Isotopic evidence (Sr/Sr, δLi) for alteration of the oceanic crust at deep-rooted mud volcanoes in the Gulf of Cadiz, NE Atlantic Ocean

The chemical and isotopic composition of pore fluids is presented for five deep-rooted mud volcanoes aligned on a transect across the Gulf of Cadiz continental margin at water depths between 350 and 3860 m. Generally decreasing interstitial Li concentrations and ⁸⁷Sr/⁸⁶Sr ratios with increasing distance from shore are attributed to systematically changing fluid sources across the continental margin. Although highest Li concentrations at the near-shore mud volcanoes coincide with high salinities derived from dissolution of halite and late-stage evaporites, clayey, terrigenous sediments are identified as the ultimate Li source to all pore fluids investigated. Light δ⁷Li values, partly close to those of hydrothermal vent fluids (δ⁷Li: +11.9‰), indicate that Li has been mobilized during high-temperature fluid/sediment or fluid/rock interactions in the deep sub-surface. Intense leaching of terrigenous clay has led to radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7106) in pore fluids of the near-shore mud volcanoes. In contrast, non-radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7075) at the distal locations are attributed to admixing of a basement-derived fluid component, carrying an isotopic signature from interaction with the basaltic crust. This inference is substantiated by temperature constraints from Li isotope equilibrium calculations suggesting exchange processes at particularly high temperatures (>200 °C) for the least radiogenic pore fluids of the most distal location.Advective pore fluids in the off-shore reaches of the Gulf of Cadiz are influenced by successive exchange processes with both oceanic crust and terrigenous, fine-grained sediments, resulting in a chemical and isotopic signature similar to that of fluids in near-shore ridge flank hydrothermal systems. This suggests that deep-rooted mud volcanoes in the Gulf of Cadiz represent a fluid pathway intermediate between mid-ocean ridge hydrothermal vent and shallow, marginal cold seep. Due to the thicker sediment coverage and slower fluid advection rates, the overall geochemical signature is shifted towards the sediment-diagenetic signal compared to ridge flank hydrothermal environments.     

A Global Terrestrial Reference Frame from simulated VLBI and SLR data in view of GGOS

In this study, we assess the impact of two combination strategies, namely local ties (LT) and global ties (GT), on the datum realization of Global Terrestrial Reference Frames in view of the Global Geodetic Observing System requiring 1 mm-accuracy. Simulated Very Long Baseline Interferometry (VLBI) and Satellite Laser Ranging (SLR) data over a 7 year time span was used. The LT results show that the geodetic datum can be best transferred if the precision of the LT is at least 1 mm. Investigating different numbers of LT, the lack of co-located sites on the southern hemisphere is evidenced by differences of 9 mm in translation and rotation compared to the solution using all available LT. For the GT, the combination applying all Earth rotation parameters (ERP), such as pole coordinates and UT1-UTC, indicates that the rotation around the Z axis cannot be adequately transferred from VLBI to SLR within the combination. Applying exclusively the pole coordinates as GT, we show that the datum can be transferred with mm-accuracy within the combination. Furthermore, adding artificial stations in Tahiti and Nigeria to the current VLBI network results in an improvement in station positions by 13 and 12%, respectively, and in ERP by 17 and 11%, respectively. Extending to every day VLBI observations leads to 65% better ERP estimates compared to usual twice-weekly VLBI observations.     

Das Problem der Entstehung und Altersstellung der Siegerländer Spateisensteingänge

Ohne Zusammenfassung     

Measurements of the vertical correlation in turbulence under broken waves

Turbulence measurements have been carried out in the surf zone of a wave flume. The purpose of the measurements is to determine the length scale of the turbulence generated by the wave breaking. The length scale of the turbulence is estimated on basis of the correlation between simultaneous measurements of the vertical turbulent fluctuations, taken at different levels above the bed.     

