Climatic aspects and vertical structure circulation associated with the severe drought in Northeast Brazil (2012–2016)

Climate Dynamics - This study provides an updated dynamical analysis of the observed climate conditions during the longest, most severe and continuous drought (2012–2016) ever recorded in...     

Relation between the deposition and petrology of Shanxi coals and the composition of their extracts

The soluble organic material present in a set of 12 coal samples representing three major episodes of coal deposition in Shanxi Province, North China, has been examined. Shanxi coals, like those from Gondwanaland, contain little liptinite and accordingly the material extracted by pyridine yields only small quantities of n-hexane soluble n-alkanes, steranes and hopanes identifiable by gas-chromatography/mass spectrometry. The distribution of the n-alkanes is characteristic of the environment from which each of the Shanxi coals was formed but the distribution of the branched alkanes is generally determined by the dia- and catagenesis each coal experienced. Aromatic compounds identified in the extracts typify the small molecules present within the vitrinite lattice. Technologically significant benzene-methanol extracts deriving from vitrinite-inertinite have been characterised by proton NMR spectroscopy and partially separated by HPLC.     

Projected Reorganization of Florida Bay Seagrass Communities in Response to the Increased Freshwater Inflow of Everglades Restoration

Historic changes in water-use management in the Florida Everglades have caused the quantity of freshwater inflow to Florida Bay to decline by approximately 60% while altering its timing and spatial distribution. Two consequences have been (1) increased salinity throughout the bay, including occurrences of hypersalinity, coupled with a decrease in salinity variability, and (2) change in benthic habitat structure. Restoration goals have been proposed to return the salinity climates (salinity and its variability) of Florida Bay to more estuarine conditions through changes in upstream water management, thereby returning seagrass species cover to a more historic state. To assess the potential for meeting those goals, we used two modeling approaches and long-term monitoring data. First, we applied the hydrological mass balance model FATHOM to predict salinity climate changes in sub-basins throughout the bay in response to a broad range of freshwater inflow from the Everglades. Second, because seagrass species exhibit different sensitivities to salinity climates, we used the FATHOM-modeled salinity climates as input to a statistical discriminant function model that associates eight seagrass community types with water quality variables including salinity, salinity variability, total organic carbon, total phosphorus, nitrate, and ammonium, as well as sediment depth and light reaching the benthos. Salinity climates in the western sub-basins bordering the Gulf of Mexico were insensitive to even the largest (5-fold) modeled increases in freshwater inflow. However, the north, northeastern, and eastern sub-basins were highly sensitive to freshwater inflow and responded to comparatively small increases with decreased salinity and increased salinity variability. The discriminant function model predicted increased occurrences of Halodule wrightii communities and decreased occurrences of Thalassia testudinum communities in response to the more estuarine salinity climates. The shift in community composition represents a return to the historically observed state and suggests that restoration goals for Florida Bay can be achieved through restoration of freshwater inflow from the Everglades.     

Seafloor mapping for geohazard assessment: state of the art

During the last two decades, increasing use of full-coverage sonic mapping of the seafloor has made us more aware of the large and different number of seafloor processes and events bearing significant geohazard potential. This awareness combines with the increasing use of the seafloor for infrastructure and with the high density of population and settlement on the coast. Seafloor mapping is the first step in making a census of the geohazard-bearing features present in a given offshore area. It often provides the only tool for a comprehensive, although non-specific, seafloor geohazard assessment over large areas that are scarcely groundtruthed by acoustic prospection and seafloor sampling. However, the characterization of geohazard features on a morphological basis alone is limited, and more detailed investigations are needed to define the character and state of activity of potentially hazardous features. Such investigations include the use of deep-tow or autonomous platforms designed to acquire high-resolution data at depth as well as in situ measurements, both being very expensive activities not applicable over large areas. Thus seafloor mapping is often not only the first and the main but also the only tool for a comprehensive seafloor geohazard assessment. This special issue represents an example of the diversity of approaches to seafloor geohazard assessment and summarizes the present state of this discipline. Both the diverse technologies applied and the specific aims of offshore geohazard assessment brought different communities to deal with the study of seafloor processes and events from remarkably distinct viewpoints. We identified three end members in offshore geohazard assessment: (1) geohazard assessment ??sensu stricto??, (2) ??engineering?? geohazard assessment, (3) ??non-specific?? geohazard assessment. These are being conducted by industry, academia and public agencies in charge of civil protection and land-use planning and management. Understanding the needs and geohazard perception of the different groups is a necessary step for a profitable collaboration in such an interesting and rapidly developing field of marine geology.     

