The synergistic effect of calcium on organic carbon sequestration to ferrihydrite

Sequestration of organic carbon (OC) in environmental systems is critical to mitigating climate change. Organo-mineral associations, especially those with iron (Fe) oxides, drive the chemistry of OC sequestration and stability in soils. Short-range-ordered Fe oxides, such as ferrihydrite, demonstrate a high affinity for OC in binary systems. Calcium commonly co-associates with OC and Fe oxides in soils, though the bonding mechanism (e.g., cation bridging) and implications of the co-association for OC sequestration remain unresolved. We explored the effect of calcium (Ca²⁺) on the sorption of dissolved OC to 2-line ferrihydrite. Sorption experiments were conducted between leaf litter-extractable OC and ferrihydrite at pH 4 to 9 with different initial C/Fe molar ratios and Ca²⁺ concentrations. The extent of OC sorption to ferrihydrite in the presence of Ca²⁺ increased across all tested pH values, especially at pH ≥ 7. Sorbed OC concentration at pH 9 increased from 8.72 ± 0.16 to 13.3 ± 0.20 mmol OC g^?1 ferrihydrite between treatments of no added Ca²⁺ and 30 mM Ca²⁺ addition. Batch experiments were paired with spectroscopic studies to probe the speciation of sorbed OC and elucidate the sorption mechanism. ATR-FTIR spectroscopy analysis revealed that carboxylic functional moieties were the primary sorbed OC species that were preferentially bound to ferrihydrite and suggested an increase in Fe-carboxylate ligand exchange in the presence of Ca at pH 9. Results from batch to spectroscopic experiments provide significant evidence for the enhancement of dissolved OC sequestration to 2-line ferrihydrite and suggest the formation of Fe–Ca-OC ternary complexes. Findings of this research will inform modeling of environmental C cycling and have the potential to influence strategies for managing land to minimize OM stabilization.     

Heavy metal exposure from co-processing of hazardous wastes for cement production and associated human risk assessment

This study was carried out to determine the concentration of heavy metals (Cd, Ni, Pb, Cr, Ni and Zn) in ordinary Portland cement (OPC) produced from the co-processing with hazardous waste in comparison with OPC produced using natural raw materials. The results showed that the concentration of heavy metals in cement produced from natural raw material was in the order of Zn > Pb > Cr > Ni > Cu > Cd. Zn and Cd were the highest and the lowest concentrations, respectively, in cements produced from the co-processing activity. The difference between heavy metals concentrations in OPC produced with and without co-processing was found to be statistically significant. The concentration of heavy metals in the cement produced is generally factory dependent. The human risk assessment associated with the heavy metals for non-carcinogenic and carcinogenic risks has been evaluated. The calculated hazard index (HI) and total lifetime cancer risks (LCR) were lower than the acceptable threshold reference values, HI < 1 and LCR < 1 × 10^?4, respectively. Thus, it is anticipated that there is no potential of non-carcinogenic and carcinogenic risks for both adult and children. However, the findings indicated that there is a need for regulatory monitoring. The exposure pathway for both non-carcinogenic and carcinogenic risks are both in the order of ingestion > dermal > inhalation.     

Identifying influence areas with connectivity analysis – application to the local perturbation of heterogeneity distribution for history matching

Numerical representations of a target reservoir can help to assess the potential of different development plans. To be as predictive as possible, these representations or models must reproduce the data (static, dynamic) collected on the field. However, constraining reservoir models to dynamic data – the history-matching process – can be very time consuming. Many uncertain parameters need to be taken into account, such as the spatial distribution of petrophysical properties. This distribution is mostly unknown and usually represented by millions of values populating the reservoir grid. Dedicated parameterization techniques make it possible to investigate many spatial distributions from a small number of parameters. The efficiency of the matching process can be improved from the perturbation of specific regions of the reservoir. Distinct approaches can be considered to define such regions. For instance, one can refer to streamlines. The leading idea is to identify areas that influence the production behavior where the data are poorly reproduced. Here, we propose alternative methods based on connectivity analysis to easily provide approximate influence areas for any fluid-flow simulation. The reservoir is viewed as a set of nodes connected by weighted links that characterize the distance between two nodes. The path between nodes (or grid blocks) with the lowest cumulative weight yields an approximate flow path used to define influence areas. The potential of the approach is demonstrated on the basis of 2D synthetic cases for the joint integration of production and 4D saturation data, considering several formulations for the weights attributed to the links.     

