Organochlorine pesticides in soil and air at and around a compound contaminated site: vertical distribution,soil–air exchange and risk evaluation

The control of soil pollution in China has become an issue, and in this study, a compound contaminated site was selected and focus on the site and its nearby environment, organochlorine pesticides (OCPs) were investigated in both soil (top and deep soil) and air samples. The main pollutants in top soils at site are dichlorodiphenyltrichloroethane (DDTs, 0.05–104 mg/kg d.w., avg: 14.5 mg/kg d.w.) and hexachlorobenzene (HCB, 0.02–4.85 mg/kg d.w., avg: 0.72 mg/kg d.w.) which is in accordance with its production history. As for the deep soils, ΣOCPs at site were found concentrated at workshops especially the technical pesticide workshop (5.29–22.1 mg/kg d.w., avg: 9.15 mg/kg d.w.) and the history DDTs’ workshop (4.00–64.8 mg/kg d.w., avg: 20.4 mg/kg d.w). Around site, OCPs were mainly concentrated at layers of −20 cm and the −40 cm and decreased with distance being far away, at 5000 m, the ΣOCPs was comparable with normal agriculture soil (22.1−91.4 ng/g d.w., avg: 55.4 ng/g d.w.). ΣOCPs in the air samples ranged 64.6–823 ng/m³ (avg: 459 ng/m³) at site and 9.93–176 ng/m³ (avg: 50.8 ng/m³) around site which are all dominated with DDTs and HCHs. Soil–air exchange fugacity was calculated to judge the transportation of the OCPs and the results showed soils at the site and its nearby areas (within 5000 m) are releasing most of the OCPs into air, and accordingly through evaluation, inhalation was found to be the major source for human health risk, which is a great threat to the workers at site and the nearby residents.

     

Modeling lateral circulation and its influence on the along-channel flow in a branched estuary

A numerical modeling study of the influence of the lateral flow on the estuarine exchange flow was conducted in the north passage of the Changjiang estuary. The lateral flows show substantial variabilities within a flood-ebb tidal cycle. The strong lateral flow occurring during flood tide is caused primarily by the unique cross-shoal flow that induces a strong northward (looking upstream) barotropic force near the surface and advects saltier water toward the northern part of the channel, resulting in a southward baroclinic force caused by the lateral density gradient. Thus, a two-layer structure of lateral flows is produced during the flood tide. The lateral flows are vigorous near the flood slack and the magnitude can exceed that of the along-channel tidal flow during that period. The strong vertical shear of the lateral flows and the salinity gradient in lateral direction generate lateral tidal straining, which are out of phase with the along-channel tidal straining. Consequently, stratification is enhanced at the early stage of the ebb tide. In contrast, strong along-channel straining is apparent during the late ebb tide. The vertical mixing disrupts the vertical density gradient, thus suppressing stratification. The impact of lateral straining on stratification during spring tide is more pronounced than that of along-channel straining during late flood and early ebb tides. The momentum balance along the estuary suggests that lateral flow can augment the residual exchange flow. The advection of lateral flows brings low-energy water from the shoal to the deep channel during the flood tide, whereas the energetic water is moved to the shoal via lateral advection during the ebb tide. The impact of lateral flow on estuarine circulation of this multiple-channel estuary is different from single-channel estuary. A model simulation by blocking the cross-shoal flow shows that the magnitudes of lateral flows and tidal straining are reduced. Moreover, the reduced lateral tidal straining results in a decrease in vertical stratification from the late flood to early ebb tides during the spring tide. By contrast, the along-channel tidal straining becomes dominant. The model results illustrate the important dynamic linkage between lateral flows and estuarine dynamics in the Changjiang estuary.     

Acoustic reflection well logging modeling using the frequency-domain finite-element method with a hybrid PML

In this paper, we propose a hybrid PML (H-PML) combining the normal absorption factor of convolutional PML (C-PML) with tangential absorption factor of Mutiaxial PML (M-PML). The H-PML boundary conditions can better suppress the numerical instability in some extreme models. and the computational speed of finite-element method and the dynamic range are greatly increased using this HPML. We use the finiteelement method with a hybrid PML to model the acoustic reflection of the interface when wireline and well logging while drilling (LWD), in a formation with a reflector outside the borehole. The simulation results suggests that the PS- and SP- reflected waves arrive at the same time when the inclination between the well and the outer interface is zero, and the difference in arrival times increases with increasing dip angle. When there are fractures outside the well, the reflection signal is clearer in the subsequent reflection waves and may be used to identify the fractured zone. The difference between the dominant wavelength and the model scale shows that LWD reflection logging data are of higher resolution and quality than wireline acoustic reflection logging.     

