纤磷钙铝石类化合物:来自地球具工艺用途的材料(英文)

纤磷钙铝石类化合物系由自纤磷钙铝石CaAl3 (OH) 6(HPO4) (PO4)本身、经磷钙铝石CaAl3 (OH) 6(SO4) (PO4)到钾明矾石KAl3 (OH ) 6(SO4) 2 等的天然矿物族所组成的。它们表现出具有很大范围的阳离子置换系列 ,其中以Sr2 +和Ba2 +置换Ca2 +,REEs3 +置换Ca2 +和H+,As5 +置换P5 +,S6+/Se6+置换H+P5 +最为重要。随着置换的进行 ,其热动力学稳定性也逐渐增加。由此 ,纤磷钙铝石类化合物成为很能抗风化的矿物 ,在红土中尤其如此。厚的纤磷钙铝石层形成在闪长岩 (富Sr) ,碳酸盐岩 (富REEs)和含金石英脉 (富As)之上 ,从而保护整个磷酸盐红土 ,使之免受风化。以此方式 ,形成了桌状山脉或岛屿 ,他们具有未受覆盖的表面。这些“纤磷钙铝”石化合物为上述及其它元素形成一有效的地球化学障。“纤磷钙铝石”的这种天然地球化学固定作用可以用适当的母体或人工合成晶体来进行模拟 ,即通过金属阳离子交换或就地反应来模拟。这种固定作用还可用于处理天然和人造的放射性裂变产物、有毒的重金属元素、砷酸盐和硒酸盐、硫酸盐等。     

New <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar age constraints on cooling and unroofing history of the metamorphic host rocks (and igneous intrusion associates) from the Bulfat Complex (Bulfat area), NE-Iraq

The Northern Zagros Suture Zone (NZSZ), formed as a result of the collision between Arabian and Sanandaj-Sirjan microplate, is considered as part of the Zagros orogenic belt. NZSZ is marked by two allochthonous thrust sheets in upward stacking order: lower and upper allochthon. The Bulfat complex is a part of the upper allochthon or “Ophiolite-bearing terrane” of Albian-Cenomenion age (97–105 Ma). Voluminous highly sheared serpentinites associated with ophiolites occur within this upper allochthon. In addition, the Gemo-Qandil Group is characterized by gabbroic to dioritic Bulfat intrusion with a crystallization age spanning from ~45 to ~?40 Ma, as well as extensive metapelites with contact to the Walash-Naupurdam metavolcanic rocks. Due to the deformation in the Sanandaj-Sirjan Zone along the eastern side of the Iraqi segment of NZSZ, the Gemo-Qandil Group was regionally metamorphosed during late Cretaceous (~?80 Ma). This tectono-compressional dynamics ultimately caused an oscillatory deformation against Arabian continental margin deposits as well. During these events, gabbro-diorite intrusion with high-grade contact metamorphic aureoles occurred near Bulfat. Thus, there is an overlap between regional and contact metamorphic conditions in the area. The earlier metamorphic characteristic can be seen only in places where the latter contact influence was insignificant. Generally, this can only observed at a distance of more than 2.5 km from the contact. According to petrographic details and field observations, the thermally metamorphosed metapelitic units of the metasediment have been completely assimilated, with only some streaks of biotite and relicts of initial foliation. They strongly resemble amphibolite-grade slices from the regional metamorphic rocks in the region. Metapelitic samples far from the intrusion give similar biotite cooling ages as the intrusive rocks. Thus, they may be affected by the same thermal event. ⁴⁰Ar/³⁹Ar dating of biotite in metapelite rocks of Bulfat by step-wise heating with laser gave average weighted isotopic ages of 34.78?±?0.06 Ma. This is interpreted as crystallization/recrystallization age of biotite possibly representing the time of cooling and uplift history of the Bulfat intrusion. Cooling and exhumation rates for the Bulfat gabbro-diorite rocks were estimated as ~?400 °C/Ma and ~?3.3 mm/year respectively. According to petrographic details, field observations and Ar/Ar dating concerning the contact metamorphism near Bulfat due to the gabbro-diorite intrusion, no significant deformation is visible during exhumation processes after the Paleogene tectono-thermal event, indicating that isotopic ages of 34.78?±?0.06 Ma could mark the timing of termination of the island arc activity in the Ophiolite-bearing terrane (upper allochthon).     

