Apportioning deformation among depth intervals in an aquifer system using InSAR and head data

Land surface subsidence due to excessive groundwater pumping is an increasing concern in California, USA. Interferometric Synthetic Aperture Radar (InSAR) is a remote sensing technique for measuring centimeter-to-millimeter surface deformation at 10–100 m spatial resolution. Here, a data-driven approach that attributes deformation to individual depth intervals within an aquifer system by integrating head data acquired from each of three screened intervals in a monitoring well with InSAR surface deformation measurements was developed. The study area was the Colusa Basin in northern Central Valley. To reconstruct the surface deformation history over the study area, 13 ALOS-PALSAR scenes acquired between 2006 and 2010 were processed. Up to ~3-cm year^?1 long-term subsidence and up to ~6 cm seasonal subsidence were observed using the InSAR technique. The technique developed in this paper integrates the InSAR-observed seasonal deformation rate and the co-located head measurements in multiple depth intervals to estimate the elastic skeletal storage coefficient, the time delay between the head change and the observed deformation, and subsequently the deformation of each depth interval. This technique can be implemented when hydraulic head measurements within each depth interval are not correlated with each other. Using this approach, the depth interval that contributed the most to the total subsidence, as well as storage parameters for all intervals, are estimated. The technique can be used for identification of the depth interval within the aquifer system responsible for deformation.

     

Raman instrument calibration for astromaterials and analysis of Mars return samples

The study of astromaterials generally involves the distribution of limited sample to many laboratories for analysis. Maximum scientific yield for a sample occurs when the data and results from different studies are examined as a collective. This collective examination of results will be particularly important for upcoming sample return missions including Mars sample return and OSIRIS-REx. When comparing results across laboratories, instrument calibration is of key importance. For Raman data, this includes the calibration of all three Raman band parameters: peak wavenumber position, bandwidth, and intensity. Although wavenumber is routinely calibrated, bandwidth and intensity are not; though they are commonly compared across studies. In addition, Raman instrument calibration is time dependent. An understanding of the time dependence of instrument calibration is important for proper calibration. Here, we use a mixture of well-established and recently developed calibration techniques to propose a standard method of calibrating Raman astromaterial data across laboratories to maximize the scientific value of the data.     

Isotopic Characterization of Sulfate in a Shallow Aquifer Impacted by Agricultural Fertilizer

The stable isotope ratios of groundwater sulfate (³⁴S/³²S, ¹⁸O/¹⁶O) are often used as tracers to help determine the origin of groundwater or groundwater contaminants. In agricultural watersheds, little is known about how the increased use of sulfur as a soil amendment to optimize crop production is affecting the isotopic composition of groundwater sulfate, especially in shallow aquifers. We investigated the isotopic composition of synthetic agricultural fertilizers and groundwater sulfate in an area of intensive agricultural activity, in Ontario, Canada. Groundwater samples from an unconfined surficial sand aquifer (Lake Algonquin Sand Aquifer) were analyzed from multi-level monitoring wells, riverbank seeps, and private domestic wells. Fertilizers used in the area were analyzed for sulfur/sulfate content and stable isotopic composition (δ¹⁸O and/or δ³⁴S). Fertilizers were isotopically distinct from geological sources of groundwater sulfate in the watershed and groundwater sulfate exhibited a wide range of δ³⁴S (−6.9 to +20.0‰) and δ¹⁸O (−5.0 to +13.7‰) values. Quantitative apportionment of sulfate sources based on stable isotope data alone was not possible, largely because two of the potential fertilizer sulfate sources had an isotopic composition on the mixing line between two natural geological sources of sulfate in the aquifer. This study demonstrates that, when sulfate isotope analysis is being used as a tracer or co-tracer of the origin of groundwater or of contaminants in groundwater, sulfate derived from synthetic fertilizer needs to be considered as a potential source, especially when other parameters such as nitrate independently indicate fertilizer impacts to groundwater quality.     

Northern landscapes in transition: Evidence,approach and ways forward using the Krycklan Catchment Study

Improving our ability to detect changes in terrestrial and aquatic systems is a grand challenge in the environmental sciences. In a world experiencing increasingly rapid rates of climate change and ecosystem transformation, our ability to understand and predict how, when, where, and why changes occur is essential for adapting and mitigating human behaviours. In this context, long-term field research infrastructures have a fundamentally important role to play. For northern boreal landscapes, the Krycklan Catchment Study (KCS) has supported monitoring and research aimed at revealing these changes since it was initiated in 1980. Early studies focused on forest regeneration and microclimatic conditions, nutrient balances and forest hydrology, which included monitoring climate variables, water balance components, and stream water chemistry. The research infrastructure has expanded over the years to encompass a 6790 ha catchment, which currently includes 11 gauged streams, ca. 1000 soil lysimeters, 150 groundwater wells, >500 permanent forest inventory plots, and a 150 m tall tower (a combined ecosystem-atmosphere station of the ICOS, Integrated Carbon Observation System) for measurements of atmospheric gas concentrations and biosphere-atmosphere exchanges of carbon, water, and energy. In addition, the KCS has also been the focus of numerous high resolution multi-spectral LiDAR measurements and large scale experiments. This large collection of equipment and data generation supports a range of disciplinary studies, but more importantly fosters multi-, trans-, and interdisciplinary research opportunities. The KCS attracts a broad collection of scientists, including biogeochemists, ecologists, foresters, geologists, hydrologists, limnologists, soil scientists, and social scientists, all of whom bring their knowledge and experience to the site. The combination of long-term monitoring, shorter-term research projects, and large-scale experiments, including manipulations of climate and various forest management practices, has contributed much to our understanding of boreal landscape functioning, while also supporting the development of models and guidelines for research, policy, and management.     

