Riddle of arsenic in groundwater of Bengal Delta Plain—role of non-inland source and redox traps

In the Bengal Delta Plain (BDP) the primary arsenic sourcing appears to be different from the global scenario. Here, the Terminal Pleistocene–Holocene depositional platform, the interactive early Holocene depositional morphology with fluvio-estuarine and marine incursions played a crucial role for arsenic sourcing and enrichment. The lenticular silt-fine sand layer between anoxic clay beds favoured entrapment of dissolved organic carbon with decayed phyto-planktons debris. The Terminal Pleistocene–Holocene transgression and regression processes may have acted as major events in the BDP. Interestingly, at the end of the last glacial maxima, the Pleistocene delta had undergone block movements, wherein some parts of the platform were raised above the level of Holocene deposition. Those blocks were found to be free from arsenic in the groundwater. The sea, during re-emerging inundation (10–7 ka BP), has witnessed a monsoon-induced environment in the BDP with the resultant oscillation of sea level leading to higher upsurge towards the north. This might have resulted in the marine incursion and inundation in pre-existing land depressions. Meanwhile arsenic entrapments through marine incursion as well as enrichment in the presence of organic carbon/DOC and/or Fe/Mn/Al catalytic agents could have developed into localised redox traps. It may be of relevance that due to the repetitive transgressive–regressive phases in Holocene, resulting in periodic exposure and weathering of iron-bearing minerals and consequent iron enrichment in the aquifer system. The iron, thus present, had free charge to host arsenic as a sink. It appears that arsenic, wherever found, would likely be of atypical localised exhaustible phenomenon, both in horizontal and vertical context. It also rationalises the cause of the absence of arsenic in the other nearby Pleistocene platform, which has not come across Holocene interaction and marine incursion, as to the likely limiting condition for the search for arsenic in the BDP or beyond.     

Cloud — Aerosol interaction during lightning activity over land and ocean: Precipitation pattern assessment

The present study attempts to identify the land - ocean contrast in cloud - aerosol relation during lightning and non-lightning days and its effect on subsequent precipitation pattern. The thermal hypothesis in view of Convective Available Potential Energy (CAPE) behind the land - ocean contrast is observed to be insignificant in the present study region. The result shows that the lightning activities are significantly and positively correlated with aerosols over both land and ocean in case of low aerosol loading whereas for high aerosol loading the correlation is significant but, only over land. The study attempts to comprehend the mechanism through which the aerosol and lightning interact using the concept of aerosol indirect effect that includes the study of cloud effective radius, cloud fraction and precipitation rate. The result shows that the increase in lightning activity over ocean might have been caused due to the first aerosol indirect effect, while over land the aerosol indirect effect might have been suppressed due to lightning. Thus, depending on the region and relation between cloud parameters it is observed that the precipitation rate decreases (increases) over ocean during lightning (non-lightning) days. On the other hand during non-lightning days, the precipitation rate decreases over land.     

On conformity of the EEJ based ionospheric model to the fountain effect and resulting improvements

The total electron content (TEC) of the equatorial ionosphere is controlled by photochemical processes as well as the transport of the ionospheric plasma near the magnetic equator. The transport phenomenon is initiated by the vertical drift driven by the eastward electric field, which also drives the Equatorial Electrojet. The empirical relation between the Equatorial Electrojet and the anomaly component of the equatorial TEC has already been established. Taking this relation as a reference, a simplified physical model of the anomaly component of equatorial TEC is obtained as a function of Equatorial Electrojet. Influence of other factors like the solar incidence angle and the solar flux are also considered here and the extent of their influence are also investigated. This has been done using TEC data obtained from dual frequency GPS receivers during the low solar activity period of 2005. The derived model is based on the physics of the underlying fountain effect and matches with the observed empirical relation to a fair extent. Obtained results are found to corroborate with previous findings and these physical model values are found to have improved correlation with the observed data than the reference empirical relation. This establishes the conformity between the EEJ based ionospheric model and the physical phenomenon of the fountain effect.     

Bottom Simulating Reflector and Gas Seepage in Okinawa Trough： Evidence of Gas Hydrate in an Active Back-Arc Basin

To look for gas hydrate, 22 multi-channel and 3 single-channel seismic lines on the East China Sea (ECS) shelf slope and at the bottom of the Okinawa Trough were examined. It was found that there was indeed bottom simulating reflector (BSR) occurrence, but it is very rare. Besides several BSRs, a gas seepage was also found. As shown by the data, both the BSR and gas seepage are all related with local geological structures, such as mud diapir, anticline, and fault-controlled graben-like structure. However, similar structural "anomalies" are quite common in the tectonically very active Okinawa Trough region, but very few of them have developed BSR or gas seepage. The article points out that the main reason is probably the low concentration of organic carbon of the sediment in this area. It was speculated that the rare occurrence of gas hydrates in this region is governed by structure-controlled fluid flow. Numerous faults and fractures form a network of high-permeability channels in the sediment and highly fractured igneous basement to allow fluid circulation and ventilation. Fluid flow in this tectonic environment is driven primarily by thermal buoyancy and takes place on a wide range of spatial scales. The fluid flow may play two roles to facilitate hydrate formation:to help gather enough methane into a small area and to modulate the thermal regime.     

