Characterization of shale matrix pore structure via experiment and model

Shale gas reservoirs develop multi-scale pores ranging in size from nanometer to micrometer, the characteristics of gas transport involve the multi-scale pore space which divided into organic and inorganic matrix pores. This paper reveals the shale pore structure with large amounts of organic mesoporous based on the techniques of focused ion beam scanning electron microscopes (FIB-SEM), high-pressure mercury intrusion (MICP), and low-pressure adsorption (LPA), which also shows the size and distribution of these pores. Then the research characterizes effective pore scale via circular tube bundle model with due regard for gas adsorption layer thickness on the walls of organic pores and water film thickness on the walls of inorganic pores, and the investigation of shale pore geometry is significant for designing and developing shale gas reservoirs. This work shows that the widely existing shale mesoporous volume with diameter of 2~50 nm accounts for 81% based on experimental testing, then it reduces to about 76% via effective diameter model calculation.     

Comparison between the TOPMODEL and the Xin’anjiang model and their application to rainfall runoff simulation in semi-humid regions

To study the application of the TOPMODEL and the Xin’anjiang model to rainfall runoff simulation in semi-humid regions, the Holtan excess infiltration runoff module was added to the TOPMODEL structure. The basin of the Heihe Jinpen Reservoir in Shaanxi Province, China, was selected as the study area. Rainfall and runoff data and digital elevation models were collected. The watershed topographic parameters and 21 floods that occurred from 2005 to 2013 were obtained to simulate rainfall runoff. Results show that the improved TOPMODEL and the Xin’anjiang model can effectively stimulate rainfall runoff. The average values of their Nash coefficient are 0.84 and 0.83, respectively, upon calibration, and 0.78 and 0.80, respectively, upon validation. The Xin’anjiang model performs slightly better than the improved TOPMODEL. The results of large flood peaks are better than those of ordinary floods. Both results can be used to simulate the rainfall runoff of a watershed.     

内蒙古丰镇市泉子沟斑岩钼矿床成岩成矿年代学及其地质意义

泉子沟斑岩钼矿床位于内蒙古丰镇市,地处华北克拉通北缘内蒙古台隆凉城断隆内。矿区出露一套燕山期花岗质杂岩体——红娘山杂岩体,主要由中粗粒花岗岩、似斑状花岗岩和石英斑岩组成,钼矿体主要赋存于似斑状花岗岩中。文章在详细的野外地质调查基础上,对泉子沟矿床的成岩成矿时代进行了详细研究,并探讨了地质意义。5件辉钼矿样品的Re-Os模式年龄介于(158.8±2.2)Ma~(161.5±2.2)Ma之间,其加权平均值为(159.8±1.0)Ma(MSWD=0.92),等时线年龄为(161.7±3.1)Ma(MSWD=1.40)。红娘山杂岩体LA-ICP-MS锆石U-Pb年龄分别为:中粗粒花岗岩结晶年龄为(173±1)Ma(MSWD=0.88),似斑状花岗岩侵位年龄为(162±1)Ma(MSWD=0.40),石英斑岩结晶年龄为(160±2)Ma(MSWD=1.90)。辉钼矿Re-Os和锆石U-Pb定年结果表明,泉子沟钼矿床形成于晚侏罗世早期,成矿与似斑状花岗岩关系密切。泉子沟钼矿床的辉钼矿w(Re)介于16.49×10~(-6)~32.87×10~(-6),暗示成矿物质主要来自下地壳。     

河南崤山金矿床流体包裹体及同位素特征

崤山金矿床位于华北克拉通南缘的豫西地区,矿体大多呈脉状产于断裂带内。成矿期可以划分为3个阶段:(1)石英-黄铁矿阶段;(2)石英-多金属硫化物阶段;(3)石英-碳酸盐阶段。成矿期石英中发育气液两相水溶液包裹体(WL型)和H_2O-CO_2包裹体(C型)。石英-黄铁矿阶段发育WL型和C型包裹体,它们的均一温度为300~393℃,盐度w(NaCl_(eq))为1.6%~11.0%,密度介于0.57~0.82 g/cm~3;石英-多金属硫化物阶段亦发育WL型和C型包裹体,它们的均一温度为261~298℃,盐度w(NaCl_(eq))为1.1%~11.8%,密度介于0.74~0.89 g/cm~3;石英-碳酸盐阶段仅见WL型包裹体,其均一温度为193~258℃,盐度w(NaCl_(eq))介于2.2%~12.7%,密度为0.87~0.97g/cm~3。成矿流体具有中高温、中低盐度、低密度等特征,属于H_2O-NaCl±CO_2体系。崤山金矿石英的δ~(18)OH_2O值介于0.7‰~4.5‰之间,δDV-SMOW值介于-47.8‰~-69.5‰之间。H-O同位素结果表明成矿流体主要来源于岩浆水。矿石硫化物的δ_(34)SV-CDT值为0.7‰~3.9‰,206Pb/204Pb值为17.391~17.728,~(207)Pb/~(204)Pb值为15.420~15.577,~(207)Pb/~(204)Pb值为37.420~37.923。S-Pb同位素结果表明成矿物质主要来源于花岗质岩浆。崤山金矿为中温热液脉型金矿,流体相分离和温度的降低是导致矿质沉淀的主要机制。     

