warm gas giants and super Earths. Synthetic primary and secondary transit spectra for a range of planets are passed through EChOSim [13] to obtain the expected level of noise for different observational scenarios; these are then used as inputs for the NEMESIS atmospheric retrieval code and the retrieved atmospheric properties (temperature structure, composition and cloud properties) compared with the known input values, following the method of [1]. To correctly retrieve the temperature structure and composition of the atmosphere to within 2 σ, we find that we require: a single transit or eclipse of a hot Jupiter orbiting a sun-like (G2) star at 35 pc to constrain the terminator and dayside atmospheres; 20 transits or eclipses of a warm Jupiter orbiting a similar star; 10 transits/eclipses of a hot Neptune orbiting an M dwarf at 6 pc; and 30 transits or eclipses of a GJ1214b-like planet.     

The Compatibility of Flare Temperatures Observed with AIA,GOES, and RHESSI

We test the compatibility and biases of multi-thermal flare DEM (differential emission measure) peak temperatures determined with AIA with those determined by GOES and RHESSI using the isothermal assumption. In a set of 149 M- and X-class flares observed during the first two years of the SDO mission, AIA finds DEM peak temperatures at the time of the peak GOES 1?–?8 Å flux to have an average of T _p=12.0±2.9 MK and Gaussian DEM widths of log₁₀(σ _T )=0.50±0.13. From GOES observations of the same 149 events, a mean temperature of T _p=15.6±2.4 MK is inferred, which is systematically higher by a factor of T _GOES/T _AIA=1.4±0.4. We demonstrate that this discrepancy results from the isothermal assumption in the inversion of the GOES filter ratio. From isothermal fits to photon spectra at energies of ?≈6?–?12 keV of 61 of these events, RHESSI finds the temperature to be higher still by a factor of T _RHESSI/T _AIA=1.9±1.0. We find that this is partly a consequence of the isothermal assumption. However, RHESSI is not sensitive to the low-temperature range of the DEM peak, and thus RHESSI samples only the high-temperature tail of the DEM function. This can also contribute to the discrepancy between AIA and RHESSI temperatures. The higher flare temperatures found by GOES and RHESSI imply correspondingly lower emission measures. We conclude that self-consistent flare DEM temperatures and emission measures require simultaneous fitting of EUV (AIA) and soft X-ray (GOES and RHESSI) fluxes.     

Residence of trace elements in metasomatized spinel lherzolite xenoliths: a proton-microprobe study

Minerals occurring in dry and modally metasomatized spinel lherzolites from western Victoria have been analysed by proton microprobe for Ni, Cu, Zn, Ga, Rb, Sr, Y, Zr, Nb, Ba, Pb, Br, rare-earth elements (REE), Th and U. Mass-balance calculations demonstrate that these trace elements are contained in specific acceptor minerals and do not occur in significant concentrations at clean grain boundaries. The level of particular trace elements in the rock depends on the presence of specific phases: for example high levels of REE, Sr (and U, Th, Br) require apatite, while Ba, Nb and Ta are strongly concentrated in amphibole±mica. Mantle metasomatism in these spinel lherzolites is inferred to result from an open-system process involving infiltration of fluids released by crystallizing silicate melts. This process produces metasomatic zones with different modal mineralogy and hence greatly different trace-element signatures. The data demonstrate that large-ion-lithophile (LIL) and high-field strength (HFS) elements in metasomatized spinel lherzolites are strongly concentrated in non-refractory phases, which will break down easily in heated volumes such as the walls of magma conduits. The heterogeneity observed in trace-element patterns of intraplate alkali basaltic rocks may not reflect source heterogeneity, but may result largely from contamination by metasomatized mantle wall rock. The K_Ds for most trace elements show little temperature dependence except for K_DSr between orthopyroxene and clinopyroxene where K_D decreases with increasing temperature. The generally uniform K_Ds can be used to test for disequilibrium in such assemblages.     

Preparation and Measurement of Cassiterite for Sn Isotope Analysis

Increased interest in the fractionation of Sn isotopes has led to the development of several techniques for preparing cassiterite (SnO₂, the primary ore of Sn) for isotopic analysis. Two distinct methods have been applied in recent isotopic studies of cassiterite: (a) reduction to tin metal with potassium cyanide (KCN) at high temperature (800 °C), with subsequent dissolution in HCl, and (b) reduction to a Sn solution with hydriodic acid (HI) at low temperature (100 °C). This study compares the effectiveness and accuracy of these two methods and contributes additional methodological details. The KCN method consistently yielded more Sn (> 70% in comparison with < 5%), does not appear to fractionate Sn isotopes at high temperatures over a 2‐hour period and produced consistent Sn isotope values at flux mass ratios of ≥ 4:1 (flux to mineral) with a minimum reduction time of 40 min. By means of a distillation experiment, it was demonstrated that HI could volatilise Sn, explaining the consistently low yields by this method. Furthermore, the distillation generated Sn vapour, which is up to 0.38‰ per mass unit different from the starting material, the largest induced Sn fractionation reported to date. Accordingly, the HI method is not recommended for cassiterite preparation for Sn isotopic analysis.     

