Diffusive Oxygen Emitters for Enhancement of Aerobic In Situ Treatment

Aerobic biodegradation can be enhanced within contaminant plumes by elevating typically low dissolved oxygen (D.O.) levels using materials or devices that passively release oxygen. We have developed passive devices that provide a uniform, steady, long-term source of oxygen by diffusion from pressurized polymeric tubing and report test results under lab and field conditions. Lab flow-through reactor tests were conducted to determine the diffusion coefficient (D) of oxygen through four readily available tubing materials. Oxygen diffusion was greatest through Tygon® 3350 platinum-cured silicone (D = 6.67 ± 10^-7 cm²/sec), followed by 2075 Ultra Chemical Resistant Tygon (1.59 ± 10^-7 cm²/sec), 2275 High Purity Tygon (5.11 ± 10^-8 cm²/sec), and low-density polyethylene (LDPE; 1.73 ± 10^-8 cm²/sec). Variable-pressure release tests with LDPE resulted in very close estimates of D, which confirmed that mass transfer is controlled by diffusion and that the concentration gradient is a valid approximation of the chemical potential driving diffusion. LDPE emitter devices were designed and installed in seven 8-inch-diameter well screens across a portion of a gasoline plume at a former service station. With the devices pressurized to 620.5 kPag (kilopascals gauge) late in the test, steady-state D.O. concentrations reached as high as 25 mg/L, comparing favorably to the value predicted using the mass-transfer coefficient estimated from the lab test (26.3 mg/L). The method can also be used to release other gases for other reasons: gaseous tracers (i.e., sulphur hexafluoride, helium, and argon), hydrogen (for reductive dechlorination), or light alkanes (for cometabolic biodegradation of methyl tertiary butyl ether [MTBE] or chlorinated solvents).     

Defining phases of bedload transport using piecewise regression

Differences in the transport rate and size of bedload exist for varying levels of flow in coarse‐grained channels. For gravel‐bed rivers, at least two phases of bedload transport, with notably differing qualities, have been described in the literature. Phase I consists primarily of sand and small gravel moving at relatively low rates over a stable channel surface. Transport rates during Phase II are considerably greater than Phase I and more coarse grains are moved, including material from both the channel surface and subsurface. Transition from Phase I to Phase II indicates initiation and transport of grains comprising the coarse surface layer common in steep mountain channels. While the existence of different phases of transport is generally acknowledged, the threshold between them is often poorly defined. We present the results of the application of a piecewise regression analysis to data on bedload transport collected at 12 gravel‐bed channels in Colorado and Wyoming, USA. The piecewise regression recognizes the existence of different linear relationships over different ranges of discharge. The inflection, where the fitted functions intersect, is interpreted as the point of transition from Phase I to Phase II transport; this is termed breakpoint. A comparison of grain sizes moved during the two phases shows that coarse gravel is rarely trapped in the samplers during Phase I transport, indicating negligible movement of grains in this size range. Gravel larger than about D₁₆ of the channel surface is more consistently trapped during Phase II transport. The persistence of coarse gravel in bedload samples provides good evidence that conditions suitable for coarse grain transport have been reached, even though the size of the sediment approaches the size limits of the sampler (76 mm in all cases). A relative breakpoint (R_br) was defined by the ratio between the discharge at the breakpoint and the 1·5‐year flow (a surrogate for bankfull discharge) expressed as a percentage. The median value of R_br was about 80 percent, suggesting that Phase II begins at about 80 percent of the bankfull discharge, though the observed values of R_br ranged from about 60 to 100 percent. Variation in this value appears to be independent of drainage area, median grain size, sorting of bed materials, and channel gradient, at least for the range of parameters measured in 12 gravel‐bed channels. Published in 2002 by John Wiley & Sons, Ltd.     

International boundaries: Fresh perspectives

Reports

International boundaries: Fresh perspectivesSecond international boundaries research unit conference     

Automated drainage extraction in mapping the Monterey submarine drainage system,California margin

Drainage-extraction algorithms traditionally used for extracting river networks and watersheds from gridded land topography are applied to gridded multibeam bathymetry of the mid-California margin. The algorithms are used to automatically map two regional tributary networks of submarine canyons and deepsea channels draining Monterey Bay, the principal conduits of which are Acension and Monterey Canyons. The algorithms reliably map subaqueous drainage areas, but are prone to error in mapping the extent of submarine canyon and channel thalwegs due to operator subjectivity and algorithm limitations. A geomorphic comparison of the Acension and Monterey Canyon networks, with 12 river networks in the continental U.S., illustrates both the potential and weaknesses of using drainage extraction algorithms to analyze sediment pathways in gridded bathymetry.     