敦煌造山带长山子地区变质演化及年代学研究

长山子地区位于敦煌造山带东北部,瓜州南部约100km处。该区主要出露一套中-高级变质表壳岩,主要岩石类型有长英质片麻岩、变泥质麻粒岩、高压基性麻粒岩、斜长角闪片麻岩。高压基性麻粒岩岩块、斜长角闪片麻岩岩块以构造透镜体或布丁(长度为0. 5~15m)的形式,被夹持于长英质片麻岩、变泥质麻粒岩组成的基质之中,呈现典型"基质夹岩块"的混杂带特征。高压基性麻粒岩、斜长角闪片麻岩、泥质麻粒岩中,普遍保留了二至三个阶段的变质矿物组合。进变质阶段矿物组合(M1)为石榴子石变斑晶中的细小矿物包裹体,变质高峰期矿物组合(M2)为石榴子石变斑晶和基质矿物,退变质阶段矿物组合(M3)主要为围绕石榴子石变斑晶边部发育的"白眼圈"状后成合晶。本区各类变质岩石均记录了顺时针型变质作用P-T轨迹,系典型俯冲-碰撞造山带变质作用特征。退变质阶段P-T轨迹属于西阿尔卑斯型,说明变质岩折返速率较快。变质高峰期(M2)属于中压变质相系,P-T条件分别为790~870℃/1.29~1.37GPa(高压基性麻粒岩)、680~685℃/0.89~0.97GPa(斜长角闪片麻岩)、860~880℃/0.90~1.14GPa(变泥质麻粒岩),它们之间存在大的差异。这说明,它们是形成于同一俯冲隧道内不同深度的变质岩石,在构造折返阶段才混杂在一起形成构造混杂岩。二次离子质谱(SIMS)锆石U-Pb定年表明,长山子地区变质杂岩记录了早泥盆世的俯冲事件(419~417Ma)。     

东昆仑五龙沟金矿田控矿构造带的变形条件——来自EBSD组构的启示

五龙沟金矿田是东昆仑地区最重要的金矿集中区之一,金矿田主要控矿构造为偏脆性断裂破碎带,在三条控矿构造带中仅在萤石沟—红旗沟构造带邻近北侧的局部出露韧性变形带。本文作者运用电子背散射衍射技术(EBSD)技术方法,对东昆仑五龙沟金矿田萤石沟—红旗沟构造带变形岩石的组构分析显示,花岗质糜棱岩韧性变形强烈,大部分样品石英变形机制是以中温I级柱面(1010)1120滑移为主,变形式样比较单一;少量样品为中高温II级柱面(101—0)0001滑移和中低温底面(0001)112—0滑移。从岩石组构特点结合宏观构造分析,五龙沟金矿田萤石沟—红旗沟构造带及其邻近北侧经历了中-中深层次、中-中高温条件(15~25 km,t=350~550°C,P=0.40~0.60 Gpa)的韧性变形,局部叠加中浅层次、中低温条件(10~15 km,t=250~350°C,P=0.25~0.40 Gpa)的韧脆性变形;而岩金沟和三道梁—苦水泉构造带为低温低压条件的脆性破碎带。结合变形花岗闪长岩年代学资料,确定构造变形时代为早中生代。     

