Orbital interactions in phyllosilicates: Perturbations of an idealized two-dimensional,infinite silicate frame

The _∞ ² [Si₂O ₅ ²⁻ ] frame in phyllosilicate minerals is distorted through the rotation and tilting of the silicate tetrahedra and interacts with octahedral cations through its apical oxygens. Qualitative perturbation theory and extended Hückel band structure calculations demonstrate that rotation and tilting distortions of the _∞ ² [Si₂O ₅ ²⁻ ] frame have little influence on orbital interactions within the frame. The effects which are observed can be traced to next-nearestneighbor, oxygen-oxygen interactions. Analysis of band widths and crystal-orbital-overlap-populations demonstrate the importance of O(2s) orbitals in the silicate bond. Interactions between Si(3s, 3p) and O(2s) atomic orbitals account for about half of the bonding overlap in the Si-O bond. Crystal orbitals within the _∞ ² [Si₂O ₅ ²⁻ ] frame are perturbed in kaolinite, lizardite, pyrophyllite and talc through interactions of the apical oxygens with octahedrally coordinated Al(III) and Mg(II). These interactions appear to involve states that are non-bonding in an isolated frame, having little effect on the Si-O_apical bond while significantly reducing the apical-oxygen atomic population.     

Horizontal ground deformation patterns and magma storage during the Puu Oo eruption of Kilauea volcano,Hawaii: episodes 22–42

Horizontal ground deformation measurements were made repeatedly with an electronic distance meter near the Puu Oo eruption site approximately perpendicular to Kilauea's east rift zone (ERZ) before and after eruptive episodes 22–42. Line lengths gradually extended during repose periods and rapidly contracted about the same amount following eruptions. The repeated extension and contraction of the measured lines are best explained by the elastic response of the country rock to the addition and subsequent eruption of magma from a local reservoir. The deformation patterns are modeled to constrain the geometry and location of the local reservoir near Puu Oo. The observed deformation is consistent with deformation patterns that would be produced by the expansion of a shallow, steeply dipping dike just uprift of Puu Oo striking parallel to the trend of the ERZ. The modeled dike is centered about 800 m uprift of Puu Oo. Its top is at a depth of 0.4 km, its bottom at about 2.9 km, and the length is about 1.6 km; the dike strikes N65° E and dips at about 87°SE. The model indicates that the dike expanded by 11 cm during repose periods, for an average volumetric expansion of nearly 500 000 m³. The volume of magma added to the dike during repose periods was variable but correlates positively with the volume of erupted lava of the subsequent eruption and represents about 8% of the new lava extruded. Dike geometry and expansion values are used to estimate the pressure increase near the eruption site due to the accumulation of magma during repose periods. On average, vent pressures increased by about 0.38 MPa during the repose periods, one-third of the pressure increase at the summit. The model indicates that the dikelike body below Puu Oo grew in volume from 3 million cubic meters (Mm³) to about 10–12 Mm³ during the series of eruptions. The width of this body was probably about 2.5–3.0 m. No net long-term deformation was detected along the measured deformation lines.     

Methode zur Bestimmung des Ammoniakstickstoffes in Gewässern

For the spectrophotometrical determination of ammonia in surface water the reaction with hypochlorite and thymol in alkaline solution is used. Compared with other techniques, expenditure is low, the reagents are stable for a long period of time and the reaction is little dependent on external conditions. In 2 cm cuvettes there can be determined 0.05… 0.5 mg/l ammonia nitrogen. Comparative investigations carried out at nine sites in the area of the lake Balaton have revealed concentrations of 0.2… 0.7 mg/l ammonia nitrogen.     

A Contribution to the Mechanism of Elimination of Dimethylformamide and Dimethylamine by a Heterogenous Culture of Microorganisms

In a batch experiment with activated sludge from a large-scale plant the hydrolytical and biochemical degradation of dimethylformamide (DMF) and its reaction product dimethylamine (DMA) and the conversion connected with this under aerobic and anaerobic conditions is investigated. Parallel to the hydrolysis of DMF the biochemical degradation of DMA occurs. The extensive conversion of these substrates is followed by the nitrification of the ammoniumions formed, and under subsequent anaerobic conditions with methanol as the carbon source also denitrification can be achieved. If the oxygen supply of the activated sludge is insufficient, however, also DMA can be used as a carbon source for denitrification, ammonium-ions being released from DMA in addition. In the batch experiment the elimination rates referred to nitrogen were 7 … 14 mg/g · h for DMF, 0.8 … 1.7 mg/g · h for DMA, 0.3 … 0.6 mg/g · h for NH and 0.4 to 1.3 mg/g · h for nitrate in the presence of methanol. DMF and DMA are obviously not suitable as the only carbon source for denitrification.     

