The weathering of norite at Black Hill,South Australia

Black Hill is a boulder‐strewn residual of norite standing 45 m above the Murray Plains about 80 km northeast of Adelaide. Between the boulders, the crystalline rock has weathered to a dark‐brown terra rossa‐rendzina soil with calcite, illite, kaolin, and hematite as the principal secondary minerals. At one site on the smooth lower slopes of the outcrop, the material above the norite consists of partially weathered granular fragments with considerable dolomite and some calcite in nodular form. Below the surface, the rock has been weathered along joints to produce the clay mineral nontronite, and between each corestone and this plastic clay there is a zone of laminated but essentially unaltered rock 10–25 cm thick. Pieces of amorphous silica occur sporadically in some joints and on the surface.

The dark‐brown soil appears to be related to the present environment but the nontronite in the joint weathering, the dolomite, and the amorphous silica are all consistent with the norite having been inundated, possibly during the Miocene marine transgression.

Calculations based on the retention of elements such as aluminium, potassium, titanium, and iron have been used to predict quantitatively the amount of certain minerals such as quartz, calcite, and dolomite introduced to the weathering profiles.     

Stormwater management network effectiveness and implications for urban watershed function: A critical review

Deleterious effects of urban stormwater are widely recognized. In several countries, regulations have been put into place to improve the conditions of receiving water bodies, but planning and engineering of stormwater control is typically carried out at smaller scales. Quantifying cumulative effectiveness of many stormwater control measures on a watershed scale is critical to understanding how small‐scale practices translate to urban river health. We review 100 empirical and modelling studies of stormwater management effectiveness at the watershed scale in diverse physiographic settings. Effects of networks with stormwater control measures (SCMs) that promote infiltration and harvest have been more intensively studied than have detention‐based SCM networks. Studies of peak flows and flow volumes are common, whereas baseflow, groundwater recharge, and evapotranspiration have received comparatively little attention. Export of nutrients and suspended sediments have been the primary water quality focus in the United States, whereas metals, particularly those associated with sediments, have received greater attention in Europe and Australia. Often, quantifying cumulative effects of stormwater management is complicated by needing to separate its signal from the signal of urbanization itself, innate watershed characteristics that lead to a range of hydrologic and water quality responses, and the varying functions of multiple types of SCMs. Biases in geographic distribution of study areas, and size and impervious surface cover of watersheds studied also limit our understanding of responses. We propose hysteretic trajectories for how watershed function responds to increasing imperviousness and stormwater management. Even where impervious area is treated with SCMs, watershed function may not be restored to its predevelopment condition because of the lack of treatment of all stormwater generated from impervious surfaces; non‐additive effects of individual SCMs; and persistence of urban effects beyond impervious surfaces. In most cases, pollutant load decreases largely result from run‐off reductions rather than lowered solute or particulate concentrations. Understanding interactions between natural and built landscapes, including stormwater management strategies, is critical for successfully managing detrimental impacts of stormwater at the watershed scale.     

A magneto-telluric deep crustal study in south-central Portugal

Summary A geothermal anomaly reported to exist in southern Portugal and with heat flow density values as high as 160 mW/m² was studied by the magneto-telluric method. The results of the magneto-telluric survey indicate that the study area is divided into several high electrical resistivity, deep-rooted blocks separated by low electrical resistivity zones. These latter zones coincide with the main trends of the faults that cross the region. The high heat flow density values reported for the area are incompatible with the high electrical resistivities observed in the magneto-telluric survey. Furthermore, heat production values calculated for some of the rocks that crop out in the area of the geothermal anomaly cannot explain the high heat flow density valuss. Since no hydrothermal activity is known for the region and recent volcanism is absent, it is suggested that previous heat flow density calculations for the area covered by the magnetotelluric survey are overestimated.Presented at International Meeting on Terrestrial Heat Flow and the Structure of Lithosphere, Bechyn Castle, Czech Republic, September 2 – 7, 1991.     