Oceanographic and eustatic control of carbonate platform evolution and sequence stratigraphy on the Cretaceous (Valanginian–Campanian) passive margin,northern Gulf of Mexico

An integrated sequence stratigraphic study based on outcrop, core and wireline log data documents the combined impact of Cretaceous eustacy and oceanic anoxic events on carbonate shelf morphology and facies distributions in the northern Gulf of Mexico. The diverse facies and abundant data of the Comanche platform serve as a nearly complete global reference section and provide a sensitive record of external processes affecting Cretaceous platform development. Regional cross‐sections across the shoreline to shelf‐margin profile provide a detailed record of mixed carbonate–siliciclastic strata for the Hauterivian to lower Campanian stages (ca 136 to 80 Ma). The study window on the slowly subsiding passive margin allows the stratigraphic response to external forcing mechanisms to be isolated from regional structural processes. Three second‐order supersequences comprised of eight composite sequences are recognized in the Valanginian–Barremian, the Aptian–Albian and the Cenomanian–Campanian. The Valanginian–Barremian supersequence transitioned from a siliciclastic ramp to carbonate rimmed shelf and is a product of glacial ice accumulation and melting, as well as variable rates of mid‐ocean ridge volcanism. The Aptian–Albian supersequence chronicles the drowning and recovery of the platform surrounding oceanic anoxic events 1a and 1b. The Cenomanian–Campanian supersequence similarly documents shelf drowning following oceanic anoxic event 1d, after which the platform evolved to a deep‐subtidal system consisting of anoxic/dysoxic shale and chalk in the time surrounding oceanic anoxic event 2. Each period of oceanic anoxia is associated with composite sequence maximum flooding, termination of carbonate shelf sedimentation and deposition of condensed shale units in distally steepened ramp profiles. Composite sequences unaffected by oceanic anoxic events consist of aggradational to progradational shelves with an abundance of grain‐dominated facies and shallow‐subtidal to intertidal environments. Because they are products of eustacy and global oceanographic processes, the three supersequences and most composite sequences defined in the south Texas passive margin are recognizable in other carbonate platforms and published eustatic sea‐level curves.     

Large-Scale Synoptic Systems and Fog During the C-FOG Field Experiment

Boundary-Layer Meteorology - The goal of this work is to summarize synoptic meteorological conditions during the Coastal Fog (C-FOG) field project that took place onshore and offshore of the Avalon...     

Microphysics and Optical Attenuation in Fog: Observations from Two Coastal Sites

Boundary-Layer Meteorology - A total of 15 fog events from two field campaigns are investigated: the High Energy Laser in Fog (HELFOG) project (central California) and the Toward Improving Coastal...     

The application of visible/near‐infrared reflectance (VNIR) spectroscopy to chert: A case study from the Dover Quarry sites,Tennessee

Prehistoric cultural material is commonly composed of chert, due in large part to its physical properties that are conducive to tool manufacture. Despite its ubiquity, archaeologists are faced with an arduous task when attempting to source chert artifacts to known quarries/deposits. The application of visible/near‐infrared reflectance (VNIR) spectroscopy to chert sourcing attains a cost‐efficient, fast, non‐destructive, and accurate means of identifying material type and geologic/geographic origin. This study examines the merits of VNIR spectroscopy within chert sourcing studies by highlighting a material‐based case study from the Dover Quarry sites, Tennessee. Results demonstrate the ability of VNIR spectroscopy to differentiate chert types from different geologic formations with 98% accuracy. However, accuracy significantly decreased when attempting to distinguish particular outcrops within the same formation. Although the application of VNIR spectroscopy to chert sourcing is in its experimental phase, the preliminary results compare favorably with other provenance techniques whose aim is to quantify inter‐outcrop variation. © 2011 Wiley Periodicals, Inc.     

Spatiotemporal environmental triggers of Ebola and Marburg virus transmission

Despite their fame, Ebola and Marburg viruses (family Filoviridae) remain mysterious. Filovirus outbreaks are restricted to tropical Africa, but their likely geographic extent has been outlined only recently, and their natural reservoir host(s) remains unidentified. If environmental conditions associated with outbreaks in space and time can be identified precisely, much could be learned about the ecology, evolution and transmission of these viruses. We examined five filovirus outbreaks for which time series of remotely sensed data (NDVI values) are available and for which the reservoir-to-human index case transmission timing and location are known. A wavelet analysis was used to detect anomalous behaviour in the NDVI signal across multiple time scales for each outbreak. Scale-wise anomalies were manifested at a 20-day scale, and were found in four of the five sites, one to three weeks preceding outbreaks, suggesting that filovirus-caused disease outbreaks may be associated with either behavioural shifts in a vertebrate host or changes in viral population dynamics. More generally, wavelet analysis offers a powerful tool for identifying temporal correlates of disease transmission events.