Comparative study of urban development and groundwater condition in coastal areas of Buenos Aires,Argentina

The geomorphological evolution of a sand-dune barrier in Buenos Aires, Argentina, is analyzed as a factor regulating the fresh groundwater reserves available. The impact of geomorphological evolution and the consequences for the social and economic development of two coastal areas are assessed. This is one of the most important tourist destinations in the country; for study purposes, it was divided into a northern sector and a southern sector. In the southern sector, the exploitable groundwater is associated with the Holocene and upper Pleistocene geomorphological evolution, which generated three interrelated aquifer units, constituting a system whose useful thickness reaches at least 45 m. In contrast, the northern sector is restricted to two Holocene aquifer units, whose total thickness is on the order of 12 m. The morphological characteristics and the occurrence of the largest fresh groundwater reserves in the southern sector are indicators of better conditions for economic growth, which is mainly reflected on the expansion of real estate ventures. The relationships of transmissivity vs area of real estate ventures (Arev), and total water consumption vs Arev, are indicators for the sustainable management of the water resources. The approach chosen may be used by decision makers in other regions to assess the feasibility of future tourism projects on the basis of the availability of water resources associated with geomorphological features.     

Application of Laser‐Induced Breakdown Spectroscopy and Hyperspectral Images for Direct Evaluation of Chemical Elemental Profiles of Coprolites

This study demonstrates the application of laser‐induced breakdown spectroscopy (LIBS) and hyperspectral imaging to the investigation of coprolite and fossil samples. Solid samples from the Permian (seven coprolites and one fossil), Cretaceous (one coprolite) and Oligo‐Miocene (two coprolites) periods were directly analysed, and emission spectra from 186 to 1042 nm were obtained in several areas covering coprolite/fossil and rock material. Initial exploratory analyses were performed using principal component analysis with the data set normalised by the norm (Euclidean norm = 1). After identification and selection of emission lines of eleven elements (Al, Ca, Cr, Fe, K, Mg, Mn, Na, Ni, P and Si), the signals were normalised again by the relative intensity of the selected element. Phosphorus was identified mainly in the coprolites, while K and Na were primarily found in the rock material. In several cases, there was a positive correlation between Ca and P. A sample from the Oligo‐Miocene series was also analysed using inductively coupled plasma‐optical emission spectrometry (ICP‐OES) (rock and coprolites were analysed separately). Based on the quantitative results from ICP‐OES, it was confirmed that the tendency was the same as that observed with the results obtained from LIBS directly in the solid sample.     

An approximate nearest neighbors search algorithm for low-dimensional grid locations

We propose a new algorithm for the problem of approximate nearest neighbors (ANN) search in a regularly spaced low-dimensional grid for interpolation applications. It associates every sampled point to its nearest interpolation location, and then expands its influence to neighborhood locations in the grid, until the desired number of sampled points is achieved on every grid location. Our approach makes use of knowledge on the regular grid spacing to avoid measuring the distance between sampled points and grid locations. We compared our approach with four different state-of-the-art ANN algorithms in a large set of computational experiments. In general, our approach requires low computational effort, especially for cases with high density of sampled points, while the observed error is not significantly different. At the end, a case study is shown, where the ionosphere dynamics is predicted daily using samples from a mathematical model, which runs in parallel at 56 different longitude coordinates, providing sampled points not well distributed that follow Earth’s magnetic field-lines. Our approach overcomes the comparative algorithms when the ratio between the number of sampled points and grid locations is over 2849:1.     

Drying of salt-contaminated masonry: MRI laboratory monitoring

Drying of masonry specimens was monitored by means of a two-dimensional (2D) magnetic resonance imaging (MRI) technique. The external surfaces stayed wet for longer if NaCl was present instead of pure water only. This corroborates many practical observations that salts aggravate dampness in masonry. A slower evaporation process and not hygroscopicity was the cause. That suggests that salt-induced dampness may, in general, arise simply from changes in the drying process of masonry materials. That also implies that the height and depth at which crystallization occurs in walls may depend on the relative equilibrium humidity (RHeq) and other properties of salts that influence drying of porous materials. Evaporation rates of free surfaces of pure water and saturated NaCl solution were measured by a gravimetric technique. The results indicate that slow drying of salt-contaminated materials is not due only to the lower RHeq of salt solutions. The effective surface of evaporation is likely to be reduced perhaps due to blocking of pores by salt crystals. Final salt-distribution maps of the specimens show that: (a) salts may affect the inner materials of the masonry, even in evaporation-induced processes that lead crystallization to occur predominantly on the external surface; (b) distinct internal distribution patterns occur if masonry composition varies. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.     