Product formation from the gas-phase reactions of OH radicals and O3 with a series of monoterpenes

The formation yields of nine carbonyl products are reported from the gas-phase OH radical-initiated reactions (in the presence of NO _x ) and the O₃ reactions with seven monoterpenes. The products were identified using GC/MS and GC-FTIR and quantified by GC-FID analyses of samples collected on Tenax solid adsorbent cartridges. The identities of products from camphene, limonene and -pinene were confirmed by comparison with authentic standards. Sufficient quantities of products from the 3-carene, limonene, -pinene, sabinene and terpinolene reactions were isolated to allow structural confirmation by proton NMR spectroscopy. The measured total carbonyl formation yields ranged from non-detectable for the OH radical reaction with camphene and the O₃ reactions with 3-carene and limonene to 0.5 for the OH radical reaction with limonene and the O₃ reaction with sabinene.     

The mid-IR radio correlation at high angular resolution: NGC253

We present high angular resolution (1.2), narrow band (/=0.1) images of the nucleus of NGC253 at three wavelengths in the mid-IR (8.5, 10.0, and 12.5 m). We find that most of the mid-IR flux in the nucleus of NGC253 derives from a very small region 120 pc in diameter. Within this small region there are three spatially and spectrally distinct IR components: two bright compact sources, and a surrounding envelope of low level, diffuse emission. The mid-IR and 6cm radio are loosely correlated in position but not in brightness. The implication is that the mid-IR - radio correlation may begin to break down on small spatial scales relevant to individual star forming regions and large individual sources. These variations in the mid-IR spectra and in the radio-IR correlation imply that the nuclear emission is excited by more than one mechanism and source type.     

Alkyl nitrate formation from the atmospheric photoxidation of alkanes; a revised estimation method

The available experimental data concerning the yields of alkyl nitrates in the reactions of alkyl peroxy radicals with NO have been used to derive a revised expression for the estimation of alkyl nitrate yields in the atmospheric photooxidation of alkanes as a function of temperature and pressure. This revised expression gives more reasonable predictions of alkyl nitrate yields under high altitude tropospheric conditions than that which has been previously published.     

Sediment accumulation and its effects on a Mississippi River oxbow lake

Recent sediment accumulation rates were measured in Moon Lake, a large (10.1 km²) Mississippi River oxbow lake in northwestern Mississippi. Moon Lake, which receives channeled inflow from an intensively cultivated soybean, rice, and cotton watershed (166 km²) and limited overland flow from surrounding lands, exhibited depositional patterns that were associated with (1) points of inflow, (2) flow patterns, and (3) lake morphology. From 1954 to 1965, 70 percent of the lake bottom experienced accumulation rates greater than 2 cm/yr. Accumulation rates exceeded 4 cm/yr in areas of delta formation. Changes in cropping systems during the 1960s, from cotton to soybeans and rice which require less cultivation, resulted in significantly (a = 0.01) less sediment accumulation during the period 1965- 1982 when 86 percent of the lake averaged less than 2 cm/yr sediment deposition. If current sediment accumulation rates continue, open water habitat in the lake will be reduced by only 3 to 7 percent during the next 50 years.Contribution of the Sedimentation Laboratory, Agricultural Research Service, U.S. Department of Agriculture, Oxford, MS 38655