Hydrothermal alteration as a control of regional geochemistry and ore formation in the central Baltic Shield

In a geochemical study of the Proterozoic volcano-sedimentary Bergslagen ore province in central Sweden, more than 1000 eruptive rocks were analyzed for main and trace elements. The volcanic rocks form a bimodal suite dominated by rhyolites but deficient in andesites. Igneous geochemical variation bears little relevance to the occurrence and distribution of ores which mostly appear related to secondary alteration patterns. Hydrothermal metasomatic alteration occurs on a regional scale and has affected markedly more than half of the 732 analyzed, macroscopically fresh, porphyritic volcanic rocks. Metasomatism produced extreme Na- and K-differentiation, and Fe-Mg-Si relationships incompatible with igneous variation patterns. Enrichment in Na and Mg, and leaching of ore-forming metals are prominent in the lower parts of the volcanic pile, whereas meta-volcanics enriched in K and volcanogenic sediments associated with ores and marbles dominate the upper levels. The metasomatic alteration of the volcanic rocks and the formation of most ores are two aspects of a comprehensive process of hydrothermal convection which circulated sea water, extracted the ore-forming elements from the lower levels of the volcanic pile and enriched them at or close to the top of the volcanic sequence.

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Zusammenfassung Über 1000 proterozoische Eruptivgesteine der vulkanisch-sedimentären Erzprovinz in Mittelschweden wurden auf Haupt- bzw. Spurenelemente analysiert. Die Gesteine bilden eine Folge mit Schwerpunkt auf basaltischen und insbesondere rhyolitischen Zusammensetzungen, während Andesite nur schwach vertreten sind. Die primärmagmatische Zusammensetzung hat wenig Bezug zu den Erzen, die genetisch größtenteils an sekundäre Veränderungen gebunden sind. Hydrothermale Metasomatose hat eine regionale Verbreitung. Auch von den makroskopisch intakten, 732 analysierten, sauren porphyrischen Eruptivgesteinen sind mehr als die Hälfte durchgreifend verändert. Die metasomatischen Prozesse führten zu extremer Natriumund Kaliumdifferenzierung und zu Fe-Mg-Si-Beziehungen, die nicht auf magmatische Differentiation zurückzuführen sind. Anreicherung von Na und Mg und Auslaugen der erzbildenden Metalle treten in den tieferen Teilen der vulkanischen Schichtenfolge auf. Die höheren Lagen werden von kalireichen Metavulkaniten, Karbonatgesteinen und vulkanogenen, erzassoziierten Sedimenten beherrscht. Metasomatische Gesteinsumwandlung und Erzbildung sind zwei Teilprozesse einer großräumigen hydrothermalen Konvektion, durch die Meereswasser durch die Schichtenfolge getrieben wurde. Die erzbildenden chemischen Bestandteile wurden dabei den tieferen Teilen des Vulkanitpaketes entzogen und an oder nahe der Oberfläche angereichert.

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Résumé Dans le cadre d'une étude géochimique de la province protérozoïque volcano-sédimentaire minéralisée de Bergslagen (Suède centrale), plus de 1000 échantillons de roches magmatiques ont été analysés (éléments majeurs et traces). Ces roches volcaniques forment une suite dominée par les rhyolites et les basaltes, tandis que les andésites sont peu représentées. Les variations géochimiques montrent peu de relation avec la distribution des minerais, ceux-ci étant surtout engendrés lors de processus d'altération secondaires. En effet, une métasomatose hydrothermale s'est manifestée à l'échelle régionale au point d'affecter plus de la moitié des 732 porphyres volcaniques acides analysés, en dépit de l'aspect de fraîcheur qu'ils présentent macroscopiquement. La métasomatose se traduit par un fractionnement extrême de Na et K, ainsi que par des relations entre Fe-Mg-Si incompatibles avec la différenciation magmatique. La partie inférieure de la série volcanique stratifiée montre un enrichissement en Na et Mg ainsi qu'un lessivage des métaux des minerais. Dans la partie supérieure de la série, les termes dominants sont des métavolcanites riches en K, des marbres et des sédiments volcanogènes associés aux minerais. La modification métasomatique et la genèse des minerais sont deux aspects d'un vaste processus de convection hydrothermale qui a fait circuler l'eau de mer à travers la pile stratifiée, en enlevant les métaux des minerais dans la partie inférieure pour les concentrer dans la partie pouche du sommet.

