Sea level response to ENSO along the central California coast: how the 1997–1998 event compares with the historic record

Long-term monthly sea level and sea surface temperature (SST) anomalies from central California show that during winter months, positive anomalies are associated with El Niño events and the negative ones with La Niña events. There is no significant impact on monthly mean anomalies associated with Pacific decadal oscillations, although there is a tendency for more extreme events and greater variance during positive decadal oscillations. The very strong 1997–1998 El Niño was analyzed with respect to the long-term historic record to assess the forcing mechanisms for sea level and SST. Beginning in the spring of 1997, we observed several long-period (>30 days) fluctuations in daily sea level with amplitudes of over 10 cm at San Francisco, California. Fluctuations of poleward long-period alongshore wind stress anomalies (AWSA) are coherent with the sea level anomalies. However, the wind stress cannot entirely account for the observed sea level signals. The sea level fluctuations are also correlated with sea level fluctuations observed further south at Los Angeles and Tumaco, Columbia, which showed a poleward phase propagation of the sea level signal. We suggest that the sea level fluctuations were, to a greater degree, forced by the passage of remotely generated and coastally trapped waves that were generated along the equator and propagated to the north along the west coast of North America. However, both local and remote AWSA can significantly modulate the sea level signals. The arrival of coastally trapped waves began in the spring of 1997, which is earlier than previous strong El Niño events such as the 1982–1983 event.     

Accretion,structure and hydrology of intermediate spreading-rate oceanic crust from drillhole experiments and seafloor observations

Downhole measurements recorded in the context of the Ocean Drilling Program in Hole 504B, the deepest hole drilled yet into the oceanic crust, are analyzed in terms of accretion processes of the upper oceanic crust at intermediate spreading-rate. The upper part of the crust is found to support the non steady-state models of crustal accretion developed from seafloor observations (Kappel and Ryan, 1986; Gente, 1987). The continuous and vertical nature of borehole measurements provides stratigraphic and structural data that cannot be obtained solely from seafloor studies and, in turn, these models define a framework to analyze the structural, hydrological, and mineralogical observations made in the hole over the past decade.Due to the observed zonation with depth of alteration processes, and its relation to lava morphologies, the 650-m-thick effusive section penetrated in Hole 504B is postulated to be emplaced as the result of two main volcanic sequences. Massive lava flows are interpreted as corresponding to the onset of these sequences emplaced on the floor of the axial graben. The underlying lava made of structures with large porosity values and numerous cm-scale fractures is thus necessarily accreted at the end of the previous volcanic episode. On top of such high heterogeneous and porous intervals, the thick lava flows constitute crustal permeability barriers, thereby constraining the circulation of hydrothermal fluids.Accreted in the near vicinity of the magma chamber, the lower section is that exposed to the most intense hydrothermal circulation (such as black smokers activity). Once capped by a massive flow at the onset of the second volcanic phase, the lower interval is hydrologically separated from ocean-waters. A reducing environment develops then below it resulting, for example, in the precipitation of sulfides. Today, whereas the interval corresponding to the first volcanic episode is sealed by alteration minerals, the second-one is still open to fluid circulation in its upper section. Thus, upper part of the volcanic edifice is potentially never exposed to fluids reaching deep into the crust, while the lower one is near the ridge axis.Considering that most of the extrusives are emplaced within a narrow volcanic zone, the first unit extruded for a given vertical cross-section is necessarily emplaced at the ridge-axis. In Hole 504B, the 250-m-thickTransition Zone from dikes to extrusives is interpreted as the relict massive unit flooding the axial graben at the onset of the first volcanic sequence, and later ruptured by numerous dikes. Further from the axis, the same massive unit constitutes a potential permeability cap for vertical crustal sections accreted earlier. Also, the upper 50 meters of the basement might be considered as the far-end expression of massive outpours extruded near the ridge-axis.     

Exploration potential of Cu isotope fractionation in porphyry copper deposits

We examined the copper isotope ratio of primary high temperature Cu-sulfides, secondary low temperature Cu-sulfides (and Cu-oxides) as well as Fe-oxides in the leach cap, which represent the weathered remains of a spectrum of Cu mineralization, from nine porphyry copper deposits. Copper isotope ratios are reported as δ⁶⁵Cu‰ = ((⁶⁵Cu/⁶³Cu_sample/⁶⁵Cu/⁶³Cu_{NIST 976 standard}) − 1) ? 10³. Errors for all the analyses are ± 0.14‰ (determined by multiple analyses of the samples) and mass bias was corrected through standard-sample-standard bracketing. The overall isotopic variability measured in these samples range from − 16.96‰ to 9.98‰.     

