River loads of suspended solids, nitrogen, phosphorus and herbicides delivered to the Great Barrier Reef lagoon

Degradation of coastal ecosystems in the Great Barrier Reef (GBR) lagoon, Australia, has been linked with increased land-based runoff of suspended solids, nutrients and pesticides since European settlement. This study estimated the increase in river loads for all 35 GBR basins, using the best available estimates of pre-European and current loads derived from catchment modelling and monitoring. The mean-annual load to the GBR lagoon for (i) total suspended solids has increased by 5.5 times to 17,000ktonnes/year, (ii) total nitrogen by 5.7 times to 80,000tonnes/year, (iii) total phosphorus by 8.9 times to 16,000tonnes/year, and (iv) PSII herbicides is 30,000kg/year. The increases in river loads differ across the 10 pollutants and 35 basins examined, reflecting differences in surface runoff, urbanisation, deforestation, agricultural practices, mining and retention by reservoirs. These estimates will facilitate target setting for water quality and desired ecosystem states, and enable prioritisation of critical sources for management.     

Dynamics of herbicide transport and partitioning under event flow conditions in the lower Burdekin region, Australia

This study examined the temporal variability in herbicide delivery to the Great Barrier Reef (GBR) lagoon (Australia) from one of the GBR catchment's major sugarcane growing regions. Annual loads of measured herbicides were consistently in the order of 200+kg. Atrazine, it's degradate desethylatrazine, and diuron contributed approximately 90% of annual herbicide load, with early 'first-flush' events accounting for the majority of herbicide loads leaving the catchment. Assessment of herbicide water-sediment partitioning in flood runoff highlighted the majority of herbicides were transported in predominantly dissolved form, although a considerable fraction of diuron was transported in particulate-bound form (ca. 33%). Diuron was also the herbicide demonstrating the highest concentrations and frequency of detection in sediments collected from catchment waterways and adjacent estuarine-marine environments, an outcome aligning with previous research. Herbicide physico-chemical properties appear to play a crucial role in partitioning between water column and sediment habitat types in GBR receiving ecosystems.     

Seabirds indicate changes in the composition of plastic litter in the Atlantic and south-western Indian Oceans

I compare plastic ingested by five species of seabirds sampled in the 1980s and again in 1999-2006. The numbers of ingested plastic particles have not changed significantly, but the proportion of virgin pellets has decreased 44-79% in all five species: great shearwater Puffinus gravis, white-chinned petrel Procellaria aequinoctialis, broad-billed prion Pachyptila vittata, white-faced storm petrel Pelagodroma marina and white-bellied storm petrel Fregetta grallaria. The populations sampled range widely in the South Atlantic and western Indian Oceans. The most marked reduction occurred in great shearwaters, where the average number of pellets per bird decreased from 10.5 to 1.6. This species migrates between the South and North Atlantic each year. Similar decreases in virgin pellets have been recorded in short-tailed shearwaters Puffinus tenuirostris in the Pacific Ocean and northern fulmars Fulmarus glacialis in the North Sea. More data are needed on the relationship between plastic loads in seabirds and the density of plastic at sea in their foraging areas, but the consistent decrease in pellets in birds suggests there has been a global change in the composition of small plastic debris at sea over the last two decades.     

Dolomite dissolution: An alternative diagenetic pathway for the formation of palygorskite clay

Palygorskite is a fibrous, magnesium‐bearing clay mineral commonly associated with Late Mesozoic and Early Cenozoic dolomites. The presence of palygorskite is thought to be indicative of warm, alkaline fluids rich in Si, Al and Mg. Palygorskite has been interpreted to form in peritidal diagenetic environments, either as a replacement of detrital smectite clay during a dissolution–precipitation reaction or solid‐state transformation, or as a direct precipitate from solution. Despite a lack of evidence, most diagenetic studies involving these two minerals posit that dolomite and palygorskite form concurrently. Here, petrological evidence is presented from the Umm er Radhuma Formation (Palaeocene–Eocene) in the subsurface of central Qatar for an alternative pathway for palygorskite formation. The Umm er Radhuma is comprised of dolomitized subtidal to peritidal carbonate cycles that are commonly capped by centimetre‐scale beds rich in palygorskite. Thin section, scanning electron microscopy and elemental analyses demonstrate that palygorskite fibres formed on both the outermost surfaces of dissolved euhedral dolomite crystals and within partially to completely dissolved dolomite crystal cores. These observations suggest that dolomite and palygorskite formed sequentially, and support a model by which the release of Mg²⁺ ions and the buffering of solution pH during dolomite dissolution promote the formation of palygorskite. This new diagenetic model explains the co‐occurrence of palygorskite and dolomite in the rock record, and provides valuable insight into the specific diagenetic conditions under which these minerals may form.     

Re-evaluating the use of beached bird oiling rates to assess long-term trends in chronic oil pollution

The oiling rate (oiled birds/total birds) has become the international standard to analyze beached bird survey data. However, this index may not reliably track long-term changes in marine oil pollution in regions where other activities that kill seabirds vulnerable to oil, such as hunting and gill-netting, are also changing. We compare the oiling rate from beached bird surveys conducted in southeastern Newfoundland between 1984 and 2006 to an alternative approach, namely trends derived from a model examining the linear density of oiled birds (birds/km). In winter, there was no change in the oiling rate since 1984, while in summer oiling rates significantly increased. In contrast, the number of oiled birds/km showed a significant decline in both winter and summer. The discrepancy in these trends was attributed to steep declines in the number of unoiled birds found in both seasons. In winter, the decline in unoiled birds/km was related to a reduction in the legal murre hunt and less onshore winds, while in summer a reduced cod fishery resulting in fewer murres drowning in nets and warming summers may have lead to the decline. The significant declines in oiled birds/km over the past three decades are hopefully an indication of less oil being present in the marine environment. Although oiled bird densities since 2000 have remained relatively low for the region (winter: 0.58 birds/km, summer: 0.27 birds/km), they still exceed densities reported elsewhere in the world.     