The zonal distribution of hydrogen in the Jovian atmosphere

The Voyager ultraviolet spectrometer disclosed strong longitude variation in the midlatitude Lyman alpha brightness of Jupiter. Minimum brightness of 16 and 14.4 kR were observed from Voyagers 1 and 2, respectively, with the intensity rising to peaks of 21 and 19.6 kR at a longitude near 110°. Observations of Jovian Lyman alpha, made with the International Ultraviolet Explorer (IUE) beginning in December 1978, and continuing through January 1982, also show a region of persistently enhanced but variable flux near a longitude, λ, of 100°; however, IUE measured brightnesses are consistently lower than those of Voyager. Although the Lyman alpha flux from the “normal” region of the plant between λ 200 and 300° remained nearly constant during the period of the IUE observations, that from the “perturbed” region centered on λ 110° varied by ±25% from the mean. The sources of Lyman alpha flux include resonance scattering of solar and interplanetary Lyman alpha, and excitation by charged particle precipitation. That portion of the dayside flux due to charged particle excitation has been variously estimated at between 2.3 and 7 kR. About 1 kR of the dayside flux is due to resonance scattering of the sky background. It is assumed that H and an absorber (CH₄) are distributed above the homopause according to the local height distribution of temperature. The daytime equation of radiative transfer is solved to determine the longitudinal distribution of freely scattering atomic hydrogen that would account for the observed flux. This daytime solution shows that if the hydrogen bulge is the result of localized heating and a consequent increase in scale height, the temperature in the perturbed region must be about 100°K warmer than that in the normal region. The nightside Lyman alpha brightness exhibits a longitude variation very similar to that on the dayside. The H distribution derived from the dayside solution is used with the nightside flux to estimate the longitude variation of particle precipitation on the nightside.     

Ground water flow parameterization of an Appalachian coal mine complex

We examined a large (240 km2) northern Appalachian bituminous coal basin (Irwin Syncline, Westmoreland County, Pennsylvania) comprising 27 mine complexes with nine major (> 2.5 x 10(3) L/min) discharges. The synclinal basin was divided into seven subbasins based on equilibrium hydraulic relationships established during the past 25 years. Recharge rates, mine pool velocity, and residence times respond to hydraulic changes in the overburden induced by mine subsidence. The estimated maximum depth for subsidence fractures is 60 m (30 times mined thickness) with recharge rates decreasing significantly in subbasins with thicker overburden (> 75 m). Calculated subbasin recharge rates range from 2 to 6 x 10(-4) L/min/m2 and are significantly lower than the previously used rate for the basin. Residence time of ground water in the Irwin subbasins calculated using average linear velocity ranged from one to five years and were more consistent with field observations than estimates obtained using discharge and basin volume area. A positive correlation (r2 = 0.80) exists between net alkalinity of the mine water-impacted discharges and residence time in the mine pools. Our results for the Irwin coal basin suggest that use of a subbasin approach incorporating overburden depth, mining methodology, and the extent of postmining inundation will lead to improved determination of ground water flow parameters in mined watersheds in northern Appalachia and elsewhere.     

Electrochemical study of hydrothermal and sedimentary pyrite dissolution

The dissolution of pyrite is of interest in the formation of acid mine drainage and is a complex electrochemical process. Being able to measure the rate of dissolution of particular pyrite samples under particular conditions is important for describing and predicting rates of AMD generation. Electrochemical techniques offer the promise of performing such measurements rapidly and with small samples. The oxidation of pyrite and the reduction of Fe³⁺ ions and/or O₂ half reactions involved in the pyrite dissolution process were investigated by cyclic voltammetry and steady-state voltammetry using three pyrite materials formed in both sedimentary and hydrothermal environments. For each sample, two kinds of pyrite working electrodes (conventional constructed compact solid electrode, and carbon paste electrode constructed from fine-grained pyrite particles) were employed. Results indicated that for both the hydrothermal and sedimentary pyrite samples the oxidation and reduction half reactions involved in dissolution were governed by charge transfer processes, suggesting that hydrothermal and sedimentary pyrites obey the same dissolution mechanism despite their different formation mechanisms. In addition, the results showed that it is feasible to use a C paste electrode constructed from fine-grained or powdered pyrite to study the pyrite dissolution process electrochemically and to derive approximate rate expressions from the electrochemical data.     

Comparison of dissolution under oxic acid drainage conditions for eight sedimentary and hydrothermal pyrite samples

The abiotic oxidative dissolution behaviors of eight natural pyrite samples, five sedimentary and three hydrothermal, from various geological environments were compared under oxic conditions at pH 3 and 6 in a highly controlled batch reactor dissolution system. The three sedimentary pyrite samples associated with coal had greater specific surface areas and also exhibited greater apparent dissolution rates and extent than the other two sedimentary and three hydrothermal samples under both pH conditions. However, after normalizing for surface area, the dissolution rate constants for the different pyrite samples were similar; the greatest difference was between the two non-coal sedimentary pyrite samples. Pyrite morphology and the presence of trace metals could contribute to the differences in dissolution behavior as reflected in the normalized dissolution rates. The sulfur:iron ratio observed in the aqueous solution at pH 3 increased with time, but was always less than 2.0 (predicted from the stoichiometry of dissolution) for all the pyrite samples during the 24-h experimental duration. This can be explained by the disproportionation dissociation of thiosulfate, an initial product of pyrite dissolution, to elemental sulfur and sulfate which does not occur in a 1:1 ratio. The results of this work indicate the importance of extracting and using the specific pyrite(s) relevant to particular mining areas in order to understand pyrite dissolution rates and the influence of environmental conditions on those rates.