The long-term simulation of surface SO2 and evaluation of contributions from the different emission sources to Beijing city

With a high-resolution SO2 emission inventory categorized by industries and seasons for Beijing city and gridded meteorological data fields from NCEP, the pollution dispersion model, HYSPLIT4 (Hybrid Single Particulate Lagrangian Integrated Trajectory, version 4), is used to determine the day-to-day variation of surface SO2 in Beijing for 2000 and 2001. Furthermore,the contributions of different emission sources in and around Beijing to the surface SO2 are studied. As shown in comparison with observations, the model does well in simulating the daily variation and seasonal distribution. The model computation of the annual source contributions to Beijing surface SO2 indicates that local emissions from the city give the largest contribution and the sources from the surrounding regions contribute only about 20%. During SO2 polluted or unpolluted days, the contribution from the latter can exceed 30%, and depending upon weather conditions, the contribution may exceed 40%. If the emissions from the surrounding sources during the winter heating season are assumed to be doubled in intensity, their contribution to surface SO2 in Beijing increased from 21% to 35% and 25% to 40% in 2000 and 2001, respectively. Evaluation of 7 types of emission sources identified for Beijing for their relative contribution to the concentration of surface SO2 has shown that area emissions by industrial production and furnaces, though discharging relatively small amounts (less than 1/3 of the total), have the largest contribution to the urban surface SO2, which is the key to the mitigation of the pollutant in the city.     

A 16-ka δ18O record of lacustrine sugar biomarkers from the High Himalaya reflects Indian Summer Monsoon variability

We investigated a late glacial–Holocene lacustrine sediment archive located at 4,050 m a.s.l. in the small carbonate-free catchment of Lake Panch Pokhari, Helambu Himal, Nepal. A δ¹⁸O sugar biomarker record was established by applying novel compound-specific δ¹⁸O analysis of plant sugar biomarkers (Zech and Glaser in Rapid Commun Mass Spectrom 23:3522–3532, 2009). This method overcomes analytical challenges such as extraction and purification faced by previous methods aimed at using δ¹⁸O of aquatic cellulose as a paleoclimate proxy. The δ¹⁸O results for sugar biomarkers arabinose, xylose and fucose agree well and reveal a pronounced trend towards lower δ¹⁸O values during the deglaciation and the onset of the Bølling/Allerød interstadial. By contrast, the period of the Younger Dryas is characterized by higher δ¹⁸O values. The early Holocene again reveals lower δ¹⁸O values. We suggest that our lacustrine δ¹⁸O record reflects coupled hydrological and thermal control. It is strongly related to changes in the oxygen isotopic composition of paleo-precipitation and resembles the δ¹⁸O records of Asian speleothems. With respect to the ‘amount effect,’ the record is interpreted as reflecting the Indian Summer Monsoon intensity. The precipitation signal is, however, amplified in our record by evaporative ¹⁸O enrichment that is controlled by the ratio of precipitation to evaporation. We suggest that our δ¹⁸O record reflects the variability of the Indian Summer Monsoon, which was strong during the Bølling/Allerød interstadial and early Holocene, but weak during the Younger Dryas stadial. This interpretation is corroborated by a pollen-based index for Lake Panch Pokhari that estimated the strength of the Indian Summer Monsoon versus the strength of the Westerlies. Millennial-scale synchronicity with the Greenland δ¹⁸O temperature records highlights the previously suggested strong teleconnections between the Asian Monsoon system and North Atlantic climate variability.     

Stellar velocity profiles and line strengths out to four effective radii in the early-type galaxies NGC 3379 and 821

