Nucleation and growth of strike-slip faults in limestones from Somerset, U.K.

Small-scale structures along strike-slip fault zones in limestones exposed around the Bristol Channel, U.K., suggest that pressure solution plays a key role during fault nucleation and growth. Incipient shear zones consist of enéchelon veins. The first generation of solution seams form due to bending of the intact rock (bridge) between overlapping veins. As the bridge rotates, slip occurs along the seams, linking the veins, causing cm-scale calcite-filled pull-apart structures to form and allowing fault displacement to increase. A second generation of solution seams forms at the tip of the sliding seams. As displacement increases further, causing larger rotation, slip also can occur along these second-generation solution seams, producing the third generation of solution seams as well as tail cracks (pinnate veins) at their tips. These three generations of solution seams all contribute to the formation of individual fault segments. Fourth and fifth generations of solution seams occur within larger-scale contractional oversteps between side-stepping fault segments. The oversteps are breached by slip along these localized solution seams, eventually leading to the formation of a distinct through-going fault with several metres of displacement.The initial enéchelon veins, solution seams of various generations and tail cracks progressively fragment the fault-zone material as fault slip accumulates. Slip planes nucleate on these pre-existing discontinuities, principally along the clay-enriched, weaker solution seams. This can be observed at a variety of scales and suggests that Mode II shear fracturing does not occur as a primary fracture mechanism, but only as a macroscopic phenomenon following Mode I (veins and tail cracks) and anti-mode I (solution seams) deformation. It appears that solution seams can play a similar role to microcracks in localizing a through-going slip plane. This micromechanical model of faulting may be applicable to some other faults and shear zones in host rocks which are prone to pressure solution.     

Raman instrument calibration for astromaterials and analysis of Mars return samples

The study of astromaterials generally involves the distribution of limited sample to many laboratories for analysis. Maximum scientific yield for a sample occurs when the data and results from different studies are examined as a collective. This collective examination of results will be particularly important for upcoming sample return missions including Mars sample return and OSIRIS-REx. When comparing results across laboratories, instrument calibration is of key importance. For Raman data, this includes the calibration of all three Raman band parameters: peak wavenumber position, bandwidth, and intensity. Although wavenumber is routinely calibrated, bandwidth and intensity are not; though they are commonly compared across studies. In addition, Raman instrument calibration is time dependent. An understanding of the time dependence of instrument calibration is important for proper calibration. Here, we use a mixture of well-established and recently developed calibration techniques to propose a standard method of calibrating Raman astromaterial data across laboratories to maximize the scientific value of the data.     

Predicting Future Groundwater Resources of Coral Atoll Islands

Fresh groundwater reserves on small coral islands are under continual threat of salinization and contamination because of droughts, storm‐surge overwash events, over‐extraction, island community urbanization, and sea level rise. Whereas storm‐surge overwash events can cause sudden groundwater salinization, long‐term changes in rainfall patterns and sea level elevation have the potential of rendering these islands uninhabitable in the coming decades. This study demonstrates the use of a tested freshwater lens thickness simulator to estimate the groundwater resources of a set of atoll islands in the coming decades. The method uses ranges of projected rates of annual rainfall and sea level rise (SLR) to provide a range of probable lens thickness for each island. Projected rainfall is provided by General Circulation Models that accurately replicate the historical rainfall patterns in the geographic region of the islands. Methodology is applied to 68 atoll islands in the Federated States of Micronesia. These islands have widths that range between 150 and 1000 m, and experience annual rainfall rates of between 2.8 and 4.8 m. Results indicate that under average conditions of SLR, beach slope, and rainfall, almost half of the island will experience a 20% decrease in lens thickness by the year 2050. For worst‐case scenarios (high SLR, low rainfall), average decrease in lens thickness is 55%, with almost half of the islands experiencing a decrease of greater than 75% and half of the islands having a lens thickness less than 1.0 m. Small islands (widths less than 400 m) are particularly vulnerable because of shoreline recession. Groundwater on islands in the western region is less vulnerable to SLR because of a projected increase in rainfall during the coming decades. Results indicate the vulnerability of small islands to changing climatic conditions, and can be used for water resources management and community planning. Methodology can be applied to any group of islands as a first approximation of the effect of future climate conditions on groundwater resources. Copyright © 2016 John Wiley & Sons, Ltd.     

