Polyatomic Interferences Produced by Macroelements During Direct Multi-Elemental ICP-MS Hydrochemical Analysis

An experimental study of the interferences produced by macroelements (Na, K, Ca, Mg, Sr, S, Cl, Si, N and C) contained in natural waters during inductively coupled plasma-mass spectrometry (ICP-MS) is presented. The most significant interferences created by these elements were found to be SO, CO, CAr, SiH, SiO, NaH, NaAr, MgAr, CaO, KO and KAr, the magnitude of which was dependant on the concentration of each macroelement. To reduce these interferences, different approaches, for example, desolvating nebulisation, high resolution and dynamic reaction cell ICP-MS were applied and compared. All three approaches were found to be useful tools for significantly reducing various polyatomic interferences. Advantages and disadvantages for each approach are discussed.     

Sakurai's object: the ionized nebula at radio wavelengths

Sakurai's object (V4334 Sgr) is a planetary nebula nucleus which is undergoing its final helium shell flash. This is the first of these rare and important events to be observable with non-optical instruments. We report the first radio detection, using a short (2-h) observation with the Very Large Array (VLA) at 4.86 GHz. The radio emission structure is coincident with the 34-arcsec diameter planetary nebula seen in optical emission lines. We find a statistical distance ∼ 3.8 ± 0.6 kpc, with a range of 1.9 <  D  < 5.3 kpc, depending on the planetary nebula (PN) mass. While we have no direct evidence for a new (post-flash) stellar wind, we estimate an upper limit to the mass-loss rate due to any such wind of 1.7 × 10⁻⁷ M⊙ yr⁻¹. The number of emitting knots in the radio-visible nebula indicates an electron density of ∼ 2 × 10⁸ m⁻³ in those knots, and a total emitting ionized mass of ∼ 0.15 M⊙, at an assumed distance of 3.8 kpc. The radio flux density indicates an Hβ flux of ∼ 6 × 10⁻¹⁶ W m⁻², suggesting an extinction E ( B  −  V ) ∼ 1.15, comparable with reddening estimates in the direction of V4334 Sgr.     

Infrared spectroscopy of Sakurai's object

We present near (ground-based) and far ( ISO ) infrared spectroscopy of Sakurai's object. As in the case of the optical spectrum, between 1996 and 1997 April the near-infrared spectrum underwent a dramatic change to later spectral type, and there is some evidence that the spectrum continued to evolve during 1997. Molecular features of carbon-bearing molecules (CN, C₂, CO) — corresponding to those seen in cool carbon stars — are now prominent in the 1–2.5 μ m range, and the ¹²C/¹³C ratio is low. The ISO data demonstrate the presence of hot circumstellar dust at a temperature of ∼ 680 K. If the dust shell is optically thin, the dust mass is ∼ 2.8 × 10⁻⁸ M⊙.     

An algorithm for generating stochastic cloud fields from radar profile statistics

An algorithm is described for generating stochastic three-dimensional (3D) cloud fields from time–height fields derived from vertically pointing radar. This model is designed to generate cloud fields that match the statistics of the input fields as closely as possible. The major assumptions of the algorithm are that the statistics of the fields are translationally invariant in the horizontal and independent of horizontal direction; however, the statistics do depend on height. The algorithm outputs 2D or 3D stochastic fields of liquid water content (LWC) and (optionally) effective radius. The algorithm is a generalization of the Fourier filtering methods often used for stochastic cloud models. The Fourier filtering procedure generates Gaussian stochastic fields from a “Gaussian” cross-correlation matrix, which is a function of a pair of heights and the horizontal distance (or “lag”). The Gaussian fields are nonlinearly transformed to give the correct LWC histogram for each height. The “Gaussian” cross-correlation matrix is specially chosen so that, after the nonlinear transformation, the cross-correlation matrix of the cloud mask fields approximately matches that derived from the input LWC fields. The cloud mask correlation function is chosen because the clear/cloud boundaries are thought to be important for 3D radiative transfer effects in cumulus.The stochastic cloud generation algorithm is tested with 3 months of boundary layer cumulus cloud data from an 8.6-mm wavelength radar on the island of Nauru. Winds from a 915-MHz wind profiler are used to convert the radar fields from time to horizontal distance. Tests are performed comparing the statistics of 744 radar-derived input fields to the statistics of 100 2D and 3D stochastic output fields. The single-point statistics as a function of height agree nearly perfectly. The input and stochastic cloud mask cross-correlation matrices agree fairly well. The cloud fractions agree to within 0.005 (the total cloud fraction is 18%). The cumulative distributions of optical depth, cloud thickness, cloud width, and intercloud gap length agree reasonably well. In the future, this stochastic cloud field generation algorithm will be used to study domain-averaged 3D radiative transfer effects in cumulus clouds.     

Grain growth and inclusion formation in partially molten carbonate rocks

To learn more about the kinetics and mechanisms of coarsening and melt inclusion formation, we investigated the effects of melt content, viscosity, and topology on the microstructural evolution of partially molten and melt-free calcite aggregates. Synthetic marbles with eutectic melts were produced by annealing mixtures of calcite and either calcium hydroxide or lithium carbonate for up to 80 h at a confining pressure of 300 MPa and temperatures of 973-1,023 K. The melts produced in the two systems are expected to differ significantly in viscosity. Generally, coarsening rates decrease with increasing melt fraction, probably because the diffusion length across melt pockets increases. Analysis of grain shapes in the samples with about 40% melt indicated that coarsening was accommodated by agglomeration in the samples of the calcium/lithium carbonate system. In the calcium carbonate/hydroxide system, classical Ostwald ripening occurred. For melt contents about 10% and below, melt-filled pores are either dropped from or dragged along with migrating grain boundaries, depending on the pore size and the grain boundary curvature. These data can be used to constrain the conditions where fluid or melt inclusions form under natural conditions. Combining our results and previous studies illustrates a systematic relation between the grain boundary mobility in calcite aggregates and the diffusion kinetics associated with second phases residing on the grain boundaries. In particular, boundaries with no porosity are most mobile, those boundaries dragging melt-filled pores are slower, those with gas-filled pores are slower yet, and those containing solid phases are slowest or may even be motionless.     