Asymmetrical turbid surface-plume deposition near ice-outlets of the Pleistocene Laurentide ice sheet in the Labrador Sea

 Ice-sheet drainage of glacial detritus into the sea involves size fractionation by ice-margin winnowing on a giant scale caused by the lower density of meltwater entering cold seawater. Despite its load of suspended sediment, the fresh water rises to or stays at the sea surface forming turbid surface plumes, whereas the coarse-grained sediment forms bed load. On the Labrador Slope south of the Hudson Strait turbid plumes were supplied by meltwater from the Pleistocene ice sheet (LIS). Sediments with the seismic characteristics of plume deposits occur in a 200-km-long slope sector up to 130 km seawards from the strait. The widespread distribution of these deposits is attributed to entrainment of the surface plumes by the south-flowing Labrador Current and suppressed flocculation due to the high detrital carbonate-content of the suspended sediment. Deposits with typical characteristics of surface plume deposits have been recovered within 20 km from former ice margin south of or in front of outlets, but not north of outlets. They consist of 1 to 2-cm-thick alternations of fine sandy silt/coarse silt layers with finer-grained clayey silt/silty clay, and for brevity are called plumites. Received: 6 August 1996/Revision received: 21 January 1997     

The fine structure of lysosomal membranes and endoplasmic reticulum in the digestive cells of Mytilus edulis exposed to anthracene and phenanthrene

The stability of lysosomes in the digestive cells of Mytilus edulis is affected by changes in both the chemical and physical conditions of the environment.¹ This type of response must reflect, at least in part, some change in the organisation of the lysosomal membrane, which is a structure which can be resolved by the electron microscope. However, conventional methods of tissue preparation have produced low contrast images of the digestive gland and damage to the lysosomal membranes. Recently a cryopreparation technique² has produced lysosomal membrane preparations in the digestive cells of the digestive gland of Mytilus which have high contrast and structural integrity (Fig. 1) in control animals. This method has been used to demonstrate pathological alterations in the lysosomal membrane induced by the polynuclear aromatic hydrocarbon (PNAH) phenanthrene. Anthracene, an isomeric PNAH, had no effect on the morphology of the lysosomal membrane. Phenanthrene also induced apparent proliferation of smooth endoplasmic reticulum in the digestive cells.     

Offset Spreading Centers near 12°53′ N on the East Pacific Rise: Submersible observations and composition of the volcanics

The Offset Spreading Center located between 12°52 and 12°54 N on the East Pacific Rise (Macdonald and Fox, 1983) has been studied in 1982 and 1984 with submersible Cyana and in 1983 with the deep towed vehicle Seamarc I. The two O.S.C. segments, about 1.5 km apart and 4 km in length, separated by a depression (about 100 m in depth) show different volcano-tectonic settings. The Western Spreading Center (WSC) segment is characterised mainly by recent volcanic constructional features, while the Eastern Spreading Center (ESC) is highly fissured and consists essentially of older pillow-lava terrain. The intervening depression located between the two segments is floored by small constructional mounds (<10 m in height) of pillow lava. The crust of both segments becomes older along strike towards their respective tips. However, the W.S.C. comprises generally younger flows than does the E.S.C. A small central volcano (80 m in height and 1 km in diameter) located near 12°51 N near the Southern tip of the W.S.C. contains a different type of volcanics than that found on both spreading centers. The volcanics collected along the O.S.C. ridges are depleted tholeiites, with low K₂O (<0.15%), Na₂O (<3%) and TiO₂ (<1.76%) contents, comparable to other MORB from the axial graben of the E.P.R. south of the area of overlap. Instead the specimen from the small volcano is enriched in K₂O (>0.2%), Na₂O (>3%) and TiO₂ (2%).Although there is a morphological overlap of the spreading centers in the study area there is no overlap in the present active axial volcanic zones. The bottom observations suggest that the Western spreading center is younger than the E.S.C. and thus that the W.S.C. could be propagating to the south.Contribution N^o 39 du Centre de Brest de L'IFREMER.     

Long-term environmental change and shifts in the aquatic plant community of Jones Creek,Thousand Islands National Park,Ontario, Canada based on plant macrofossil analysis

Plant macrofossils and pollen were analyzed from sediment cores to identify long-term changes in the aquatic plant community of Jones Creek, Thousand Islands National Park, Ontario, Canada. Six sediment cores were recovered from Jones Creek in February 2014. One complete core and five top/bottom samples were analyzed for plant macrofossil abundance and diversity. Sediment analysis and ²¹⁰Pb dating confirmed a productive wetland throughout the core, dating back beyond 1883 AD. Jones Creek is currently dominated by thick stands of cattails, particularly the hybrid white cattail (Typha x glauca Godr). The relative abundance of Typha pollen began to increase in the late nineteenth and early twentieth century, reaching a relative abundance of nearly 40% in the modern day surface sediment. Common macrofossils recovered from the sediment record included seeds of Carex, Schoenoplectus, Najas, and Eleocharis. There is evidence that community composition, as recorded by the macrofossil record, has shifted in Jones Creek in response to human activities. In particular there has been a reduction in sedge species between historical and present day conditions as the wetland shifted from a sedge dominated wet-meadow wetland to a cattail dominated system. The results of our study indicate that future restoration efforts should be directed towards reintroducing native sedge species that were present prior to major changes in land-use that occurred in the St. Lawrence region throughout the nineteenth and twentieth centuries.     

Agricultural drainage practices in Ireland

Agricultural drainage practices are reviewed under two main headings: arterial drainage of river catch-ments by developing main channels, and field drainage of smaller parcels of land using pipes and open trenches. The use of cost/benefit analysis on the arterial drainage program is considered and the inherent errors are discussed. Conservation of the environment is described as it applies to land-scaping, fisheries, and wildlife, and the drainage authorities are shown to have an enlightened attitude to proper preservation of the world around us.