Solution thermochemistry of humic substances—I. Acid-base equilibria of humic acid

The technique of titration calorimetry has been used to characterize the acidic functional groups of humic acid. Both the concentrations of acidic functional groups and the thermodynamic parameters (pK_a, ΔH_a, etc.) for ionization of these functional groups were determined. The calculated values confirm the generally accepted opinion that humic acid contains both carboxyl and phenolic hydroxyl groups. Furthermore, at least one-third of the phenolic hydroxyl groups are not ortho to carboxyl groups and thus cannot participate in chelation of metal ions via salicylate-like complexing sites. The nature of the remaining two-thirds of the phenolic hydroxyl groups is still unknown.     

Fair weather and storm sand transport on the Long Island, New York, inner shelf

Both spring-summer and fall-winter sand transport have been observed on the Long Island, New York, inner shelf at water depths of 20-22 m using a radio-isotope sand tracer system. The extent of dispersal of the tagged, fine sand was measured at 3 week intervals in two 70 day experiments. In the late spring and early summer, movement was primarily diffusive in nature, extending 100 m around the line of tracer injection, while late fall-winter patterns had strong advective features, including an ellipsoidal outline extending approximately 1500 m westward of the injection points after the passage of several storms with strong northeasterly winds. Near-bottom current observations made with Savonius rotor sensors identify the event responsible for the bulk of the transport over the 135 day observation period as a storm flow of 2 days duration. Tracer and current observations together suggest that westward winter storm flow along the Long Island shelf is the major mechanism of sand transport at these depths on a yearly time scale. A least-squares fit of several of the observed winter patterns with a plume model yields average sediment mass flux lower bounds of 3.2 × 10^?3 gm/cm/sec and 1.7 × 10^?1 gm/cm/sec for ‘typical’ and extreme winter storm activity.     

A trigger mechanism for the emerging flux model of solar flares

The energetics of a current sheet that forms between newly emerging flux and an ambient field are considered. As more and more flux emerges, so the sheet rises in the solar atmosphere. The various contributions to the thermal energy balance in the sheet are approximated and the resulting equation solved for the internal temperature of the sheet. It is found that, for certain choices of the ambient magnetic field strength and velocity, the internal temperature increases until, when the sheet reaches some critical height, no neighbouring equilibrium state exists. The temperature then increases rapidly, seeking a hotter branch of the solution curve. During this dynamic heating, the threshold temperature for the onset of plasma microinstabilities may be attained. It is suggested that this may be a suitable trigger mechanism for the recently proposed emerging flux model of a solar flare.This work was done while the author was participating in the CECAM workshop on Plasma Physics applied to Active Solar Phenomena, August–September 1976 at Orsay, France, and the Skylab Solar Workshop on Solar Flares (sponsored by NASA and NSF and managed by the High Altitude Observatory).     

On the dissociation of nitrogen by electron impact and by E.U.V. photo-absorption

The dissociation of N₂ by electron impact and by e.u.v. photo-absorption is studied, and it is shown that the forbidden predissociation of the numerous ¹Π_u and ¹Σ_u⁺ valence and Rydberg states of N₂ in the 11–24eV energy range is the dominant mechanism for N atom production. By measuring the absolute emission cross sections for the e.u.v. singlet bands of N₂ and by using the generalized oscillator strength data of Lassettre (1974), it has been possible to construct a detailed model of the total N₂ dissociation cross section which is in good agreement with the measurements of Winters (1966) and Niehaus (1967) and provides some insights into the maximum possible $\text{N(}{}^2\text{D)}$ yield from dissociative excitation. The total cross section for exciting N₂ e.u.v. radiation in the 800Å–1100Å wavelength range has been measured and found to have a value of 3.4 ×10^?17 cm² at 100 eV under optically thin conditions. Although this result implies that large fluxes of e.u.v. photons should be excited in auroral substorms and in the airglow, they are not observed, and we show that this development is a consequence of radiation entrapment and predissociation. The total cross section for dissociating N₂ by electron impact is given for optically thin and thick media. And some questions concerning the energy budget of a magnetospheric storm which are raised by these results, are discussed.     