Sedimentary and geochemical evidence of Eocene climate change in the Xining Basin,northeastern Tibetan Plateau

The northeastern Tibetan Plateau began to grow during the Eocene and it is important to understand the climatic history of Asia during this period of so-called ‘doubthouse' conditions. However, despite major advances in the last few decades,the evolutionary history and possible mechanisms of Eocene climate change in the northeastern Tibetan Plateau remain unclear.The Xining Basin in the northeastern Tibetan Plateau contains a continuous sequence of Early to Late Eocene non-marine sediments which provides the opportunity to resolve long-term climate changes during this period. In this study, we report the results of analyses of lithofacies, sediment color and geochemistry of bulk samples collected from the Xijigou section of the Xining Basin. An abrupt lithofacies change between the Early(~52–40 Ma) and Late Eocene(~40–34 Ma) indicates a change in the depositional environment from a shallow lake to a playa lake in response to a significant climatic shift. During ~52–40 Ma,higher values of sediment redness(a*), redness/lightness(a*/L*) and higher modified Chemical Index of Weathering(CIW′)indicate a relatively warm and humid climate, while from ~40–34 Ma the lower values of a*, a*/L*and lower CIW′ imply subhumid to semi-arid climatic conditions. The paleoclimatic records indicate a long-term(~52–34 Ma) trend of decreasing chemical weathering, consistent with global climate change. An abrupt sharp excursion of the proxy records during ~42–40 Ma suggests a relatively brief warm interval, corresponding to the Middle Eocene Climatic Optimum(MECO). We suggest that global cooling substantially reduced humidity in inner Asia, resulting in sub-humid to semi-arid climatic conditions after 40 Ma in the Xining Basin, which may have been responsible for the long-term trend of decreasing chemical weathering during the Eocene.     

青藏高原东南三江流域黄土类堆积体斜坡地震作用下的动力响应试验研究——以四川巴塘下归洼滑坡为例

青藏高原东南三江流域广泛存在堆积体斜坡,该类斜坡极易演化为滑坡灾害。以四川巴塘下归洼斜坡为例,通过振动台模型试验研究地震诱发的堆积体滑坡动力响应特征与破坏模式。试验结果表明,在地震作用初期,由于孔隙被挤密,斜坡的自振频率增大;在茂县波激励下,斜坡肩部动力响应最强烈。高幅值茂县波激励下,因斜坡整体刚度降低,放大效应减弱。Hibert谱描述了地震波在斜坡中的传播特征,向斜坡顶部传播时,地震波高频能量显著增强,地震波经过堆积层后,放大效应减弱。在足以致使堆积层滑动的强震作用下,坡表一定深度下动力响应呈现一致剧烈现象,斜坡上部会形成“脱离体”,“脱离体”在地震作用下上下颠簸运动;在临滑时,坡表出现最强烈的动力响应。斜坡的破坏模式为：地震初期,在重力和地震耦合作用下,坡表土体剥落;随地震幅值增加,坡肩与堆积层发生明显相对位移,堆积层表面出现裂缝;最终,坡脚发生明显相对位移,随后堆积层偏离基岩加速滑塌。基于地震信号特征的斜坡堆积层滑落过程可分为三阶段：(1)稳定阶段;(2)临滑阶段;(3)滑移阶段。     

典型风力条件及水力调度下太湖藻华高频时空动态监测

湖泊藻华问题已成为全球水生态环境领域面临的长期挑战,风力条件变化和引调水工程的水力调度能改变湖体水动力结构,对藻类的生长和聚集过程产生影响,进行该过程的精细化监测和机制分析对于湖泊藻华预报预警和应急处置具有重要意义。本研究基于Hiamwari-8/AHI卫星遥感高频监测数据,对比分析了归一化差异植被指数(NDVI)、增强植被指数(EVI)和浮游藻类指数(FAI) 3种不同指数对太湖藻华的反演效果,开展了典型风力条件下和水力调度下太湖藻华生消过程的持续监测分析。结果表明,FAI对藻华区域和非藻华区域的区分更加明显,其阈值提取的藻华面积与基于MODIS图像解译的藻华面积的相对误差最低,为-2.27%。当营养盐充足且水温持续保持在蓝藻大量生长增殖的阈值以上时,风力条件是导致太湖藻类迁移聚集的关键因子,风向主要影响藻类的水平迁移,使其进行方向性迁移并逐渐形成大面积藻华区域。风速主要影响藻类的垂向迁移并存在临界阈值,当风速低于约2.5 m/s的临界风速时,藻华面积随风速增加而增加;当风速高于临界风速时,藻华面积随风速增加而降低。水力调度对距离较近的贡湖湾区域具有显著影响,主要通过水动力扰动来影响...     

基于双正交小波的遥感图像融合研究

针对多光谱图像与全色图像融合中的光谱失真问题,采用一种双正交小波的方法进行融合。试验证明,该方法可以减少图像的失真问题,提高图像的空间分辨率,保留图像的边缘细节。     

SPOT5遥感影像在土地调查中的应用

本文结合SPOT5卫星影像在某地区土地利用调查中的应用,介绍了利用SPOT5卫星遥感影像进行室内判读、结合外业调查建立土地利用数据库,进行土地利用调查的技术方法和工作流程。     

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中国石化枯竭气藏型储气库注采技术及发展建议

经长输管线输送的天然气注入到地下空间而形成的人工气藏称为地下储气库。国内外现有储气库大多数是枯竭气藏型地下储气库。中国石化储气库建设起步较晚,基础较为薄弱,同时与国内外已建成储气库相比,中石化储气库建设面临的地质条件和注采工况也较为复杂。以中国在建最大储气库项目中原文23储气库为例,其复杂地质条件以及面临的"快瞬变非稳态增压"注采难题需要进行专门研究。分析了目前中石化枯竭型气藏储气库建库现状,提出了建库技术挑战,总结了现阶段取得的注采关键技术研究成果,通过分析中国石化枯竭气藏型储气库注采技术研究现状和最新进展,提出了国产化技术完善、智能化注采营运、一体化模拟实验室的建设等方面的发展建议和要求,为持续加强规模化储气库群建设的支持提供参考。