北极巴伦支海和拉普捷夫海海冰中细菌和微藻的垂直分布

通过计算机图像测定系统测定、计算获得海冰细菌的大小、面积和碳含量,研究了北极巴伦支海和拉普捷夫海的浮冰中细菌大小、丰度和生物量的垂直分布及其与海冰微藻生物量的关系.细菌在冰心中是非均匀分布的,至少有两种不同分布类型:第一类有单一的丰度峰值,在冰心底部或在冰心中部;第二类有两个丰度峰值.海冰中细菌的丰度为0.4×105～36.7×105个/cm3.不同类型海冰中的细菌大小变化极大,在多年冰中,最大的细菌与叶绿素a最大值出现在同一层,而在一年冰中,细菌大小几乎没有垂直变化.整柱冰心的细菌生物量变化为19.2～79.2mg/cm2,细菌与海冰微藻生物量之比为0.43～10.00.对固定冰比较和研究的结果发现,海冰冰心中细菌大小、丰度和生物量的垂直分布差别极大.据此,分析了对目前海冰研究采样方法的局限性,并提出了规范采样方法的设想.     

Earthquakes and strength in the laminated lower crust —Can they be explained by the “corset model”?

We present a model that may explain deep crustal earthquakes observed, in particular, in several areas of highly reflective (laminated) lower continental crust. We combine observations from earthquake seismology, crustal reflection seismics and tectonic-rheological concepts. The study concentrates on parts of the northern Alpine foreland where many earthquakes occur inside the laminated lower crust, which is generally considered to be warm and weak. Thin mafic/ultramafic, sill-like intrusions and invisible dykes are assumed to form a corset-like network with high strength. This model can explain the observed strong and multiple reflections and the occurrence of rupture inside a stable structure within a weak lower crust. Tectonic stress transfer (from the Alpine collision zone or/and the Upper Rhine Graben) and its release may follow classical friction concepts. In addition, the heterogeneity of the laminated lower crust may also favour various viscous instabilities.     

Laboratory and numerical model studies of a negatively-buoyant jet discharged horizontally into a homogeneous rotating fluid

Abstract

The results of laboratory experiments and numerical model simulations are described in which the motion of a round, negatively-buoyant, turbulent jet discharged horizontally above a slope into a rotating homogeneous fluid has been investigated. For the laboratory study, flow visualisation data are presented to show the complex three-dimensional flow fields generated by the discharge. Analysis of the experimental data indicates that the spatial and temporal developments of the flow field are controlled primarily by the lateral and vertical discharge position of the jet (with respect to the bounding surfaces of the container of width W) and the specific momentum (M ₀) and buoyancy (B ₀) fluxes driving the jet. The flow is seen to be characterised by the formation of (i) a primary anticyclonic eddy (PCC) close to the source, (ii) an associated secondary cyclonic eddy (SCE) and (iii) a buoyancy-driven bottom boundary current along the right side boundary wall. For the parameter ranges studied, the size L _{p, s} and spatial location x _{p, s} of the PCC and SCE (and the nose velocity u _N of the boundary current) are shown to be only weakly-dependent upon the value of the mixed parameter M ₀Ω/B ₀, where Ω is the background rotation rate. Both L _p and x _p are shown to scale with the separation distance y?/W of the right side wall (y = 0) from the source (y = y?), both L _s and x _s scale satisfactorily with the length scale l _M (= M ₀ ^3/4/B ₀ ^½) and u _N is determined by the appropriate gravity current speed [(g']₀ H]^½ and the separation distance y?/W.

Numerical model results show good qualitative agreement with the laboratory data with regard to the generation of the PCC, SCE and boundary current as characteristic features of the flow in question. In addition, extension of the numerical model to

diagnose potential vorticity and plume thickness distributions for the laboratory cases allow the differences in momentum-and buoyancy-dominated flows to be clearly delineated. Specifically, the characteristic features of the SCE are shown to be strongly dependent upon the value of M ₀Ω/B ₀ for the buoyant jet flow; not least, the numerical model data are able to confirm the controlling role played by the boundary walls in the laboratory experiments. Quantitative agreement between the numerical and laboratory model data is fair; most significantly, the success of the former model in simulating the dominant flow features from the latter enables the reliable extension of the numerical model to be made to cases of direct oceanic interest.     

