Polar constituents isolated from Green River oil shale

This paper interprets the mass spectrometric, i.r. absorption and NMR data for 22 compounds obtained from a polar fraction of Green River shale. The major constituents analyzed are believed to be of the following compositional types: C_nH_2nO (cyclohexanols and chain isoprenoid ketones), C_nH_2n?10O (tetralones and indanones), C_nH_2n?7N (tetrahydroquinolines), C_nH_2n?11N (quinolines), C_nH_2n?1NO (alkoxypyrrolines), C_nH_2n?5NO₂ (maleimides), C_nH_2n?8 (tetralins), C_nH_2n?12 (naphthalenes) and C_nH_2n?14 (benzylbenzenes). This work expands the present information about nitrogen, oxygen and aromatic constituents indigenous to Green River shale.     

Stately home geology: Kelmscott Manor,Oxfordshire, UK

Kelmscott Manor on the banks of the Upper Thames in Oxfordshire is a place of pilgrimage for social historians and conversationalists as well as those who simply want to turn the clock back to a rural England long departed. The manor was leased to William Morris in 1871 to be his family home until long after his death in 1896—their escape from the hectic daily life in London. At that point, Morris spent the previous 10 years building up the crafts business for which he is best known, the patterned textiles and wallpaper designs and the basic wooden furniture we associate with the Arts and Crafts Movement. It can be difficult to remember that much of the respected craftwork was generated in the East End of London by gifted craftsmen.     

The red bed controversy revisited: shape analysis of Colorado Plateau units suggests long magnetization times

Several Triassic and earliest Jurassic sedimentary units from the Colorado Plateau region have distributions of virtual geomagnetic poles (VGPs) that are highly elongate along the path of apparent polar wander (APW). This suggests that the remanent magnetizations measured in these units were acquired over an extended period of time, possibly approaching 35 m.y., and are not precisely coeval with the stratigraphic age of the rock. Comparison with other paleomagnetic studies shows that the observed elongation is not a general attribute of the age of the rock, nor is it related to paleolatitude. The rocks that yield elongate VGP distributions are dominantly red to brown mudstones, and it is possible that their remanence is dominated by a slowly acquired chemical remanent magnetization, as suggested by Larson et al. [J. Geophys. Res. 87 (1982) 1081] and other authors. However, several superficially similar units from the Colorado Plateau have nearly circular VGP distributions. The process by which remanence is acquired in clastic sedimentary rocks merits further study.     

Use of clast shape in determining the sedimentary history of the late devonian keepit conglomerate,Australia

Clasts of the Late Devonian Keepit Conglomerate of northeastern New South Wales, Australia, are predominantly andesites of isotropic nature that lack any apparent initial shape controls. Given adequate time in a particular environment, these clasts could be reasonably expected to develop shapes characteristic of abrasion within that environment.Clasts from both fluvial and marine resedimented conglomerates of the Keepit Conglomerate possess shape characteristics indicative of shaping within a fluvial environment. Maximum projection sphericity, and a plot of sphericity against either the oblate-prolate index or the flatness parameter C/A, were the most useful in indicating fluvial shaping processes. In addition, the $\text{OP}$ Index and the dominant form classes of the Sneed and Folk Sphericity-Form diagram were in support of a fluvial history for the clasts.The occurrence of clasts exhibiting typical fluvial shapes in marine resedimented conglomerates indicates a lack of time and/or insufficient energy in a beach environment for reshaping of the clasts prior to resedimentation into deeper-water submarine-fan environments. This interpretation is consistent with and lends support to the interpretation, based on all other available data, for the Keepit Conglomerate of a history of rapid progradation of fluvial gravels into a relatively low-energy coastline environment, with periodic resedimentation of coarse sediment into deeper water.     

Single-crystal x-ray diffraction of brucite to 14 GPa

Single-crystal brucite, Mg(OH)₂, was studied to 14 GPa in a quasi-hydrostatic pressure medium using a diamond anvil cell and energy-dispersive synchrotron x-ray diffraction. The parameters of a third-order Birch-Murnaghan equation of state fit to the data are: K _OT=42(2) GPa, and (?K _OT/?P)_T= 5.7(5). The bulk modulus is significantly lower than that obtained in recent shock compression and powder x-ray diffraction experiments under non-hydrostatic conditions. No evidence was found for a transition involving the Mg -O sub-structure over the pressure range of these experiments. This implies that the structural change previously identified at high pressure by Raman spectroscopy probably involves rearrangement of hydrogen atoms, leaving the Mg — O substructure largely unaffected.     

Determination of High Field Strength Elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g−1 Levels in Geological Reference Materials by Magnetic Sector ICP-MS after HF/HClO4 High Pressure Digestion

Six low abundance rock reference materials (basalt BIR-1, dunite DTS-1, dolerite DNC-1, peridotite PCC-1, serpentine UB-N and basalt TAFAHI) have been analysed for high field strength elements (Zr, Nb, Hf, Ta, Th and U), Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels (in rock) by magnetic sector inductively coupled plasma-mass spectrometry after HF/HClO₄ high pressure decomposition. The adopted method uses only indium as an internal standard. Detection limits were found to be in the range of 0.08 to 16.2 pg ml⁻¹ in solution (equivalent to 0.08 to 16.2 ng g⁻¹ in rock). Our data for high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi for the six selected low abundance geological reference materials show general agreement with previously published data. Our Ta values in DTS-1 and PCC-1 (1.3 and 0.5 ng g⁻¹) are lower than in previously published studies, providing smooth primitive mantle distribution patterns. Lower values were also found for Tl in BIR-1, DTS-1 and PCC-1 (2, 0.4 and 0.8 ng g⁻¹). Compared with quadrupole ICP-MS studies, the proposed magnetic sector ICP-MS method can generally provide better detection limits, so that the measurement of high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels can be achieved without pre-concentration, ion exchange separation or other specialised techniques.     