We use the integral-field spectrograph SAURON to measure the stellar line-of-sight velocity distribution and absorption line strengths out to four effective radii ( R _e) in the early-type galaxies NGC 3379 and 821. With our newly developed observing technique, we can now probe these faint regions in galaxies that were previously not accessible with traditional long-slit spectroscopy. We make optimal use of the large field-of-view and high throughput of the spectrograph: by adding the signal of all ∼1400 lenslets into one spectrum, we obtain sufficient signal-to-noise in a few hours of observing time to reliably measure the absorption line kinematics and line strengths out to large radius.
We find that the line strength gradients previously observed within 1 R _e remain constant out to at least 4 R _e, which puts constraints on the merger histories of these galaxies. The stellar halo populations are old and metal poor. By constructing orbit-based Schwarzschild dynamical models, we find that dark matter is necessary to explain the observed kinematics in NGC 3379 and 821, with 30–50 per cent of the total matter being dark within 4 R _e. The radial anisotropy in our best-fitting halo models is less than in our models without halo, due to differences in orbital structure. The halo also has an effect on the  Mg  b – V _esc  relation: its slope is steeper when a dark matter halo is added to the model.     

Dione’s spectral and geological properties

We present a detailed analysis of the variations in spectral properties across the surface of Saturn’s satellite Dione using Cassini/VIMS data and their relationships to geological and/or morphological characteristics as seen in the Cassini/ISS images. This analysis focuses on a local region on Dione’s anti-saturnian hemisphere that was observed by VIMS with high spatial resolution during orbit 16 in October 2005. The results are incorporated into a global context provided by VIMS data acquired within Cassini’s first 50 orbits. Our results show that Dione’s surface is dominated by at least one global process. Bombardment by magnetospheric particles is consistent with the concentration of dark material and enhanced CO₂ absorption on the trailing hemisphere of Dione independent of the geology. Local regions within this terrain indicate a special kind of resurfacing that probably is related to large-scale impact process. In contrast, the enhanced ice signature on the leading side is associated with the extended ejecta of the fresh impact crater Creusa (∼49°N/76°W). Although no geologically active regions could be identified, Dione’s tectonized regions observed with high spatial resolution partly show some clean H₂O ice implying that tectonic processes could have continued into more recent times.     

Development and application of sedimentary pigments for assessing effects of climatic and environmental changes on subarctic lakes in northern Sweden

A surface-sediment survey of pigments in 100 lakes in the Scandes Mountains, northern Sweden, was combined with a reconstruction of Holocene sedimentary pigments from Lake Seukokjaure to assess the major factors regulating phototrophic communities, and how these controls may have changed during the period from the deglaciation (~9700 cal. years BP) to the present. The study area covers a pronounced gradient of temperature and precipitation, and encompasses the subarctic tree line, an important ecotonal boundary in this region. Lake Seukokjaure is located in a presently treeless basin close to the modern tree line. The spatial survey of sedimentary pigments was analyzed using principle components analysis (PCA) and redundancy analysis (RDA). PCA explained 73–83% of variance in pigment abundance and composition, whereas RDA explained 22–32% of variation in fossil assemblages. Dissolved organic carbon (DOC) content of lake water, sediment δ¹³C, maximum lake depth, elevation and lake-water conductivity were all identified as environmental variables with significant association with pigment abundances in the spatial survey, although phototrophic communities of lakes situated in different vegetation zones (alpine, birch, conifer/birch) were incompletely distinguished by the ordinations. In the RDAs, the primary pigment variability occurred along a production gradient that was correlated negatively to water-column DOC content and δ¹³C signature of sediments. This pattern suggested that the important controls of primary production were light regime and terrestrial supplies of ¹³C-depleted carbon. In contrast, depth, elevation and conductivity were found to be more important for the differentiation of the phototrophic community composition. Application of these spatial survey results to the Holocene sediment record of Lake Seukokjaure demonstrated the importance of DOC for the temporal development of the lake, from an early state of high production to a period of slight oligotrophication. In general, the algal changes were regulated by the interaction of DOC and conductivity, although transitions in the phototrophic community during the late Holocene were less easily interpreted. Terrestrial vegetation development thus appears to be of utmost importance for the regulation of primary production in oligotrophic alpine and subarctic lakes and climate impacts on lakes, whereas other basin-specific factors may control the ontogeny of algal community composition.     