The Source Mechanism of the Athens Earthquake,September 7, 1999, Estimated from P Seismograms Recorded at Long Range

On 7 September, 1999, an earthquake (5.8 m_b ^USGS)took place about 20 km from the centre of Athens, until then a seismically quiet region ofeastern Greece. Considerable damage ranging from rock falls to the collapse of reinforcedconcrete structures was reported in the city and surrounding area. No surface break which couldbe directly attributed to rupture on the fault plane was mapped. We use the relativeamplitude method and forward modelling of broadband P seismogramsrecorded at long range to produce a two-dimensional model of the source. We conclude that the earthquake tookplace on a south-west dipping normal fault at a depth of 10 km. This implies that the depthof the seismogenic zone in the area is comparable to other more active regions of Greece.The rupture speed (2.1 km/s) and stress drop (0.54 MPa) are low and are typical of earthquakesin a tectonic environment dominated by high rates of extension. The estimated seismicmoment is 6.014 × 10¹⁷ N m. We have investigated reported rupture directivity and thepossibility of a circular rupture is also examined. Extrapolation of the fault plane to the freesurface suggests that the earthquake took place on a structure associated with the Fili fault.     

Structures in the Iranides of South-eastern Turkey

The effects of two phases of deformation in Cretaceous rocks of the Alpine Orogenic Zone of south-eastern Turkey are described. These can be correlated with the late Cretaceous and Tertiary phases of deformation already known from the zone of foreland folding to the south. Some details of the stratigraphical succession are given and a previously unrecorded development of Oligocene rocks is described. The upper Cretaceous sediments are dominantly marine carbonates but include a red bed formation. Basic volcanics are intercalated with the lower carbonate beds. A profound unconformity separates the Eocene from the Upper Cretaceous. This unconformity results from uplift consequent upon the first phase of deformation which produced north-westward plunging folds and related thrusts. Some of these north-westerly folds have been considerably modified by the superposition of younger east-north-easterly trending Alpine folds and thrusts.

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Zusammenfassung Die Effekte zweier Verformungsphasen im Kreidegestein der alpidischen orogenetischen Zone im Südosten der Türkei werden beschrieben. Diese können mit den schon bekannten Verformungsphasen der Oberkreide und des Tertiärs in der Vorlandfaltungszone im Süden zusammen betrachtet werden. Einzelheiten über die Stratigraphie werden angegeben, und die Ausbildung oligozäner Gesteine wird zum ersten Mal beschrieben. Die Sedimente der Oberkreide bestehen zum größten Teil aus marinen Karbonaten, enthalten aber eine rote Formation. In den unteren Karbonatschichten ist basisches vulkanisches Gestein zwischengelagert. Eine erhebliche stratigraphische Diskordanz stammt aus einer Hebung, die der ersten Verformungsphase folgte, in der nach Nordwesten abtauchende Falten und verwandte Aufschiebungen entstanden. Diese Falten sind zum Teil überprägt von jüngeren ostnordöstlich streichenden alpidischen Falten und Aufschiebungen, die sie wesentlich veränderten.

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Résumé Les auteurs décrivent les effets des deux phases de déformation des roches crétaciques de la zone orogénique alpine du sud-est de la Turquie. On peut les mettre en corrélation avec les phases de déformation, déjà connues, du Crétacique supérieur et du Tertiaire dans la zone de plissement de l'avant-pays au sud. Les auteurs donnent quelques détails sur la succession stratigraphique et décrit pour la première fois le développement des roches oligocènes. Les sédiments du Crétacique supérieur sont surtout des carbonates marins, mais comprennent toutefois une formation rouge. Des roches volcaniques basiques sont intercalées dans les couches carbonatées inférieures. Une discordance nette sépare l'Eocène du Crétacique supérieur; elle résulte du soulèvement succédant à la première phase de déformation qui produisit les plis plongeant au nord-ouest et les chevauchements apparentés. Ces plis ont été en partie remaniés par des plis et des chevauchements alpins plus jeunes, de direction est-nord-est, qui les ont fortement modifiés.

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Widespread occurrence of magnesiocummingtonite in ultramafic schists,Cima di Gagnone,Ticino, Switzerland

Abundant magnesiocummingtonite (space group P2₁/m) with Mg/(Mg+Fe) ratios between 0.85 and 0.89 occurs in lenses of schistose metaperidotite enclosed in kyanite-zone rocks of the Lepontine Alps, Ticino, Switzerland. It forms prisms and needles that extend homoaxially from cores of tremolite. Coexisting magnesian phases are olivine, orthopyroxene, talc, magnesite, and chlorite. Except for γ∶z, optical and structural properties of one example fall on extrapolations of existing determinative curves. Analogous to synthetic F-clinoamphiboles, zz∶z has a maximum at approximately 0.7 Mg/(Mg+Fe). Anthophyllite, of almost identical composition, occurs in the same region, often intergrown with cummingtonite along lamellae ‖(010) and ‖(100). Cummingtonite is believed to have partially inverted to anthophyllite during cooling.