Channel response to a dam-removal sediment pulse captured at high-temporal resolution using routine gage data

In this study, we captured how a river channel responds to a sediment pulse originating from a dam removal using multiple lines of evidence derived from streamflow gages along the Patapsco River, Maryland, USA. Gages captured characteristics of the sediment pulse, including travel times of its leading edge (~7.8 km yr⁻¹) and peak (~2.6 km yr⁻¹) and suggest both translation and increasing dispersion. The pulse also changed local hydraulics and energy conditions, increasing flow velocities and Froude number, due to bed fining, homogenization and/or slope adjustment. Immediately downstream of the dam, recovery to pre-pulse conditions occurred within the year, but farther downstream recovery was slower, with the tail of the sediment pulse working through the lower river by the end of the study 7 years later. The patterns and timing of channel change associated with the sediment pulse were not driven by large flow or suspended sediment-transporting events, with change mostly occurring during lower flows. This suggests pulse mobility was controlled by process-factors largely independent of high flow. In contrast, persistent changes occurred to out-of-channel flooding dynamics. Stage associated with flooding increased during the arrival of the sediment pulse, 1 to 2 years after dam removal, suggesting persistent sediment deposition at the channel margins and nearby floodplain. This resulted in National Weather Service-indicated flood stages being attained by 3–43% smaller discharges compared to earlier in the study period. This study captured a two-signal response from the sediment pulse: (1) short- to medium-term (weeks to months) translation and dispersion within the channel, resulting in aggradation and recovery of bed elevations and changing local hydraulics; and (2) dispersion and persistent longer-term (years) effects of sediment deposition on overbank surfaces. This study further demonstrated the utility of US Geological Survey gage data to quantify geomorphic change, increase temporal resolution, and provide insights into trajectories of change over varying spatial and temporal scales.     

Interannual variability of water ice clouds over major martian volcanoes observed by MOC

Using Mars Global Surveyor Mars Orbiter Camera daily global maps, cloud areas have been measured daily for water ice clouds associated with the topography of the major volcanoes Olympus Mons, Ascraeus Mons, Pavonis Mons, Arsia Mons, Elysium Mons, and Alba Patera. This study expands on that of Benson et al. [Benson, J.L., Bonev, B.P., James, P.B., Shan, K.J., Cantor, B.A., Caplinger, M.A., 2003. Icarus 165, 34-52] by continuing their cloud area measurements of the Tharsis volcanoes, Olympus Mons and Alba Patera for an additional martian year (August 2001-May 2003) and by also including Elysium Mons measurements from March 1999 through May 2003. The seasonal trends in cloud activity established by Benson et al. [Benson, J.L., Bonev, B.P., James, P.B., Shan, K.J., Cantor, B.A., Caplinger, M.A., 2003. Icarus 165, 34-52] for the five volcanoes studied earlier are corroborated here with an additional year of coverage. For volcanoes other than Arsia Mons, interannual variations that could be associated with the large 2001 planet encircling dust storm are minimal. At Arsia Mons, where cloud activity was continuous in the first two years, clouds disappeared totally for ∼85° of LS (LS=188°-275°) due to the dust storm. Elysium Mons cloud activity is similar to that of Olympus Mons, however the peak in cloud area is near LS=130° rather than near LS=100°.     

Geological controls on refractory ore in an orogenic gold deposit, Macraes mine, New Zealand

The Macraes mine is hosted in an orogenic (mesothermal) gold deposit in metasedimentary rocks of the Otago Schist belt. Much gold occurs within altered schist with minimal silica-addition, and this study focuses on altered schist ore types. The unmineralized host schists are chemically and mineralogically uniform in composition, but include two end-member rock types: feldspathic schist and micaceous schist. Both rock types have undergone hydrothermal alteration along a shallow-dipping foliation-parallel shear zone, but their different rheological properties have affected the style of mineralisation. Micaceous schist has been extensively recrystallized and hydrothermally altered during ductile deformation, to form ores characterized by abundant, disseminated millimetre-scale pyrite cubes (typically 1–2 wt% S) and minor silicification. The earliest pyrite contained Ni and/or As in solid solution and no gold was imaged in these pyrites or later arsenopyrite grains. The ore type is refractory and gold recovery by cyanide leaching is less than 50%, with lowest recovery in rocks that have been less affected by later brittle deformation. In contrast, hydrothermally altered feldspathic schist is characterized by mineralised black microshears and veinlets formed during shear-zone related brittle deformation. Microsheared ore has relatively low sulphur content (<0.7 wt%) and muscovite has been illitised during hydrothermal alteration. Pyrite and arsenopyrite in microshears are fractured and deformed, and contain 1–10 m blebs of gold. Later pyrite veinlets also contain micron- to submicron-scale inclusions of sphalerite, chalcopyrite, galena, and gold (10 microns). Gold in microsheared ore is more readily recoverable than in the refractory ore, although encapsulation of the fine gold grains inhibits cyanidation. Both microsheared ore and disseminated pyritic ore pass laterally into mineralised black shears, which contain hydrothermal graphite and late-stage cataclastic sulphides. This black, sheared ore releases gold readily, but the gold is then adsorbed on to gangue minerals (preg-robbed) and net cyanidation recovery can be less than 50%. Hence, low gold recovery during cyanidation results from (1) poor liberation of gold encapsulated in microcrystalline quartz and unfractured sulphide grains, and (2) preg-robbing of liberated gold during cyanidation. Introduction of pressure-oxidation of ore prior to cynidation has mitigated these issues.