Pre-flare association of magnetic fields and millimeter-wave radio emission

Observations of radio emission at 3.3 mm wavelength associated with magnetic fields in active regions are reported. Results of more than 200 regions during the years 1967–1968 show a strong correlation between peak enhanced millimeter emission, total flux of the longitudinal component of photospheric magnetic fields and the number of flares produced during transit of active regions. For magnetic flux greater than 10²¹ maxwells flares will occur and for flux of 10²³ maxwells the sum of the H flare importance numbers is about 40. The peak millimeter enhancement increases with magnetic flux for regions which subsequently flared. Estimates of the magnetic energy available and the correlation with flare production indicate that the photospheric fields and probably chromospheric currents are responsible for the observed pre-flare heating and provide the energy of flares.This work was supported in part by NASA Contract No. NAS2-7868 and in part by Company funds of The Aerospace Corporation.     

Dynamics of coronal hole regions

The hydrodynamic properties of a steadily expanding corona are explored for situations in which departures from spherically symmetric outflow are large, in the sense that the geometrical cross section of a given flow tube increases outward from the Sun faster than r ² in some regions. Assuming polytropic flow, it is shown that in certain cases the flow may contain more than one critical point. We derive the criterion for determining which of these critical points is actually crossed by the transonic solution which begins at the Sun and extends continuously outward. Next, we apply the theory to geometries which exhibit rapid spreading of the flow tubes in the inner corona, followed by more-or-less radial divergence at large distances. This is believed to be the type of geometry found in coronal hole regions. The results show that, if this initial divergence is sufficiently large, the outflow becomes supersonic at a critical point encountered low in the corona in the region of high divergence, and it remains supersonic at all greater heights in the corona. This feature strongly suggests that coronal hole regions differ from other open-field regions of the corona in that they are in a fast, low density expansion state over much of their extent. Such a dynamical configuration makes it possible to reconcile the low values of electron density observed in coronal holes with the large particle fluxes in the associated high speed streams seen in the solar wind.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Differential rotation and giant cell circulation of solar Ca+-network

We report new results obtained from high precision computer controlled tracings of ca. 400 bright Ca⁺-mottles made during summer 1975 in continuation of our 1974 program (Schröter and Wöhl, 1975). In particular, we looked in 1975 for the existence of a giant circulation pattern in the equatorial zone. We find for the differential rotation: = 13.93 – 2.90 sin² B (deg/day, sidereal) when combining the new measurements with those obtained in 1974. Observations from 26th April until June 19th give strong evidence that at that time four giant circulation cells, crossing the solar equator, (i.e. a nonaxisymmetric velocity field pattern with respect to the solar equator) did exist. This yields two more rapid and two slower rotating sectors with v = ±80 m s^–1. These giant cells transport angular momentum towards the equator.     

Reversals of the geomagnetic field,magnetostratigraphy, and relative magnitude of paleosecular variation in the phanerozoic

The percentage of normal and reversed magnetization in land-based paleomagnetic studies of Phanerozoic rocks (0 to ? 570 m.y.) have been compiled in order to determine the long-term variation in polarity bias of the geomagnetic field. Where possible the results are compared with the record from marine magnetic anomalies. Only rarely is there an even balance between normal and reversed polarity. During the past 350 m.y. two quiet intervals can be recognized when few reversals occurred, the Cretaceous (KN about ? 81 to ? 110 m.y.) and Permo-Carboniferous (PCR about ? 227 to ? 313 m.y.). Less firmly established are two other quiet intervals, one in the Jurassic (JN about ? 145 to ? 165 m.y.), and one in the Triassic (TRN about ? 205 to ? 220 m.y.). Between these quiet intervals there are disturbed intervals when reversals were comparatively frequent. From ? 680 to ? 350 m.y. the paleomagnetic record is inadequate to delineate a succession of quiet and disturbed intervals although one is probably present. Maximum entropy spectral analysis reveals three periodicities, a dominant one at about 300 m.y. and others, less well-defined, at 113 and 57 m.y. The variations in polarity bias are compared with the paleosecular variation, and it is shown that the magnitude of the paleosecular variation is greater in disturbed than in quiet intervals. This indicates that the magnitude of paleosecular variation and polarity bias are governed by variations in the balance between non-dipole and dipole components of the field, and that these variations probably had their origin in processes near the core—mantle interface. The correspondence between the dominant periods of 300 m.y. and plate tectonics is noted and a causal relationship suggested.