Evaluation of a distributed model for urban catchments using a 7‐year continuous data series

The documentation existing on both land use and the delineation of pervious and impervious zones in urban areas tends to be rather complete. In addition, topographical information (altitudes, slopes) is generally available, although contours are not drawn in detail on urban‐area maps. The development of urban databases has provided a convenient means of accessing this information for the purpose of hydrological modelling. The objective of this paper is to evaluate a recent model, ‘SURF’ (semi‐urbanized runoff flow), specifically developed for coupling with a GIS based on a digital terrain representation. This model was evaluated by use of an original approach from the field of urban hydrology. A 7‐year continuous data series, which includes the dry periods, has been used as input to run the model. The principles behind the SURF model are briefly described herein. A sensitivity analysis is then performed in order to select the most influential parameters. Following the calibration stage, the model's validation is discussed. This validation is conducted not only by comparing observed and simulated hydrographs, but also by comparing the SURF model with a more conventional model in urban hydrology, called the URBAN model. It is demonstrated that the SURF model provides useful simulation results and does outperform the URBAN model. Copyright © 2000 John Wiley & Sons, Ltd.     

Ancient subsurface structure beneath crater Clavius:constraint by recent high-precision gravity and topography data

With the increasing precision of the GRAIL gravity field models and topography from LOLA, it is possible to investigate the substructure beneath crater Clavius. An admittance between gravity and topography data is commonly used to estimate selenophysical parameters, including load ratio, crustal thickness and density, and elastic thickness. Not only a surface load, but also a subsurface load is considered in estimation. The algorithm of particle swarm optimization(PSO) with a swarm size of 400 is employed as well.Results indicate that the observed admittance is best-fitted by the modeled admittance based on a spherical shell model, which was proved to be unsatisfactory in the previous study. The best-fitted load ratio f is around-0.194. Such a small load ratio conforms to the direct proportion between the nearly uncompensated topography and its corresponding negative gravity anomaly. It also indicates that a surface load dominates all the loads. Constrained within 2σSTD, a small crustal thickness(～30 km) and a crustal density of ～2587 kg m-3are found, quite close to the results from previous GRAIL research. Considering the well constrained crustal thickness and density, the best-fitted elastic thickness(～7 km) is rational. This result is slightly smaller than the previous study(～12 km). Such difference can be attributed to the difference in crustal density used and the precision of gravity and topography data. Considering that the small difference between the modeled gravity anomaly and observations is quite small, a parameter inversed here could be an indicator of the subsurface structure beneath Clavius.     

Catastrophic hurricane history revealed by organic geochemical proxies in coastal lake sediments: a case study of Lake Shelby,Alabama (USA)

We developed a new method for reconstructing millennia-long hurricane records from coastal environments that uses Organic Geochemical Proxies (OGPs) of organic carbon and nitrogen concentrations and their δ¹³C and δ¹⁵N compositions. The new method is independent of presence/absence of sand layers and improves significantly the severe-storm history resolution. The subject of this investigation is a 1.5 m long sediment core raised at 2.8 m water depth from the center of Lake Shelby, Alabama, a freshwater lake located approximately 250 m from the Gulf of Mexico, from which an overwash sand-layer based record was previously derived. The core contains two distinct sediment units; an upper 62 cm thick, fine-grained, organic-rich lacustrine sapropel (gyttja) that shows no visible structures except one sand lamina at 23.7 cm depth, and an underlying 90 cm thick, organic-poor lagoon/estuary clay unit. The sapropel unit was deposited over a 682 ± 30 cal year time interval (1320–2002 A.D.) with a mean sedimentation rate of 0.79 ± 0.04 mm/year. Lake Shelby’s water column exhibits two contrasting states based on water chemistry surveys (i) an “isolated”, stratified, mode under calm weather conditions with a relatively low trophic state, and (ii) a “flooded” mode occurring during storm surges when nutrient-rich seawater floods the lake. Statistically significant δ¹³C and δ¹⁵N positive excursions in organic matter, up to maximum values of −25 (‰ PDB) and 4 (‰ Air N₂), respectively, are interpreted as geochemical responses to the marine intrusions that fertilize the lake, increase light availability, and cause eutrophication spikes. Detailed OGPs analyses crossing a sand layer that offers visual evidence of a catastrophic hurricane overwash event at 1717 A.D. exhibit large δ¹³C and δ¹⁵N positive shifts bounded by rapid returns to base values, thus confirming the validity of the hurricane identification by the OGPs model. Our data indicate that 11 catastrophic hurricanes hit the Alabama coast over the past 682 years with a rough recurrence interval of one in 62 years.     