Internal morphology, habit and U-Th-Pb microanalysis of amphibolite-to-granulite facies zircons: geochronology of the Ivrea Zone (Southern Alps)

Several types of growth morphologies and alteration mechanisms of zircon crystals in the high-grade metamorphic Ivrea Zone (IZ) are distinguished and attributed to magmatic, metamorphic and fluid-related events. Anatexis of pelitic metasediments in the IZ produced prograde zircon overgrowths on detrital cores in the restites and new crystallization of magmatic zircons in the associated leucosomes. The primary morphology and Th-U chemistry of the zircon overgrowth in the restites show a systematic variation apparently corresponding to the metamorphic grade: prismatic (prism-blocked) low-Th/U types in the upper amphibolite facies, stubby (fir-tree zoned) medium-Th/U types in the transitional facies and isometric (roundly zoned) high-Th/U types in the granulite facies. The primary crystallization ages of prograde zircons in the restites and magmatic zircons in the leucosomes cannot be resolved from each other, indicating that anatexis in large parts of the IZ was a single and short lived event at 299 ± 5 Ma (95% c. l.). Identical U/Pb ages of magmatic zircons from a metagabbro (293 ± 6 Ma) and a metaperidotite (300 ± 6 Ma) from the Mafic Formation confirm the genetic context of magmatic underplating and granulite facies anatexis in the IZ. The U-Pb age of 299 ± 5 Ma from prograde zircon overgrowths in the metasediments also shows that high-grade metamorphic (anatectic) conditions in the IZ did not start earlier than 20 Ma after the Variscan amphibolite facies metamorphism in the adjacent Strona–Ceneri Zone (SCZ). This makes it clear that the SCZ cannot represent the middle to upper crustal continuation of the IZ. Most parts of zircon crystals that have grown during the granulite facies metamorphism became affected by alteration and Pb-loss. Two types of alteration and Pb-loss mechanisms can be distinguished by cathodoluminescence imaging: zoning-controlled alteration (ZCA) and surface-controlled alteration (SCA). The ZCA is attributed to thermal and/or decompression pulses during extensional unroofing in the Permian, at or earlier than 249 ± 7 Ma. The SCA is attributed to the ingression of fluids at 210 ± 12 Ma, related to hydrothermal activity during the breakup of the Pangaea supercontinent in the Upper Triassic/Lower Jurassic. Received: 7 July 1998 / Accepted: 4 November 1998     

Stratigraphic evidence for an Early Aptian sea-level fluctuation: the Graua Limestone of south-eastern Ethiopia

The occurrence of a thin band of marine limestone (Graua Limestone) within a thick succession of fluviatile sandstones in south-eastern Ethiopia is direct evidence of flooding of part of the East African craton (Horn of Africa). According to the presence of abundant orbitolinid foraminifers (Palorbitolina lenticularis Blumenbach andPraeorbitolina cormyi Schroeder), the age of the Graua Limestone can be referred to the Early Aptian. Stratigraphy and palaeogeographic reconstructions for the Early Cretaceous in the surrounding regions (Kenya, Somalia, Yemen, Socotra, Oman, Syria, Lebanon, Israel, Egypt and Libya) show that the Early Aptian transgression was of regional extent. Our data seem to confirm that this transgression was of relatively short duration. This pulse cannot be related to tectono-eustatic mechanisms, which are too slow. A short-lived event should be invoked: either a regional tectonic pulse or the desiccation of the proto-South Atlantic.     

Impact of grazing by benthic eukaryotic organisms on the nitrogen sediment–water exchange in the North Sea

The metabolic inhibitor cycloheximide was used to estimate the influence of primarily unicellular eukaryotes (heterotrophic protozoa) on nutrient recycling in different types of sediments in the North Sea. Fluxes of dissolved inorganic nitrogen across the sediment–water interface were measured in undisturbed sediment cores (controls) and compared to fluxes in sediment cores with cycloheximide added. If eukaryotes play an important role in nutrient recycling, one would expect to find lower nitrogen sediment–water effluxes in cores with cycloheximide due to the inactivation of eukaryotes. This important role hypothesised for eukaryotes was not generally observed: Only at four of the nineteen stations were ammonium effluxes significantly higher in controls than in cores with cycloheximide, and at five stations nitrate effluxes were significantly higher in the controls than in the cores with cycloheximide. Eukaryotic activity apparently contributed to the sediment–water exchange of ammonium through mineralisation of organic matter, nitrification and the subsequent release of ammonium and nitrate at these stations. At most other stations no differences were obtained between controls and cores with cycloheximide. This suggests that bacteria were the most important nutrient mineralisers at these stations at the time of the cruises.     