Climatic and environmental reconstructions based on fossil assemblages from middle devensian (Weichselian) deposits of the river Thames at south kensington, central London, UK

Fossiliferous silts within the Late Pleistocene Kempton Park Gravel, of the River Thames Valley, were exposed in 1980 during foundation works for the Ismaili Centre in South Kensington, London. The results of a multidisciplinary study of the geomorphology, sediments, fossil plants, vertebrates, molluscs, ostracods and insects are reported. The silts were deposited under two distinct climatic regimes; a lower unit accumulated when the climate was arctic and an upper when the temperatures were at least as warm as those of the present day. Both these units occupy the same channel system and are separated from one another by less than a metre of sediment, implying that the climatic change was probably sudden and intense. The strongest evidence for this climatic difference comes from a study of the Coleoptera, which show an almost complete replacement of the arctic element in the fauna by a suite of temperate species. Palaeotemperature reconstructions using the Mutual Climatic Range method, based on the coleopteran assemblages from the lower unit, suggest that the mean temperature of the warmest month was 9±2 °C and that of the coldest month −22±10 °C. For the upper unit the mean temperature of the warmest month had risen to about 17 °C and that of the coldest month to about −4 °C. The episode represented by the lower unit, with its arctic climate, had not previously been recognized in the Thames Valley. The fauna from the upper, temperate, unit is very similar to that from other sites in the Kempton Park Gravel, such as that from Isleworth, 10 km upriver, which, like the upper unit at the Ismaili Centre, was characterized by the virtual absence of trees. It would appear that in such cases this treelessness does not indicate cold conditions, equivalent to those of the modern tundra, but may instead result from a combination of ecological and temporal factors. The value of multidisciplinary studies in reaching such conclusions is emphasized.The temperate episode described here is correlated with the thermal maximum at the early part of the Upton Warren Interstadial Complex. An earlier suggestion, based on amino acid epimerization ratios, that the Upton Warren Interstadial correlates with Oxygen Isotope Sub-stage 5a is not supported by the data, which show no evidence of the forested environments that characterized this period in both Britain and the adjacent Continent. It is thought that the temperate deposits at the Ismaili Centre belong to the Middle (Pleniglacial), rather than the Early, Devensian (Weichselian) and are equivalent to Oxygen Isotope Stage 3.     

Detailing the impact of the Storegga Tsunami at Montrose,Scotland

The Storegga tsunami, dated in Norway to 8150±30 cal. years BP, hit many countries bordering the North Sea. Run-ups of >30 m occurred and 1000s of kilometres of coast were impacted. Whilst recent modelling successfully generated a tsunami wave train, the wave heights and velocities, it under-estimated wave run-ups. Work presented here used luminescence to directly date the Storegga tsunami deposits at the type site of Maryton, Aberdeenshire in Scotland. It also undertook sedimentological characterization to establish provenance, and number and relative power of the tsunami waves. Tsunami model refinement used this to better understand coastal inundation. Luminescence ages successfully date Scottish Storegga tsunami deposits to 8100±250 years. Sedimentology showed that at Montrose, three tsunami waves came from the northeast or east, over-ran pre-existing marine sands and weathered igneous bedrock on the coastal plain. Incorporation of an inundation model predicts well a tsunami impacting on the Montrose Basin in terms of replicate direction and sediment size. However, under-estimation of run-up persisted requiring further consideration of palaeotopography and palaeo-near-shore bathymetry for it to agree with sedimentary evidence. Future model evolution incorporating this will be better able to inform on the hazard risk and potential impacts for future high-magnitude submarine generated tsunami events.     

Coleopteran evidence for a mosaic of environments at high altitude in the eastern Pyrénées,France, during the climatic transition between the Allerød and Younger Dryas

Late‐glacial environmental and climatic implications are inferred from an insect fauna from organic sediments infilling a palaeochannel on the banks of the River Têt, eastern Pyrénées, France. A pine cone in association with the insect fauna has been radiocarbon dated to 10 920 ± 60 yr BP, namely close to the Allerød – Younger Dryas boundary. Two distinct insect associations appear to be recognisable here. One is an assemblage typical of the high altitude forest and a second is characteristic of an alpine grassland. The close coexistence of these two assemblages is attributed to the climatic cooling towards the start of the Younger Dryas Stadial, when the forest cover broke up into remnant patches interspersed by alpine grassland. It is suggested that in a region of such high relief a mosaic of habitats may have been caused by patchy differences in insolation aspect, especially during a period of climatic deterioration. Copyright © 1999 John Wiley & Sons, Ltd.