Possible Density Change of the Origin of North Pacific Intermediate Water Due to Double Diffusion in the Mixed Water Region

In this study we test Talley's hypothesis that Oyashio winter mixed-layer water (26.5–26.6σ _θ) increases its density to produce the North Pacific Intermediate Water (NPIW) salinity minimum (26.7– 26.8σ_θ) in the Mixed Water Region, assuming a combination of cabbeling and double diffusion. The possible density change of Oyashio winter mixed-layer water is discussed using an instantaneous ratio of the change of temperature and salinity along any particular intrusion (R _l ). We estimate the range of R _l ^DD required to convert Oyashio winter mixed-layer water to the NPIW salinity minimum due to double diffusion, and then assume double-diffusive intrusions as this conversion mechanism. A double-diffusive intrusion model is used to estimate R _l ^DD in a situation where salt fingering dominates vertical mixing, as well as to determine whether Oyashio winter mixed-layer water can become the NPIW salinity minimum. Possible density changes are estimated from the model R _l ^DD by assuming the amount of density change due to cabbeling. From these results, we conclude that Oyashio winter mixed-layer water contributes to a freshening of the lighter layer of the NPIW salinity minimum (around 26.70σ_θ) in the MWR.     

Estuary/ocean exchange and tidal mixing in a Gulf of Maine Estuary: A Lagrangian modeling study

A Lagrangian particle method embedded within a 2-D finite element code, is used to study the transport and ocean–estuary exchange processes in the well-mixed Great Bay Estuarine System in New Hampshire, USA. The 2-D finite element model, driven by residual, semi-diurnal and diurnal tidal constituents, includes the effects of wetting and drying of estuarine mud flats through the use of a porous medium transport module. The particle method includes tidal advection, plus a random walk model in the horizontal that simulates sub-grid scale turbulent transport processes. Our approach involves instantaneous, massive [O(500,000)] particle releases that enable the quantification of ocean–estuary and inter-bay exchanges in a Markovian framework. The effects of the release time, spring–neap cycle, riverine discharge and diffusion strength on the intra-estuary and estuary–ocean exchange are also investigated.The results show a rather dynamic interaction between the ocean and the estuary with a fraction of the exiting particles being caught up in the Gulf of Maine Coastal Current and swept away. Three somewhat different estimates of estuarine residence time are calculated to provide complementary views of estuary flushing. Maps of residence time versus release location uncover a strong spatial dependency of residence time within the estuary that has very important ramifications for local water quality. Simulations with and without the turbulent random walk show that the combined effect of advective shear and turbulent diffusion is very effective at spreading particles throughout the estuary relatively quickly, even at low (1 m²/s) diffusivity. The results presented here show that a first-order Markov Chain approach has applicability and a high potential for improving our understanding of the mixing processes in estuaries.     

Paleoenvironment and sea-level change in the early Cretaceous Barents Sea—implications from near-shore marine sapropels

The late Volgian (early "Boreal" Berriasian) sapropels of the Hekkingen Formation of the central Barents Sea show total organic carbon (TOC) contents from 3 to 36 wt%. The relationship between TOC content and sedimentation rate (SR), and the high Mo/Al ratios indicate deposition under oxygen-free bottom-water conditions, and suggest that preservation under anoxic conditions has largely contributed to the high accumulation of organic carbon. Hydrogen index values obtained from Rock-Eval pyrolysis are exceptionally high, and the organic matter is characterized by well-preserved type II kerogen. However, the occurrence of spores, freshwater algae, coal fragments, and charred land-plant remains strongly suggests proximity to land. Short-term oscillations, probably reflecting Milankovitch-type cyclicity, are superimposed on the long-term trend of constantly changing depositional conditions during most of the late Volgian. Progressively smaller amounts of terrestrial organic matter and larger amounts of marine organic matter upwards in the core section may have been caused by a continuous sea-level rise.     