Vitriclastic lithofacies from Macquarie Island (Southern Ocean): compositional influence on abyssal eruption explosivity in a dying Miocene spreading ridge

Macquarie Island is composed of a complete section of oceanic crust that formed in a slow-spreading mid-ocean ridge 2.0 to 3.5 km below sea level. Vitriclastic facies preserved on the island have both pyroclastic and hyaloclastic characteristics. Monomict hyaloclastic breccia facies are widespread across the island and are predominantly composed of near-primitive (~7.9 wt% MgO) subalkaline/transitional (~0.7 wt% K₂O) sideromelane shards and crystalline basalt clasts with low vesicularity (LV, < 15% vesicles). Breccias are thick bedded and structureless with matrix-supported angular pillow fragments, bomb-sized fluidal mini-pillows, and globular glass lapilli. Clasts are lithologically similar to interbedded pillow basalts and laterally grade into fine-grained sandstone facies. These sandstones are normal-graded, well-laminated, thin bedded, and interstratified with red pelagic mudstone. Lithofacies associations indicate that the hyaloclastic breccias were formed proximal to a source vent via quench-fragmentation, and subsequently reworked by ocean-bottom currents into distal epiclastic sandstone facies. During eruption, co-genetic pillow lava and hypabyssal intrusions mingled with the breccia, forming fluidal peperite. Rare polymict pyroclastic facies only occur in the highest stratigraphic levels and are mostly composed of highly vesicular (HV, 15–50% vesicles) sideromelane shards and crystalline basalt clasts with alkaline (~1.0 wt% K₂O) fractionated (~6.8% MgO) compositions. Minor lithic grains are composed of subalkaline (~0.7 wt% K₂O) to very highly alkaline (~1.7 wt% K₂O) LV sideromelane shards, and amphibole-bearing diabase. The pyroclastic facies contains medium to thick beds of lapilli-tuff that exhibit both reverse and normal grading, diffuse lamination, and planar-grain fabric. These beds are locally overlain by thin fine-grained tuff beds entirely composed of cuspate to very thin elongate bubble-wall shards. These characteristics indicate that explosive deep-marine eruptions produced high-density coarse-grained gravity flows that were covered by slower suspension settle-out of delicate bubble-wall shards. Stratigraphic relationships suggest that explosive eruptions started during the waning stages of more alkaline volcanism along the proto-Macquarie spreading center.     

Shear wave velocities of Mississippi embayment soils from low frequency surface wave measurements

Deep unconsolidated sediments in the Mississippi embayment will influence ground motions from earthquakes in the New Madrid seismic zone. Shear wave velocity profiles of these sediments are important input parameters for modeling wave propagation and site response in this region. Low-frequency, active-source surface wave velocity measurements were performed to develop small-strain shear wave velocity (V_S) profiles at eleven deep soil sites in the Mississippi embayment, from north of New Madrid, Missouri to Memphis, Tennessee. A servo-hydraulic, low-frequency source was used to excite surface wave energy to wavelengths of 600 m, resulting in V_S profiles to depths of over 200 m. The average V_S profile calculated from the eleven sites is in good agreement with common reference V_S profiles that have been used in seismic hazard studies of this region. The variability in V_S profiles is shown to be associated with changes in formation depth and thickness from site-to-site. Using lithologic information at each site, average formation velocities were developed and compared to previous studies. We found average V_S values of about 193 m/s for alluvial deposits, 400 m/s for the Upper Claiborne formations, and 685 m/s for the Memphis Sand formation.     

Temporal and Spatial Dynamics of Estuarine Shoreline Change in the Albemarle-Pamlico Estuarine System,North Carolina,USA

Many shoreline studies rely on historical change rates determined from aerial imagery decades to over 50 years apart to predict shoreline position and determine setback distances for coastal structures. These studies may not illustrate the coastal impacts of short-duration but potentially high-impact storm events. In this study, shoreline change rates (SCRs) are quantified at five different sites ranging from marsh to sediment bank shorelines around the Albemarle-Pamlico estuarine system (APES) for a series of historical (decadal to 50-year) and short-term (bimonthly) time periods as well as for individual storm events. Long-term (historical) SCRs of approximately ?0.5 ± 0.07 m year^?1 are observed, consistent with previous work along estuarine shorelines in North Carolina. Short-term SCRs are highly variable, both spatially and temporally, and ranged from 15.8 ± 7.5 to ?19.3 ± 11.5 m year^?1 at one of the study sites. The influence of wave climate on the spatial and temporal variability of short-term erosion rates is investigated using meteorological observations and coupled hydrodynamic (Delft3D) and wave (SWAN) models. The models are applied to simulate hourly variability in the surface waves and water levels. The results indicate that in the fetch-limited APES, wind direction strongly influences the wave climate at the study sites. The wave height also has an influence on short-term SCRs as determined from the wave simulations for individual meteorological events, but no statistical correlation is found for wave height and SCRs over the long term. Despite the significantly higher rates of shoreline erosion over short time periods and from individual events like hurricanes, the cumulative impact over long time periods is low. Therefore, while the short-term response of these shorelines to episodic forcing should be taken into account in management plans, the long-term trends commonly used in ocean shoreline management can also be used to determine erosion setbacks on estuarine shorelines.