A comparative error analysis of manual versus automated methods of data acquisition for algebraic strain estimation

This paper presents a statistical analysis of the algebraic strain estimation algorithm of Shimamoto and Ikeda [Shimamoto, T., Ikeda, Y., 1976. A simple algebraic method for strain estimation from deformed eillipsoidal objects: 1. Basic theory. Tectonophysics 36, 315–337]. It is argued that the error in their strain estimation procedure can be quantified using an expected discrepancy measure. An analysis of this measure demonstrates that the error is inversely proportional to the number of clasts used. The paper also examines the role of measurement error, in particular that incurred under (i) a moment based and (ii) manual data acquisition methods. Detailed analysis of these two acquisition methods shows that in both cases, the effect of measurement error on the expected discrepancy is small relative to the effect of the sample size (number of objects). Given their relative speed advantage, this result favours the use of automated measurement methods even if they incur more measurement error on individual objects. Validation of these results is carried out by means of a simulation study, as well as by reference to studies appearing in previous literature. The results are also applied to obtain an upper bound on the error of strain estimation for various studies published in the literature on strain analysis.     

The evolution of conservation rules and norms in the Maine lobster industry

Natural resources of all kinds have been overexploited by user groups who cannot or will not develop rules to constrain their own exploitive efforts. One notable exception is the Maine lobster industry, where an effective set of conservation laws has been developed due, in great part, to the strong support of the industry. In the early decades of the 20th century, however, the lobster industry was marked by widespread violations of the existing conservation laws and opposition to developing more. This article explores the way that the pirate ethic gave way to the conservation ethic in the 1930s. Our explorations in evolutionary game theory suggest that this change was produced by three factors: costs and benefits of defection from the conservation ethic; numbers of people accepting the conservation ethic quality rule; and events that shocked the system from one state to another. We argue that the shock to the system in the late 1920s and 1930s was caused by massive stock failure which changed the attitudes of many fishermen about the need for conservation. People began to report violations of the law, which made law enforcement more effective and quickly led to a cascade of fishermen abandoning the pirate ethic. In the late 1930s, increasing catches, in combination with a number of other social, technical, and economic factors continued the upward spiral.     

A simplified computational approach for prediction of transient climatic conditions in underground mine airways

Summary A simplified approach for prediction of transient climatic conditions in an underground airway os presented. The dry surface temperature of the airway is calculated using a finite difference scheme, whereas the wet surface temperature is determined following the concept of pseudo-base-temperature of air and using the value of thermal gradient at the dry surface as obtained from the finite difference solution of the temperature profile in the dry rock. The air-current temperatures are regularly evaluated after a suitable time span so as to simulate a real-case situation, and the re-evaluated air-current temperatures are used for further calculations. For increasing age of the airway the wet surface temperature obtained by the finite difference scheme, with an appropriate value of thermal diffusivity, is compared with its value determined by the pseudo-base-temperature approach.     

Mössbauer studies of marine and fresh water manganese nodules

Practically identical Mössbauer spectra have been obtained for 40 ferromanganese nodules from a wide variety of marine and fresh-water locations. None of the nodules examined contains more than one weight percent Fe²⁺, so no more than a few percent of the total iron in these nodules can be Fe²⁺. Most of the iron is present as Fe³⁺ in paramagnetic or superparamagnetic oxide phases, although hysteresis loops show the presence of small amounts of ferromagnetic phases not detected by the Mössbauer technique.     

Wind-forced continental shelf waves from a geographical origin

The response of a barotropic coastal ocean on a step-shaped continental shelf to a traveling sinusoidal wind stress forcing is predicted theoretically using a frictional force proportional to the alongshore current velocity. This theory is compared to a small set of observations from the northeast coast of Australia where a sudden widening of the continental shelf provides a geographical origin. The comparison is accomplished by means of frequency response functions relating alongshore wind stress with alongshore velocity. Amplitudes of the response functions are predicted to increase with alongshore distance equatorward and also to decrease with frequency at any location. These predictions are verified by the measurements. Predicted phase lags are generally less than about 30°, with observations agreeing with theory to within about 20°C. In general, the measurements provide reasonable evidence to support the theory of wind-forced continental shelf waves from a geographical origin.     

Continual long-term monitoring of methane in wells above the Utica Shale using total dissolved gas pressure probes

Hydrogeology Journal - Monitoring of dissolved methane concentrations in groundwater is required to identify impacts from oil and gas development and to understand temporal variability under...