Evidence of NW extension of the North Anatolian Fault Zone in the Marmara Sea: a new interpretation of the Marmara Sea (Izmit) earthquake on 17 August 1999

Active faults aligning in NW–SE direction and forming flower structures of strike-slip faults were observed in shallow seismic data from the shelf offshore of Avcılar in the northern Marmara Sea. By following the parallel drainage pattern and scarps, these faults were traced as NW–SE-directed lineaments in the morphology of the northern onshore sector of the Marmara Sea (eastern Thrace Peninsula). Right-lateral displacements in two watersheds of drainage and on the coast of the Marmara Sea and Black Sea are associated with these lineaments. This right-lateral displacement along the course of these faults suggests a new, active strike-slip fault zone located at the NW extension of the northern boundary fault of the ?ınarcık Basin in the Marmara Sea. This new fault zone is interpreted as the NW extension of the northern branch of the North Anatolian Fault Zone (NAFZ), extending from the ?ınarcık Basin of the Marmara Sea to the Black Sea coast of the Thrace Peninsula, and passing through B üy ük ?ekmece and K ü ? ük ?ekmece lagoons. These data suggest that the rupture of the 17 August 1999 earthquake in the NAFZ may have extended through Avcılar. Indeed, Avcılar and İzmit, both located on the Marmara Sea coast along the rupture route, were strongly struck by the earthquake whereas the settlements between Avcılar and İzmit were much less affected. Therefore, this interpretation can explain the extraordinary damage in Avcılar, based on the newly discovered rupture of the NAFZ in the Marmara Sea. However, this suggestion needs to be confirmed by further seismological studies.     

Trace element distributions in coastal waters along the US-Mexican boundary: relative contributions of natural processes vs. anthropogenic inputs

Trace element concentrations (Pb, Cd, Mn, Fe, and Zn) were measured along four surface water transects across the continental shelf off Baja California, to evaluate the magnitude of heavy metal contamination in the coastal waters along the US-Mexican boundary. These initial measurements of trace elements in Mexican neritic waters revealed offshore concentration gradients, with the highest levels in coastal waters with high salinities and nutrient concentrations. There were also longshore gradients, with lower concentrations in the southern locations. Although the relative enrichment of metals detected at nearshore stations along the US-Mexican border appeared to correspond to wastewater discharges in that area, these trace metal enhancements were found to be primarily associated with physical oceanographic processes (upwelling and advection), rather than anthropogenic inputs. This was demonstrated both by metal-nutrient correlations and multivariate statistical analyses. Mass balance calculations also indicated that about 1% of Cd, 9% of Zn, and 29% of Pb were from urban discharges within the area.     

Chalk shore platform erosion in the vicinity of sea defence structures and the impact of construction methods

Erosion of the intertidal chalk platform in the vicinity of groynes and seawalls is evident to the naked eye along many stretches of the engineered coastline of southeast England, leading to undermining and eventually failure of these structures. However, quantification of the magnitude and spatial extent of the erosion has been difficult to date because of a lack of data about the past elevation of the platform. The application of softcopy photogrammetry makes it possible to recreate past platform elevations from historic air photographs and to compare these with elevations from modern air photographs. Coastal sea defence structures have been installed along the chalk coast east of Brighton at various dates over the past 70 years. During this period, the construction methods have changed from predominantly manual labour to a reliance on heavy machines. The analysis of erosion patterns around structures built since the 1970s using heavy machinery show that surface lowering is 4 to 25 times greater in the vicinity of these structures than across the platform as a whole. In contrast, there is no similar pattern of increased erosion around structures built using predominantly manual labour in the 1930s. A four fold increase in average surface lowering is found also along a vehicle trackway that crosses the mid platform. Depressions developed by enhanced lowering in the front of seawalls generate their own dynamic of increased erosion by trapping pebbles and cobbles that enhance the abrasion of the chalk through bedload transport under standing waves in front of the walls.     