Diatom transfer-functions for quantifying past air temperature, pH and total organic carbon concentration from lakes in northern Sweden

The relationships between diatoms (Bacillariophyceae) in surface sediments of lakes and summer air temperature, pH and total organic carbon concentration (TOC) were explored along a steep climatic gradient in northern Sweden to provide a tool to infer past climate conditions from sediment cores. The study sites are in an area with low human impact and range from boreal forest to alpine tundra. Canonical correspondence analysis (CCA) constrained to mean July air temperature and pH clearly showed that diatom community composition was different between lakes situated in conifer-, mountain birch- and alpine-vegetation zones. As a consequence, diatoms and multivariate ordination methods can be used to infer past changes in treeline position and dominant forest type. Quantitative inference models were developed to estimate mean July air temperature, pH and TOC from sedimentary diatom assemblages using weighted averaging (WA) and weighted averaging partial least squares (WA-PLS) regression. Relationships between diatoms and mean July air temperature were independent of lake-water pH, TOC, alkalinity and maximum depth. The results demonstrated that diatoms in lake sediments can provide useful and independent quantitative information for estimating past changes in mean July air temperature (R² _jack = 0.62, RMSEP = 0.86 °C; R² and root mean squared error of prediction (RMSEP) based on jack-knifing), pH (R² _jack = 0.61, RMSEP = 0.30) and TOC (R² _jack = 0.49, RMSEP = 1.33 mg l^-1). The paper focuses mainly on the relationship between diatom community composition and mean July air temperature, but the relationships to pH and TOC are also discussed.     

Diatom-based conductivity and water-level inference models from eastern Tibetan (Qinghai-Xizang) Plateau lakes

Climate in central Asia is dominated by the Asian monsoon. The varying impact of the summer monsoon across the Tibetan (Qinghai-Xizang) Plateau provides a strong gradient in precipitation, resulting in lakes of different salinity. Diatoms have been shown to indicate changes in salinity. Thus, transfer functions for diatoms and salinity or related environmental variables represent an excellent tool for paleoclimatic reconstructions in the Tibetan Plateau. Forty freshwater to hypersaline lakes (salinity: 0.1 to 91.7 g l^–1) were investigated in the eastern Tibetan Plateau. The relationship between 120 diatom taxa and conductivity, maximum water depth and major ions were analyzed using an indicator value approach, ordination and taxon response models. Canonical correspondence analysis indicated that conductivity was the most important variable, accounting for 10.8% of the variance in the diatom assemblages. In addition water depth and weathering were influential. Weighted Averaging (WA) and Weighted Averaging Partial Least Square (WA-PLS) regression and calibration models were used to establish diatom-conductivity and water depth transfer functions. An optimal two-component WA-PLS model provided a high jack-knifed coefficient of prediction for conductivity (r² _jack = 0.92), with a moderate root mean squared error of prediction (RMSEP_jack = 0.22), a very low mean bias (0.0003), and a moderate maximum bias (0.26). A WA model with tolerance downweighting resulted in a slightly lower r² _jack (0.89) for water depth, with RMSEP_jack= 0.26, mean bias = –0.0103 and maximum bias = 0.26.     

The use of egg shells to infer the historical presence of copepods in alpine lakes

Copepods (Class Crustacea, Order Copepoda) are rarely included in paleoecological studies of lakes because they lack long-lasting exoskeletal remains. We describe the remains of eggs (egg shells) from Hesperodiaptomus copepods that are well preserved and abundant in alpine lake sediments. We demonstrate that the egg shells are the remains of Hesperodiaptomus eggs based on (i) the similar size and morphology of egg shells collected from sediments and those produced from the hatching of eggs obtained from laboratory-maintained Hesperodiaptomus, and (ii) the finding that diapausing eggs collected from lake sediments and hatched in the laboratory produced copepod nauplii that were morphologically indistinguishable from those hatched from eggs produced by laboratory-maintained Hesperodiaptomus. Egg shells were approximately two orders of magnitude more abundant in sediment cores than were viable diapausing eggs, making egg shells superior to viable diapausing eggs for quantifying the historical presence and abundance of Hesperodiaptomus. These results have important implications for alpine lake restoration as egg shells can be used to identify lakes in which Hesperodiaptomus was eliminated by fish introductions but has failed to return after fish eradication, lakes in which the pre-disturbance conditions are likely to be restored only by reintroductions of this important taxon.