Ecosystem engineering by hummock-building earthworms in seasonal wetlands of eastern South Africa: Insights into the mechanics of biomorphodynamic feedbacks in wetland ecosystems

This paper resolves the origin of clay hummock micro-topography in seasonal wetlands of the Drakensberg Foothills, providing a review and appraisal of previously-suggested mechanisms of hummock formation in the context of new field and laboratory data. Field surveys revealed neo-formation of clay hummocks in a river channel that had been abandoned in c.1984. Fresh earthworm castings were located atop hummocks protruding from inundated abandoned channel margins. Earthworm castings, and sediment cores taken in hummocks and adjacent hollows, were analysed for soil-adsorbed carbon and nitrogen using an HCN analyser, and for ²¹⁰Pb activity using alpha-geochronology. ²¹⁰Pb activity profiles suggest relative enrichment of the isotope in hummocks, and relative depletion in adjacent hollows. Earthworm castings are characterised by very high ²¹⁰Pb activity, as well as high C and N contents. Hummocks have significantly higher C and N contents than adjacent hollows. Results suggest that it is the foraging activity of earthworms in litter-rich seasonal wetland hollows, and repeated excretion of castings atop adjacent hummocks, that is responsible for the elemental enrichment observed. The paper presents a conceptual model of hummock formation in wetlands through interactions between hydrogeomorphology and earthworm activity, and illustrates a mechanism of biogeomorphic inheritance through which ordered patterns of preferential flow can emerge in ecosystems. Further implications of hummock formation and nodal accumulation of nutrients are considered in relation to wetland resilience and regulatory ecosystem service provision.© 2018 John Wiley & Sons, Ltd.     

‘Bond cycles’ recorded in terrestrial Pleistocene sediments of southwestern British Columbia,Canada

Recent data from exposures of terrestrial Pleistocene sediments in the Fraser Lowland of southwestern British Columbia reveal at least two ‘Bond cycles’ within Oxygen Isotope Stage 2. The maximum of the Coquitlam Stade coincides with the timing of Heinrich event H2, the Port Moody Interstade with Dansgaard–Oeschger (D–O) interstade 2, the maximum of the Vashon Stade with H1, and the Fort Langley interval with D–O interstade 1. The Sumas Stade apparently preceded H0 (Younger Dryas) but could have been in response to the same climatic signal. The timing of Sumas advances may be explained by a combination of glacio-isostatic rebound, destabilisation of the ice margin, and rapid movement over a short distance on soft muddy beds of a rising sea floor, thereby leading the timing of North Atlantic events by hundreds of years. In contrast, Coquitlam and Vashon advances were mainly over permeable glaciofluvial sediments and because of this their maxima probably did not precede the timing of H2 and H1. The Port Moody Interstade coincided with the global Last Glacial Maximum, due in part to the moderating effect of moist summer storms in a southward-shifted jet stream that influenced the Fraser Lowland at that time. Copyright © 1999 John Wiley & Sons, Ltd.     

Forecasting Groundwater Temperature with Linear Regression Models Using Historical Data

Although temperature is an important determinant of many biogeochemical processes in groundwater, very few studies have attempted to forecast the response of groundwater temperature to future climate warming. Using a composite linear regression model based on the lagged relationship between historical groundwater and regional air temperature data, empirical forecasts were made of groundwater temperature in several aquifers in Switzerland up to the end of the current century. The model was fed with regional air temperature projections calculated for greenhouse‐gas emissions scenarios A2, A1B, and RCP3PD. Model evaluation revealed that the approach taken is adequate only when the data used to calibrate the models are sufficiently long and contain sufficient variability. These conditions were satisfied for three aquifers, all fed by riverbank infiltration. The forecasts suggest that with respect to the reference period 1980 to 2009, groundwater temperature in these aquifers will most likely increase by 1.1 to 3.8 K by the end of the current century, depending on the greenhouse‐gas emissions scenario employed.