Convergence analysis of fixed stress split iterative scheme for anisotropic poroelasticity with tensor Biot parameter

We perform a convergence analysis of the fixed stress split iterative scheme for the Biot system modeling coupled flow and deformation in anisotropic poroelastic media with tensor Biot parameter. The fixed stress split iterative scheme solves the flow subproblem with all components of the stress tensor frozen using a multipoint flux mixed finite element method, followed by the poromechanics subproblem using a conforming Galerkin method in every coupling iteration at each time step. The coupling iterations are repeated until convergence and Backward Euler is employed for time marching. The convergence analysis is based on studying the equations satisfied by the difference of iterates to show that the fixed stress split iterative scheme for anisotropic poroelasticity with Biot tensor is contractive. We also demonstrate that the scheme is numerically convergent using the classical Mandel’s problem solution for transverse isotropy.     

Study on the deformation and failure modes of filling slope in loess filling engineering: a case study at a loess mountain airport

Lvliang airport is a typical loess filling engineering located in 20.5 km north of Lvliang City in Shanxi Province, China. By the end of March 2012, 14 fissures extending more than 7.5 m were observed in a loess-filled slope, of which the longest fissure is up to 82 m. Field monitoring and laboratory tests have been performed to investigate the slope failure modes. The test program includes wetting tests on unsaturated compacted samples and stress path tests on saturated samples. Field monitoring and observations show that differential settlement caused by non-homogeneity in compacted loess density might lead to the formation of fissures in the loess-filled slope. It was founded that the wetting deformation contributed to the development of differential settlement. Fissures are the essential factor for the loess-filled slope failure. Four deformation stages exhibit in the loess-filled slope prior final failure including development of the fissures, softening of the compacted loess, creeping of the slope leading edge and fissuring of the trailing edge and formation of the through-sliding surface. Development of the sliding surface mainly includes upward and downward expansion of the fissures. Upward expansion is a wetting failure process in loading condition, while downward expansion is a load-off wetting process. In addition, development of the sliding surface is accelerated by softening of the compacted soils as a result of water infiltration. Therefore, the key for taking countermeasures against filling landslides is to monitor and control the development of differential settlement and fissures in the slope shoulders. Digging out and extra-filling the fissures are an effective way for preventing these landslides.     

Study on the Development Laws of Bed-Separation Under the Hard-Thick Magmatic Rock and its Fracture Disaster-Causing Mechanism

Based on the analysis of dynamic phenomena under the condition of high-located hard-thick (HLHT) stratum of one coal mine, along with the similar material simulation and theoretical analysis, the characteristics of bed separation development and cracks distribution under the HLHT stratum are studied. This paper proposes a discriminating method for overlying strata Three Zones considering the influence of HLHT stratum. The development laws of cracks and disaster-causing mechanism of hard-thick magmatic rock in different strata are respectively analyzed. The studies show that in line with the working face advancing direction, the height of bed separation under the magmatic rock increases in the trend of “Increase–Stability–Decrease”, and the width of bed separation increases linearly. The width of bed separation reaches the maximum before the first breaking of magmatic rock, the bed separation completely closes after the breaking. There are no obvious bed separations during the period migration of magmatic rock. Along the direction of the height of roof, the development of bed separation is characterized by bottom-up jump based on the key strata. The analyzed results of “Three zone” height obtained by the discriminate method of overlying strata Three Zones which is based on the key strata theory and the S–R instability theory are in line with the actual facts. When the hard-thick magmatic rock is in the fractured zone, large amounts of gas and water are easy to accumulate in the bed separation space and “O” ring space around the gob. The first breaking of magmatic rock may induce bed separation gas outburst and water inrush. When the hard-thick magmatic rock is in the sagging zone, the long-term stability of magmatic rock will not cause serious disasters. But with the adjacent working face mining, bed separation gas and water often become a safety hazard.     