Condition for liquefaction instability in fluid-saturated granular soils

High-porosity granular materials such as loose sands can implode when subjected to compressive stresses. The mechanism of deformation is diffuse in that the jump in the strain rate tensor has three independent eigenvalues (full rank), in contrast to the jump in the strain rate tensor for a deformation band-type instability that has one eigenvalue (rank one). Recently, the mechanism of volume implosion has been studied in the context of material instability. In this paper we move one step further and consider the effect of a volume constraint associated with the presence of fluids in the pores of granular materials that have a tendency to implode. The upshot of this constraint is that at the onset of liquefaction the solid matrix deforms in a nearly isochoric fashion at the same time that the pore fluid pressure increases. The corresponding eigenmode (e-mode) is represented by jumps in the strain rate tensor and rate of pore fluid pressure. The framework presented in this work is used to analyze the onset of liquefaction instability in very loose Hostun RF sand tested in undrained triaxial compression and extension.     

Pb / Pb-ages of zircons from syn-collisional I-type porphyritic granites of the central Ribeira belt, SE Brazil

In the central segment of the Ribeira belt, southeast Brazil, several foliated porphyritic granitic bodies intrude high-grade migmatitic gneisses of the Andrelândia and Juiz de Fora domains and Embú Complex. Results of geological, geochemical and geochronological investigations of the Maromba, Pedra Selada, Serra do Lagarto and Funil porphyritic I-type granites provide profound similarities, except for the distinct geochemical behavior of the Funil Granite, perhaps related to a different crustal source. These granitoids show similar structural, textural and mineralogical features. Pb-evaporation of single zircons provided ages of 586 ± 6, 579.6 ± 6.3, 586.3 ± 4.8 and 584 ± 5 Ma for the granites, respectively, coincident with the syn-collision I episode of the central Ribeira belt. The intrusion of I-type porphyritic granitoids coeval with the main collisional event has not often been reported in the geological literature. The most common syn-collisional granitic magmatism has normally an S-type signature or even a slightly peraluminous I-type character. However, the occurrence of coeval I- and S-type syn-tectonic granites along the central Ribeira belt, as observed in the investigated area and discussed in this paper is noteworthy.     

The role of dust source area and pedogenesis in three loess-palaeosol sections from North Bulgaria: A mineral magnetic study

Rock magnetic studies of three loess-palaeosol sections from Bulgaria (Harletz and Orsoja in the NW and Durankulak in the NE at the Black Sea coast) have been carried out. Thermomagnetic analyses of magnetic susceptibility point to magnetite as the major ferrimagnetic carrier in the loess and palaeosol units. Maghemite gives a significant contribution to the total magnetic signal in the recent soils (S₀), while in one of the sections-Orsoja-hematite may also be present. The effective magnetic grain sizes deduced from the hysteresis measurements and the ratios M_rs/M_s and B_cr/B_c fall in the pseudo single domain (PSD) range, but the data distributions in a Day diagram for the three different sections are shifted. This is suggested to be caused by different detrital input (e.g. different dust source areas) and varying degrees of pedogenic modification. The calculated background susceptibilities χ_bg differ significantly as well. The lowest value is obtained for the Durankulak section-χ_bg = 9.95 × 10⁻⁸ m³/kg, which is in accordance with the data from other studies of loess-palaeosol profiles from the Black Sea area. The corresponding background susceptibilities for the other two sections studied-Harletz and Orsoja-are significantly higher (33.1 and 17.75 × 10⁻⁸ m³/kg, respectively). Both parent material and pedogenesis are found to be responsible for the observed differences in the magnetic characteristics.     

Spectral analysis of planetary waves seen in ionospheric total electron content (TEC): First results using GPS differential TEC and stratospheric reanalyses

The coupling of the neutral atmosphere and the ionosphere through planetary waves (PW) (zonal wavenumber 0–5) is investigated by spherical harmonic analyses of the ionospheric total electron content (TEC). These analyses detect mean variations, standing and travelling waves which are assumed to be signatures of PW. Database used for TEC analyses are 3 years of hourly TEC maps covering the higher middle and polar latitudes. They are regularly produced by DLR Neustrelitz. The obtained results are compared with PW analyses using NCEP/NCAR and Met Office stratospheric reanalyses. Case studies show that signatures of PW occur simultaneously in the middle atmosphere and ionosphere.