Vapour source and spatiotemporal variation of precipitation isotopes in Southwest Spain

The δ²H and δ¹⁸O composition of 77 precipitation samples collected between January 2014 and April 2019 from two sites across the Guadalquivir Basin, SW Spain, were analysed. The first site is located in an urban area of Seville at 100 km distance to the Atlantic coast and the second site is located in a dune area of the Doñana National Park a few kilometres from the coast. Sampling was performed within intervals of at least 14 days if rain occurred but frequently intervals were longer according to the rainfall incidence. Samples from both sites are available for the period February 2016 to June 2018 with six samples containing identical rain events at both locations. Precipitation weighted averages and local meteoric water lines produced by weighting and non-weighting regression methods are presented for its use in hydrological applications. Results show a remarkably high variability in δ²H and δ¹⁸O values and precipitation weighted average d-excess values of 11.8‰ and 13‰ at the sites Plaza de España and Doñana, respectively. Temperature and amount effects were found to be weak. A significant influence of secondary evaporation for single rainfall events during summer was identified by enriched isotopic signatures with reduced d-excess values plotting close or below the global meteoric water line. Backward trajectory analysis of 115 days with daily rainfall above 3 mm yield a predominant Atlantic Ocean vapour source with negligible Mediterranean influence and therefore, d-excess variability is attributed to the different ocean surface conditions of relative humidity and sea surface temperature. Parallel sampling indicate very similar isotopic signatures at both sites and point to the existence of thermal effects of the Plaza de España site in Seville city during the summer season.     

A 40 ka record of temperature and permafrost conditions in northwestern Europe from noble gases in the Ledo‐Paniselian Aquifer (Belgium)

The Ledo‐Paniselian Aquifer in Belgium offers unique opportunities to study periglacial groundwater recharge during the Last Glacial Maximum (LGM), as it was located close to the southern boundary of the ice sheets at that time. Groundwater residence times determined by ¹⁴C and ⁴He reveal a sequence of Holocene and Pleistocene groundwaters and a gap between about 14 and 21 ka, indicating permafrost conditions which inhibited groundwater recharge. In this paper, a dataset of noble gas measurements is used to study the climatic evolution of the region. The derived recharge temperatures indicate that soil temperatures in the periods just before and after the recharge gap were only slightly above freezing, supporting the hypothesis that permafrost caused the recharge gap. The inferred glacial cooling of 9.5°C is the largest found so far by the noble gas method. Yet, compared to other palaeoclimate reconstructions for the region, recharge temperatures deduced from noble gases for the cold periods tend to be rather high. Most likely, this is due to soil temperatures being several degrees higher than air temperatures during periods with extended snow cover. Thus the noble‐gas‐derived glacial cooling of 9.5°C is only a lower limit of the maximum cooling during the LGM. Some samples younger than the recharge gap are affected by degassing, possibly related to gas production during recharge in part of the recharge area, especially during times of melting permafrost. The findings of this study, such as the occurrence of a recharge gap and degassing related to permafrost and its melting, are significant for groundwater dynamics and geochemistry in periglacial areas. Copyright © 2010 John Wiley & Sons, Ltd.     

Numerical computations with H(div)-finite elements for the Brinkman problem

The H(div)-conforming approach for the Brinkman equation is studied numerically, verifying the theoretical a priori and a posteriori analysis in K?nn? and Stenberg (2010; Math Models Methods Appl Sci, 2011). Furthermore, the results are extended to cover a non-constant permeability. A hybridization technique for the problem is presented, complete with a convergence analysis and numerical verification. Finally, the numerical convergence studies are complemented with numerical examples of applications to domain decomposition and adaptive mesh refinement.     

Paired uraninite and molybdenite dating of the K?nigshain granite: implications for the onset of late-Variscan magmatism in the Lausitz Block

We present geochronological data for late-Variscan magmatism in the Lausitz Block of the Saxo-Thuringian Zone, Germany. The Th–U–total Pb age of uraninite and the Re–Os age of molybdenite from the composite biotite–monzogranite pluton of K?nigshain overlap at the 2σ confidence limit: 328.6 ± 1.9 Ma (uraninite), and 327.0 ± 1.3 Ma and 327.6 ± 1.3 Ma (molybdenite), indicating that crystallization of magmatic uraninite and deposition of molybdenite were nearly contemporaneous. These data imply that magmatic processes in this part of the Variscan orogen already started in latest Visean time, about 10 Ma earlier than previously assumed (315–320 Ma). The new ages correspond to ages for plutonic rocks in the Elbe Zone immediately west of the Lausitz (around 335–325 Ma) and the bulk of late-Variscan igneous rocks in the Saxo-Thuringian Zone (335–320 Ma).     