Quantifying groundwater–surface water interactions in a proglacial valley,Cordillera Blanca,Peru

A myriad of downstream communities and industries rely on streams fed by both groundwater discharge and glacier meltwater draining the Cordillera Blanca, Northern Peruvian Andes, which contains the highest density of glaciers in the tropics. During the dry season, approximately half the discharge in the region's proglacial streams comes from groundwater. However, because of the remote and difficult access to the region, there are few field methods that are effective at the reach scale to identify the spatial distribution of groundwater discharge. An energy balance model, Rhodamine WT dye tracing, and high‐definition kite‐borne imagery were used to determine gross and net groundwater inputs to a 4‐km reach of the Quilcay River in Huascaran National Park, Peru. The HFLUX computer programme ( http://hydrology.syr.edu/hflux.html ) was used to simulate the Quilcay River's energy balance using stream temperature observations, meteorological measurements, and kite‐borne areal photography. Inference from the model indicates 29% of stream discharge at the reach outlet was contributed by groundwater discharge over the study section. Rhodamine WT dye tracing results, coupled with the energy balance, show that approximately 49% of stream water is exchanged (no net gain) with the subsurface as gross gains and losses. The results suggest that gross gains from groundwater are largest in a moraine subreach but because of large gross losses, net gains are larger in the meadow subreaches. These insights into pathways of groundwater–surface water interaction can be applied to improve hydrological modelling in proglacial catchments throughout South America. Copyright © 2016 John Wiley & Sons, Ltd.     

The Late Cenozoic uplift – climate change paradox

The geologic evidence for worldwide uplift of mountain ranges in the Neogene is ambiguous. Estimates of paleoelevation vary, according to whether they are based on the characteristics of fossil floras, on the masses and grain sizes of eroded sediments, or on calculations of increased thickness of the lithosphere as a result of faulting. Detrital erosion rates can be increased both by increased relief in the drainage basin and by a change to more seasonal rainfall patterns. The geologic record provides no clear answer to the question whether uplift caused the climatic deterioration of the Neogene or whether the changing climate affected the erosion system in such a way as to create an illusion of uplift. We suggest that the spread of C₄ plants in the Late Miocene may have altered both the erosion and climate systems. These changes are responsible for the apparent contradictions between data supporting uplift and those supporting high elevations in the past.     

Nucleosynthesis and early chemical evolution in galaxies

Nucleosynthesis and galactic chemical evolution are inter-linked topics that merge various fields in astronomy and physics. Speakers at the RAS discussion meeting of January 2003 combined theory and observation in understanding these fields. Stelios A Tsangarides, Enrico Arnone and Sean G Ryan report.     

The application of visible/near‐infrared reflectance (VNIR) spectroscopy to chert: A case study from the Dover Quarry sites,Tennessee

Prehistoric cultural material is commonly composed of chert, due in large part to its physical properties that are conducive to tool manufacture. Despite its ubiquity, archaeologists are faced with an arduous task when attempting to source chert artifacts to known quarries/deposits. The application of visible/near‐infrared reflectance (VNIR) spectroscopy to chert sourcing attains a cost‐efficient, fast, non‐destructive, and accurate means of identifying material type and geologic/geographic origin. This study examines the merits of VNIR spectroscopy within chert sourcing studies by highlighting a material‐based case study from the Dover Quarry sites, Tennessee. Results demonstrate the ability of VNIR spectroscopy to differentiate chert types from different geologic formations with 98% accuracy. However, accuracy significantly decreased when attempting to distinguish particular outcrops within the same formation. Although the application of VNIR spectroscopy to chert sourcing is in its experimental phase, the preliminary results compare favorably with other provenance techniques whose aim is to quantify inter‐outcrop variation. © 2011 Wiley Periodicals, Inc.     