Dynamic Response to Seismic Waves at the Shallow Slope Supported by Bolts

In the soil slope supported by bolts, longitude waves instead of transverse waves, generated by earthquakes, first reach the slope surface. With the dynamic response of the P (pressure) wave along the anchorage structure, first, a theoretical study was conducted to investigate the propagation characteristics of the interference superposition, generated by the SV (shear-vertical) and the P waves. The SV wave was formed by the wave, originating from the bottom and reflected from the free surface of the slope, whereas the latter was the incident P wave, propagating in the slope. In addition, the structural measures, restraining the seismic wave, and the characteristics of the restraint effect at the free segment of the bolt were investigated. According to the wave-way difference between the incident P wave and the reflected SV wave, the minimum critical slope angle, influenced by the interference at the shallow slope, and the maximum influencing depth of the dynamic response, acting vertically to the slope surface, were obtained. The results indicate that the maximum influencing depth linearly correlated with the slope angle. Furthermore, based on the propagation characteristics of the P wave along the bolt, and the coupled relation between the wave length and the anchorage design parameters, the axial acceleration of the wave propagating along the bolt axis was obtained. Then, the theoretical length of the anti-seismic bolt, subjected to seismic waves, and the compensation force of the anchorage structure were obtained. Finally, a numerical study, based on FlAC3D, properly verified the theoretical conclusions.     

Laboratory Investigation of the Influence of Geotextile on the Stress–Strain and Volumetric Change Behavior of Sand

This paper presents the results of triaxial tests conducted for the investigation of the influence of geotextile on both the stress–strain and volumetric change behavior of reinforced sands. Tests were carried out on loose sand. The experimental program includes drained compression tests on samples reinforced with different values of both geotextile layers (1 ≤ Ng ≤ 3) and confining pressure (\(\upsigma_{\text{c}}^{\prime }\)) varying from 50 to 200 kPa. Tests show that the contribution of geotextile is negligible until an axial strain threshold that range between 2.5% for a confining pressure of 50 kPa to lower than 1% for 100 and 200 kPa confining pressure. At higher values of ε_a, geotextile induces a quasi-linear increase in the stress deviator (q) and volume contraction in the reinforced sand. Tests show a negligible influence of the number of geotextile layers (Ng) on the contribution of geotextile to both stress–strain and volumetric change, when normalized with Ng. Tests also show that the contribution of geotextile to the stress–strain mobilization augments with the increase in the confining pressure, while its contribution to the volume contraction decreases with the increase in the confining pressure. The reinforced soil becomes contracting in the case of 2 and 3 geotextile layers.     

Prediction of Engineering Properties of Basalt Rock in Jordan Using Ultrasonic Pulse Velocity Test

Basalt is an extrusive igneous rock derived from Lava and spread over different localities in Jordan. It can be used in industrial applications, and as construction materials. Before using basalt, it is essential to determine its dry density, porosity, uniaxial compressive strength, and Brazilian tensile strength. The testing procedure and sample preparation used to determine the engineering properties are time-consuming and need expertise. Hence, the ultrasonic pulse velocity (UPV) test, a quick and non-destructive evaluation method, was used to determine the engineering properties. Empirical relationships for determination of dry density, porosity, uniaxial compressive strength, Brazilian tensile strength, and tangent modulus of elasticity were deduced. Good correlation coefficients (R²?=?0.832–0.929) were obtained between UPV and dry density, porosity, uniaxial compressive strength, Brazilian tensile strength and modulus of elasticity. These correlations were limited to intact basalt with UPV?≥?4000 m/s.     

Emerging grassroots resilience and flood responses in informal settlements in Accra,Ghana

In the last five decades, many informal communities in Accra, Ghana have suffered from annual flood hazards. Residents of these communities appear to have successfully resisted evictions by city authorities; survived flood hazards and poor environmental health conditions. These flood affected households continue to survive with increasing housing and population densities in the face of these annual floods. Are they becoming resilient? Have residents built adaptive capacities through learning experiences from previous flood occurrences and evictions attempts? What has produced and continued to shape their responses to flooding? What can be learned from this supposed grassroots resilience to inform flood management in urban Africa? Using case studies of three informal communities of Glefe, Agbogbloshie and Old Fadama, this paper explores the gradual and evolving adaptive capacities and social resilience to flood hazards among poor urban dwellers. The paper reveals the depth of understanding and embodied nature of flood experiences among affected slum dwellers and how these are gradually being transformed into adaptive capacities and shaping their responses. In the absence of efficient state flood interventions, there are emerging and enduring flood responses and adaptation practices shaped by residents’ social networks, political alliances and sense of place. These responses translates into continuous re-structuring of housing units, construction of communal drains, creation of local evacuation teams and safe havens. Urban policy contributions that can be learned from these emerging grassroots capacities for flood vulnerability management have been proposed.