PCB contamination from sampling equipment and packaging

Work reported in this paper suggests that there are cases of contamination of soil and water samples by polychlorinated biphenyls (PCB) from paper and plastic packaging. Soil samples, which have been stored in paper bags for more than 20 years, share a similar congener distribution as the bags. Analyses showed a predominance of light congeners. PCB-analyses of water also indicate that water samples could be contaminated by plastic packaging. All analytical results of solid material packaging, as well as soil stored in the packaging, show a high relative amount of light weight PCB congeners. The paper bags that were analysed are made of strong paper and very popular among geochemists because of their watertight quality. These paper bags were manufactured more than 20 years ago. The plastic packaging that was analysed was produced in 1997 and 2008. The analyses of plastic and paper show that the raw material that has been used in the production at different times contains a wide concentration range of PCB. Re-sealable plastic bags, which contained the highest levels of PCB of the plastic material, are used by researchers world-wide as sampling bags for soils and sediments. This paper raises an important issue that packaging may potentially contaminate the samples that they hold.     

The Sensitivity of the Phanerozoic Inorganic Carbon System to the Onset of Pelagic Sedimentation

The onset of pelagic sedimentation attending the radiation of pelagic calcifiers during the Mesozoic was an important divide in Earth history, shifting the locus of significant carbonate sedimentation from the shallow shelf environments of the Paleozoic to the deep sea. This shift would have impacted the CO₂ cycle, given that decarbonation of subducted pelagic carbonate is an important return flux of CO₂ to the atmosphere. Coupled with the fact that the mean residence time of continental platform and basin sedimentary carbonate exceeds that of the oceanic crust, it thus becomes unclear whether carbon cycling would have operated on a substantially different footing prior to the pelagic transition. Here, we examine this uncertainty with sensitivity analyses of the timing of this transition using a coupled model of the Phanerozoic atmosphere, ocean, and shallow lithosphere. For purposes of comparison, we establish an age of 250 Ma (i.e., after the Permo-Triassic extinctions) as the earliest opportunity for deposition of extensive biogenic pelagic carbonate on the deep seafloor, an age that predates known occurrences of pelagic calcifiers (and intact seafloor). Although an approximate boundary, we do show that attempts to shift this datum either significantly earlier or later in time produce model results that are inconsistent with observed trends in the mass–age distribution of the rock record and with accepted trends in seawater composition as constrained by proxy data. Significantly, we also conclude that regardless of the timing of the onset of biogenic pelagic carbonate sedimentation, a carbon sink involving seawater-derived dissolved inorganic carbon played a critical role in carbon cycling, particularly in the Paleozoic. This CaCO₃ sink may have been wholly abiogenic, involving calcium derived either directly from seawater (thus manifest as a direct seafloor deposit), or alternatively from basalt–seawater reactions (represented by precipitation of CaCO₃ in veins and fissures within the basalt). Despite the uncertainty in the source and magnitude of this abiogenic CaCO₃ flux, it is likely a basic and permanent feature of global carbon cycling. Subduction of this CaCO₃ would have acted as a basic return circuit for atmospheric CO₂ even in the absence of biogenically derived pelagic carbonate sedimentation. Lastly, model calculations of the ratio of dissolved calcium to carbonate ion (Ca²⁺/CO₃ ^2?) show this quantity underwent significant secular evolution over the Phanerozoic. As there is increasing recognition of this ratio’s role in CaCO₃ growth and dissolution reactions, this evolution, together with progressive increases in nutrient availability and saturation state, may have created a tipping point ultimately conducive to the appearance of pelagic calcifiers in the Mesozoic.     

Identification of fractions of mercury in water,soil and sediment from a typical Hg mining area in Wanshan,Guizhou province,China

Water, sediment and soil in a region with severe Hg contamination resulting from Hg mining and retorting continue to receive anthropogenic Hg loading from discarded tailings and mine waste calcine piles, even after mining has ended. Crucial for potential long-term mobilization and uptake in biota, however, are chemical forms of Hg in the environment. In order to assess potential mobility and bioavailability of Hg in contaminated areas, a refined sequential extraction technique was used for Hg in soil and sediment, allowing identification of the following conceptual Hg fractions: elemental Hg, exchangeable Hg, strongly-bound Hg and organically-bound Hg.