Re-evaluating the use of beached bird oiling rates to assess long-term trends in chronic oil pollution

The oiling rate (oiled birds/total birds) has become the international standard to analyze beached bird survey data. However, this index may not reliably track long-term changes in marine oil pollution in regions where other activities that kill seabirds vulnerable to oil, such as hunting and gill-netting, are also changing. We compare the oiling rate from beached bird surveys conducted in southeastern Newfoundland between 1984 and 2006 to an alternative approach, namely trends derived from a model examining the linear density of oiled birds (birds/km). In winter, there was no change in the oiling rate since 1984, while in summer oiling rates significantly increased. In contrast, the number of oiled birds/km showed a significant decline in both winter and summer. The discrepancy in these trends was attributed to steep declines in the number of unoiled birds found in both seasons. In winter, the decline in unoiled birds/km was related to a reduction in the legal murre hunt and less onshore winds, while in summer a reduced cod fishery resulting in fewer murres drowning in nets and warming summers may have lead to the decline. The significant declines in oiled birds/km over the past three decades are hopefully an indication of less oil being present in the marine environment. Although oiled bird densities since 2000 have remained relatively low for the region (winter: 0.58 birds/km, summer: 0.27 birds/km), they still exceed densities reported elsewhere in the world.     

Seabirds indicate changes in the composition of plastic litter in the Atlantic and south-western Indian Oceans

I compare plastic ingested by five species of seabirds sampled in the 1980s and again in 1999-2006. The numbers of ingested plastic particles have not changed significantly, but the proportion of virgin pellets has decreased 44-79% in all five species: great shearwater Puffinus gravis, white-chinned petrel Procellaria aequinoctialis, broad-billed prion Pachyptila vittata, white-faced storm petrel Pelagodroma marina and white-bellied storm petrel Fregetta grallaria. The populations sampled range widely in the South Atlantic and western Indian Oceans. The most marked reduction occurred in great shearwaters, where the average number of pellets per bird decreased from 10.5 to 1.6. This species migrates between the South and North Atlantic each year. Similar decreases in virgin pellets have been recorded in short-tailed shearwaters Puffinus tenuirostris in the Pacific Ocean and northern fulmars Fulmarus glacialis in the North Sea. More data are needed on the relationship between plastic loads in seabirds and the density of plastic at sea in their foraging areas, but the consistent decrease in pellets in birds suggests there has been a global change in the composition of small plastic debris at sea over the last two decades.     

The host stars of extrasolar planets have normal lithium abundances

The lithium abundances of planet-harbouring stars have been compared with the lithium abundances of open clusters and field stars. Young (chromospherically active) and subgiant stars have been eliminated from the comparison because they are at different stages of evolution and Li processing than the planet-harbouring stars, and hence have systematically higher Li abundances. The analysis showed that the Li abundances of the planet-harbouring stars are indistinguishable from those of non-planet-harbouring stars of the same age, temperature and composition. This conclusion is opposite to that arrived at by Gonzalez & Laws; it is believed that the field-star sample used by them contained too wide a range of ages, evolutionary types and temperatures to be accommodated by the model that they adopted to describe the dependence of Li on the parameters. The Li abundance does not appear set to provide key insights into the formation and evolution of planetary systems.     

Assessing TCE Source Bioremediation by Geostatistical Analysis of a Flux Fence

Mass discharge across transect planes is increasingly used as a metric for performance assessment of in situ groundwater remediation systems. Mass discharge estimates using concentrations measured in multilevel transects are often made by assuming a uniform flow field, and uncertainty contributions from spatial concentration and flow field variability are often overlooked. We extend our recently developed geostatistical approach to estimate mass discharge using transect data of concentration and hydraulic conductivity, so accounting for the spatial variability of both datasets. The magnitude and uncertainty of mass discharge were quantified by conditional simulation. An important benefit of the approach is that uncertainty is quantified as an integral part of the mass discharge estimate. We use this approach for performance assessment of a bioremediation experiment of a trichloroethene (TCE) source zone. Analyses of dissolved parent and daughter compounds demonstrated that the engineered bioremediation has elevated the degradation rate of TCE, resulting in a two‐thirds reduction in the TCE mass discharge from the source zone. The biologically enhanced dissolution of TCE was not significant (～5%), and was less than expected. However, the discharges of the daughter products cis‐1,2, dichloroethene (cDCE) and vinyl chloride (VC) increased, probably because of the rapid transformation of TCE from the source zone to the measurement transect. This suggests that enhancing the biodegradation of cDCE and VC will be crucial to successful engineered bioremediation of TCE source zones.     

River loads of suspended solids, nitrogen, phosphorus and herbicides delivered to the Great Barrier Reef lagoon

Degradation of coastal ecosystems in the Great Barrier Reef (GBR) lagoon, Australia, has been linked with increased land-based runoff of suspended solids, nutrients and pesticides since European settlement. This study estimated the increase in river loads for all 35 GBR basins, using the best available estimates of pre-European and current loads derived from catchment modelling and monitoring. The mean-annual load to the GBR lagoon for (i) total suspended solids has increased by 5.5 times to 17,000ktonnes/year, (ii) total nitrogen by 5.7 times to 80,000tonnes/year, (iii) total phosphorus by 8.9 times to 16,000tonnes/year, and (iv) PSII herbicides is 30,000kg/year. The increases in river loads differ across the 10 pollutants and 35 basins examined, reflecting differences in surface runoff, urbanisation, deforestation, agricultural practices, mining and retention by reservoirs. These estimates will facilitate target setting for water quality and desired ecosystem states, and enable prioritisation of critical sources for management.