Early and pervasive dolomitization by near-normal marine fluids: New lessons from an Eocene evaporative setting in Qatar

The upper Palaeocene–lower Eocene Umm er Radhuma Formation in the subsurface of Qatar is dominated by subtidal carbonate depositional packages overlain by bedded evaporites. In Saudi Arabia and Kuwait, peritidal carbonate depositional sequences with intercalated evaporites and carbonates in Umm er Radhuma have been previously interpreted to have been dolomitized via downward reflux of hypersaline brines. Here, textural, mineralogical and geochemical data from three research cores in Qatar are presented which, in contrast, are more consistent with dolomitization by near-normal marine fluids. Petrographic relationships support a paragenetic sequence whereby dolomitization occurred prior to the formation of all other diagenetic mineral phases, including chert, pyrite, palygorskite, gypsum, calcite and chalcedony, which suggests that dolomitization occurred very early. The dolomites occur as finely crystalline mimetic dolomites, relatively coarse planar-e dolomites, and coarser nonplanar dolomites, all of which are near-stoichiometric (50.3 mol% MgCO₃) and well-ordered (0.73). The dolomite stable isotope values (range −2.5‰ to +1‰; mean δ¹⁸O = −0.52‰) and trace element concentrations (Sr = 40 to 150 ppm and Na = 100 to 600 ppm) are compatible with dolomitization by near-normal seawater or mesohaline fluids. Comparisons between δ¹⁸O values from Umm er Radhuma dolomite and the overlying Rus Formation gypsum further suggest that dolomitization did not occur in fluids related to Rus evaporites. This study provides an example of early dolomitization of evaporite-related carbonates by near-normal seawater rather than by refluxing hypersaline brines from overlying bedded evaporites. Further, it adds to recent work suggesting that dolomitization by near-normal marine fluids in evaporite-associated settings may be more widespread than previously recognized.     

Threshold effects of coastal urbanization on<Emphasis Type="Italic">Phragmites australis</Emphasis> (common reed) abundance and foliar nitrogen in Chesapeake Bay

The invasion of North American tidal marshes byPhragmites australis, or common reed, is a large-scale ecological problem that has been primarily studied at small spatial scales. Previous local-scale studies have provided evidence that the expansion ofPhragmites is facilitated by disturbance and increased nitrogen (N) associated with agricultural and urban-suburban (developed) land uses along wetland-upland borders. We tested the generality of previous findings across a larger spatial scale and wider range of environmental conditions in Chesapeake Bay, the largest estuarine ecosystem in the USA. We sampled 90 tidal wetlands nested within 30 distinct subestuarine watersheds and examined the relationship between land use andPhragmites abundance and foliar N, an indicator of nitrogen availability. We estimated land use adjacent to wetland borders and within subestuary watersheds and explored the importance of spatial proximity by weighting land use by its distance from the wetland border or subestuary shoreline, respectively. Regression tree and changepoint analyses revealed thatPhragmites abundance sharply increased in almost every wetland where development adjacent to borders exceeded 15%. Where development was <15% but natural land cover at the near the subestuary shoreline was low (<∼35%),Phragmites was abundant, suggesting that wetlands in highly modified watersheds also were susceptible to invasion, regardless of land use adjacent to wetlands.Phragmites foliar N was markedly elevated in watersheds with >14–22% shoreline development, the same level of development that corresponded to high levels of invasion. Our results suggest that development near wetlands is at least partially responsible for patterns of invasion across Chesapeake Bay. Larger-scale phenomena, such as nitrogen pollution at the watershed-subestuary scale, also may be facilitating invasion. Urbanization near coastlines appears to play an important role in the invasion success ofPhragmites in coastal wetlands of Chesapeake Bay and probably much of eastern North America.