Extreme rainfall events in Catalonia. The case of 12 November 1988

A study of the synoptic situation which produced the catastrophic floods of November 1988 in Catalonia (in the northeast of the Iberian Peninsula) is presented. Analyses of the vertical structure, potential instability, precipitable water, and instability index are made through the radiosounding data from Palma, Majorca. It is found that the 1988 situation is included in type I intense convective events in Catalonia (classification obtained from all the events since 1950, (Llasat, 1989)). It was characterized by:

Solar radar astronomy with the low-frequency array

Initial studies of the Sun's corona using a solar radar were done in the 1960s and provided measurements of the Sun's radar cross-section at about 38 MHz. These initial measurements were done at a time when the large-scale phenomenon known as a coronal mass ejection was unknown; however, these data suggest that coronal mass ejections (CMEs) may have been detected but were unrecognized. That solar radar facility, which was located at El Campo, TX, no longer exists. New solar radar investigations are motivated by our modern understanding of CMEs and their effects on the Earth. A radar echo from an Earthward-directed coronal mass ejection may be expected to have a frequency shift proportional to velocity; thus providing a good estimate of arrival time at Earth and the possible occurrence of geomagnetic storms. Solar radar measurements may also provide new information on electron densities in the corona. The frequencies of interest for solar radars fall in the range of about 10–100 MHz, corresponding to the lower range planned for the low-frequency array. In combination with existing or new high-power transmitters, it is possible to use the low-frequency array to re-initiate radar studies of the Sun's corona. In this report, we review the basic requirements of solar radars, as developed in past studies and as proposed for future investigations.     

A single vs. double spike approach to improve the accuracy of Th measurements in small-volume seawater samples

²³⁴Th is a particle-reactive radionuclide widely used to trace biogeochemical oceanic processes occurring over short timescales. During the last few years, small-volume techniques based on the co-precipitation of ²³⁴Th with MnO₂ coupled with beta-counting have been developed as an alternative to large volume gamma-spectrometric techniques. Here a procedure has been developed to enhance quantitative measurement of ²³⁴Th in MnO₂ precipitates. The main objectives were to obtain a purified Th fraction for beta-counting and to determine the chemical recovery of ²³⁴Th using Th spikes and alpha-spectrometry as an alternative to ICP-MS based methods. Two variations of the procedure are presented. In the first “1 spike” method a ²³⁰Th tracer is added to the sample prior to precipitation of MnO₂, and UTEVA® extraction chromatography is used to obtain a NdF₃(Th) purified source that can be used for both beta-counting of ²³⁴Th and alpha-spectrometry of ²³⁰Th. In the “2 spike” method a ²³⁰Th spike is added and the MnO₂(Th) precipitate is directly beta-counted for ²³⁴Th and subsequently spiked with ²²⁸Th or ²²⁹Th prior to UTEVA® purification and alpha-spectrometry. The results confirm the need to process small-volume seawater samples for ²³⁴Th measurement in presence of a yield tracer, and show that both the 1 spike and 2 spike methods allow an accurate and precise determination of ²³⁴Th (relative percent difference, RPD, between expected and mean measured value < 1%; CV between replicate samples < 3%). Our work also suggests that, although the combined analytical uncertainty on total ²³⁴Th measurements accomplished with both versions of the NdF₃ procedure is promising (6% for 2-L samples), the precision of the ²³⁴Th flux estimation will ultimately depend on the degree of disequilibrium between ²³⁴Th and ²³⁸U.     

A review of present techniques and methodological advances in analyzing Th in aquatic systems

The short-lived thorium isotope ²³⁴Th (half-life 24.1 days) has been used as a tracer for a variety of transport processes in aquatic systems. Its use as a tracer of oceanic export via sinking particles has stimulated a rapidly increasing number of studies that require analyses of ²³⁴Th in both marine and freshwater systems. The original ²³⁴Th method is labor intensive. Thus, there has been a quest for simpler techniques that require smaller sample volumes. Here, we review current methodologies in the collection and analysis of ²³⁴Th from the water column, discuss their individual strengths and weaknesses, and provide an outlook on possible further improvements and future challenges. Also included in this review are recommendations on calibration procedures and the production of standard reference materials as well as a flow chart designed to help researchers find the most appropriate ²³⁴Th analytical technique for a specific aquatic regime and known sampling constraints.