微山湖流域高氟地下水的成因分析

依据2006—2016年间采集的区内475件地下水无机分析数据以及钻探岩心易溶盐测试数据,详细研究了微山湖流域高氟地下水的分布特征和富集机制。结果表明:微山湖流域高氟地下水的分布有明显的东西分区特征,湖西冲积、湖积平原区有大范围的高氟地下水,在深度0—40 m的浅层孔隙地下水中,氟含量以1~2 mg/L为主,仅现代黄河影响带地下水氟含量小于1 mg/L,金乡、单县、嘉祥局部超过3 mg/L,最大值9.5 mg/L;在深度150—400 m的深层孔隙地下水中,氟含量以1~1.5 mg/L为主,菏泽—单县条带氟含量超过2 mg/L,最大值3.5 mg/L。微山湖东冲积、洪积平原浅层孔隙地下水、深层岩溶地下水氟含量均小于1 mg/L。湖西冲积、湖积平原沉积物中可溶性氟含量随深度增加而降低。微山湖流域湖西高氟地下水形成受物质来源、淋滤和蒸发浓缩等三方面因素共同控制,CaF_2的溶解平衡是控制地下水F–含量的重要因素。     

Zircon U-Pb Geochronology,Geochemistry and Petrogenesis of Early Cretaceous A-type Granites in the Mikengshan Area,Southern Jiangxi ProvinceEI北大核心CSCD

In the Mikengshan-Yanbei area, a special region for the tin mineralization in South China, there are some Yanshanian granites and porphyries and associated porphyry tin deposits (e.g., Yanbei). Although the tin mineralization is closely associated with the granitoids magmatism, the age and petrogenesis of the granites remain controversial. The Mikengshan pluton, which intrudes into the rhyolitic tuff and pyroclastic rocks of the Upper Jurassic Jilongzhang Formation, is the largest one in Mikengshan-Yanbei area and mainly consists of K-feldspar bearing granites. In this study, we report new age and geochemical data for the Mikengshan K-feldspar bearing granites. LA-ICP-MS zircon U-Pb age dating shows that they were generated in the Early Cretaceous (~138 Ma). They have high SiO2 (74.42% to 76.69%), low Al2O3 (12.39% to 13.49%) and Mg# (11 to 19), and negative Eu, Sr and Ba anomalies, and are rich in potassium (most K2O/Na2O=1.37 to 1.94) and high field strength elements (HFSEs), and are weakly peraluminous (A/CNK=1.03 to 1.1) with high 10000×Ga/Al ratios (3.46 to 4.96) and slightly high zircon saturation temperatures (807 ℃ to 817 ℃), showing the characteristics of the typical A-type granites. Moreover, they have high Rb contents 842×10-6 to 1295×10-6, Rb/Sr (90 to 255) ratios and show rare earth elements (REE) tetrad effect, which are similar to those of high fractionated granites. Thus, we suggested that the Mikengshan K-feldspar bearing granites are high fractionated and aluminous A-type granite. Their slightly high εNd(t) values (-3.4 to -4.6) indicate that the mantle components should have played a role during their formation. Taking into account regional igneous rocks and tectonic setting data, we suggest that the Mikengshan K-bearing granites were formed in an extensional setting, which was probably related to the roll-back of the subducted Paleo-Pacific plate. © 2018, Science Press. All right reserved.     

太平洋年代际振荡、大西洋年代际振荡和全球变暖对北美地区降水的相对贡献

本文研究了1934～2018年期间太平洋年代际振荡（Interdecadal Pacific Oscillation,IPO）、大西洋年代际振荡（Atlantic Multidecadal Oscillation,AMO）以及全球变暖（Global Warming,GW）对北美地区陆地降水年代际变化的相对贡献。首先通过对冬（12至次年2月）、夏季（6～8月）北美地区的陆地降水与中低纬地区的海表面温度进行奇异值分解分析,得到对北美陆地冬季降水相对贡献较大的主要海温模态为IPO（42.33%）和AMO（23.21%）,夏季则为AMO（32.66%）和IPO（21.60%）。其次利用线性回归模型,分析三种信号分别对北美冬、夏季陆地降水的相对贡献及对北美陆地不同区域降水的相对重要性,结果表明AMO对夏季北美陆地降水变化的贡献最大,IPO次之,冬季则相反,GW对冬夏季北美陆地降水都有一定的贡献。夏季期间阿拉斯加地区AMO的贡献最大,约占65.8%,加拿大地区GW的贡献最大,约占44.5%,美国本土及墨西哥地区三者贡献基本一致;冬季期间阿拉斯加和加拿大地区GW的贡献最大,分别为62.3%和44.7%,美国本土和墨西哥地区IPO的贡献最大,分别为47.9%和71.5%。进一步利用信息流方法,验证了IPO、AMO、GW对降水的敏感性区域。最后运用全球大气环流模式ECHAM 4.6进一步确定了太平洋和大西洋海温异常对北美地区陆地降水变化的影响途径,结果表明印度洋海表面温度异常在AMO和IPO对北美陆地降水变化的作用中至关重要。