Vertical variations of the chlorophyll maximum during a red tide in a shallow lagoon

The results of eight sets of repeated observations on the vertical variations of the chlorophyll maximum layer in a shallow lagoon during a red tide show that these were more frequently hydrologically induced, rather than due to active vertical migrations of the red tide-forming organism. These results are discussed and compared to those existing in the literature, with special regard to the role of light and nitrogen in conditioning vertical migrations in red tide-forming dinoflagellates.     

Scaling analysis of deposition from turbidity currents

Many oil-bearing sedimentary deposits are formed by the settling of particles from turbidity currents. Modeling sedimentary processes that form these turbidites enables the calculation of properties such as extent, depth, porosity and permeability of hydrocarbon-bearing reservoirs. This paper estimates the extent and thickness of turbidites from the initial conditions of the turbidity flow. This is achieved by the application of scaling analysis of the partial differential equations that govern the dynamics of and deposition from turbidity currents. We apply the results of scaling analysis to five modern submarine fans. The predicted and actual values of the dimensions of the fan deposits match well. We then compare the derived results against tabulated sizes of ancient turbidites. The comparisons are good as long as we correctly identify the flow regimes in which the deposition took place. The good agreements observed in the two cases show that the estimates obtained using scaling analysis can provide useful first-guess values for the dimensions of the deposits.     

Effects of prolonged exposure to 4-tert-octylphenol on toxicity and indices of oestrogenic exposure in the sand goby (Pomatoschistus minutus, Pallas)

Alkylphenolic compounds are present in estuarine and marine environments. They are moderately bioaccumulative, and oestrogenic to fish following three week, in vivo, exposures. The effects of prolonged exposure are, as yet, unclear. Sand goby (Pomatoschistus minutus) were exposed to measured concentrations of 4-tert-octylphenol (OP) in a 28-day, dose-ranging study, and a six month temporal response study. Following 28-days exposure to measured 31+/-6 or 101+/-47 microg l(-1) OP (mean+/-SD), immature male sand goby showed elevated vitellogenin (VTG) mRNA expression. Plasma alkali-labile phosphate concentrations were elevated in both sexes and were higher in females than males. Although measured OP concentrations were variable, they were significantly different for each treatment and a range of concentration-dependent effects were observed. The LC(50) for chronic OP exposure (8 weeks) was 29+/-6 microg l(-1), and both sexes demonstrated concentration and duration dependent increases in VTG mRNA expression. Exposure to 28+/-20 microg l(-1) OP (median+/-95% CI) for 6 months inhibited development of male nuptial colouration and sperm duct glands. These findings are discussed in relation to environmental concentrations of alkylphenols and ecological concerns.     

Processes Causing the Temporal Changes in Si/N Ratios of Nutrient Consumptions and Export Flux during the Spring Diatom Bloom

Two processes are generally explained as causes of temporal changes in the stoichiometric silicon/nitrogen (Si/N) ratios of sinking particles and of nutrient consumption in the surface water during the spring diatom bloom: (1) physiological changes of diatom under the stress of photosynthesis of diatom and (2) differences of regeneration between silicon and nitrogen. We investigated which process plays an important role in these changes using a one-dimensional ecosystem model that explicitly represents diatom and the other non-silicious phytoplankton. The model was applied to station A7 (41°30′ N, 145°30′ E) in the western North Pacific, where diatom regularly blooms in spring. Model simulations show that the Si/N ratios of the flux exported by the sinking particles at 100 m depth and of nutrient consumptions in the upper 100 m surface water have their maxima at the end of the spring diatom bloom, the values and timings of which are significantly different from each other. Analyses of the model results show that the differences of regeneration between silicon and nitrogen mainly cause the temporal changes of the Si/N ratios. On the other hand, the physiological changes of diatoms under stress can hardly cause these temporal changes, because the effect of the change in the diatom's uptake ratio of silicon to nitrogen is cancelled by that in its sinking rate.