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Middle and Late Holocene Sea-Level Changes in Eastern Maine Reconstructed from Foraminiferal Saltmarsh Stratigraphy and AMS C Dates on Basal Peat

A relative sea-level history is reconstructed for Machiasport, Maine, spanning the past 6000 calendar years and combining two different methods. The first method establishes the long-term (10³ yr) trend of sea-level rise by dating the base of the Holocene saltmarsh peat overlying a Pleistocene substrate. The second method uses detailed analyses of the foraminiferal stratigraphy of two saltmarsh peat cores to quantify fluctuations superimposed on the long-term trend. The indicative meaning of the peat (the height at which the peat was deposited relative to mean tide level) is calculated by a transfer function based on vertical distributions of modern foraminiferal assemblages. The chronology is determined from AMS ¹⁴C dates on saltmarsh plant fragments embedded in the peat. The combination of the two different approaches produces a high-resolution, replicable sea-level record, which takes into account the autocompaction of the peat sequence. Long-term mean rates of sea-level rise, corrected for changes in tidal range, are 0.75 mm/yr between 6000 and 1500 cal yr B.P. and 0.43 mm/yr during the past 1500 years. The foraminiferal stratigraphy reveals several low-amplitude fluctuations during a relatively stable period between 1100 and 400 cal yr B.P., and a sea-level rise of 0.5 m during the past 300 years.     

The Budget of Turbulent Kinetic Energy in the Urban Roughness Sublayer

Full-scale observations from two urban sites in Basel, Switzerland were analysed to identify the magnitude of different processes that create, relocate, and dissipate turbulent kinetic energy (TKE) in the urban atmosphere. Two towers equipped with a profile of six ultrasonic anemometers each sampled the flow in the urban roughness sublayer, i.e. from street canyon base up to roughly 2.5 times the mean building height. This observational study suggests a conceptual division of the urban roughness sublayer into three layers: (1) the layer above the highest roofs, where local buoyancy production and local shear production of TKE are counterbalanced by local viscous dissipation rate and scaled turbulence statistics are close to to surface-layer values; (2) the layer around mean building height with a distinct inflexional mean wind profile, a strong shear and wake production of TKE, a more efficient turbulent exchange of momentum, and a notable export of TKE by transport processes; (3) the lower street canyon with imported TKE by transport processes and negligible local production. Averaged integral velocity variances vary significantly with height in the urban roughness sublayer and reflect the driving processes that create or relocate TKE at a particular height. The observed profiles of the terms of the TKE budget and the velocity variances show many similarities to observations within and above vegetation canopies.     

The evolution of Pinatubo aerosols in the Arctic stratosphere during 1994–2000

Balloon-borne aerosol measurements were performed with an optical particle counter between 1994 and 2000 at Ny-Ålesund (79°N), Svarbard. Throughout the observation period, continuous decay was found in the concentrations of particles with 0.4–0.6 μm in radius in the Arctic stratosphere, suggesting that Pinatubo aerosols remained even at the end of the 1990s. The decay rate was clearly higher for larger particle sizes, and higher at higher altitude (e-folding time of 970–526 days), suggesting a gravitational sedimentation effect. For smaller particles with R<0.4 μm, slight increases in concentration with time were found, which agreed with the measurements at mid-latitude. The sulfate mass mixing ratio in the Arctic stratosphere before 1998 showed values higher than those at middle latitude, while values were almost the same in both regions after 1998. A possible explanation of the latitudinal difference is a time lag (of 0.5–1 year) in the arrival of Pinatubo aerosols in the Arctic.