Calculating derivatives for automatic history matching

Automatic history matching is based on minimizing an objective function that quantifies the mismatch between observed and simulated data. When using gradient-based methods for solving this optimization problem, a key point for the overall procedure is how the simulator delivers the necessary derivative information. In this paper, forward and adjoint methods for derivative calculation are discussed. Procedures for sensitivity matrix building, sensitivity matrix and transpose sensitivity matrix vector products are fully described. To show the usefulness of the derivative calculation algorithms, a new variant of the gradzone analysis, which tries to address the problem of selecting the most relevant parameters for a history matching, is proposed using the singular value decomposition of the sensitivity matrix. Application to a simple synthetic case shows that this procedure can reveal important information about the nature of the history-matching problem.     

Age and magnetic fabric of the Três Córregos granite batholith: evidence for Ediacaran transtension in the Ribeira Belt (SE Brazil)

Anisotropy of magnetic susceptibility (AMS) and U–Pb (SHRIMP) zircon ages in the eastern part of the Três Córregos batholith (Ribeira belt, SE Brazil) indicate a well-defined fabric pattern acquired between 600 and 595 Ma. The batholith consists mostly of porphyritic granites distributed in the Ribeirão Branco, Barra do Chapéu and Itaóca plutons. Late fluorite-bearing alkaline granites, some containing Sn-polymetallic greisen-type deposits, intruded the Ribeirão Branco pluton and the low-grade metasedimentary host rocks. The magnetic fabric of the Ribeirão Branco granite is dominantly oblate and oblique to the pluton elongation while that in Barra do Chapéu is mostly concentric. On both plutons, AMS records the preferred orientation of coarse, homogeneous Ti-poor magnetite grains. Such fabric patterns indicate a partitioned strain field dominated by strike-slip left-lateral shear deformation in the Ribeirão Branco and extension in the Barra do Chapéu pluton. The zircon ages of these plutons are 600 ± 6 Ma and 595 ± 4 Ma. Likewise, the ages of alkaline plutons were in the range of 597 and 595 Ma, registering a fast transition between the typical syntectonic batholithic magmatism to the late, highly evolved and specialized magmas. These results indicate that the Ribeira belt was deformed by transtension in the Middle Ediacaran. The geological setting is consistent with a continental arc with the Três Córregos batholith emplacing at the middle-upper crust.     

Complex Oceanological Research during the 59th Cruise of the Research Vessel Akademik Ioffe in the Eastern North Atlantic (September–October 2021)

Oceanology - During the 59th cruise of the P/V Akademik Ioffe (September–October 2021), geophysical, sedimentological, hydrological, hydrochemical, and biological studies were carried out in...     

Climate change hotspots over South America: from CMIP3 to CMIP5 multi-model datasets

This study identifies possible hotspots of climate change in South America through an examination of the spatial pattern of the Regional Climate Change Index (RCCI) over the region by the end of the twenty-first century. The RCCI is a qualitative index that can synthesize a large number of climate model projections, and it is suitable for identifying those regions where climate change could be more pronounced in a warmer climate. The reliability and uncertainties of the results are evaluated by using numerous state-of-the-art general circulation models (GCMs) and forcing scenarios from the Coupled Model Intercomparison Project phases 3 and 5. The results show that southern Amazonia and the central-western region and western portion of Minas Gerais state in Brazil are persistent climate change hotspots through different forcing scenarios and GCM datasets. In general, as the scenarios vary from low- to high-level forcing, the area of high values of RCCI increase and the magnitude intensify from central-western and southeast Brazil to northwest South America. In general, the climatic hotspots identified in this study are characterized by an increase of mean surface air temperature, mainly in the austral winter; by an increase of interannual temperature variability, predominantly in the austral summer; and by a change in the mean and interannual variability of precipitation during the austral winter.     

Distribution patterns of the ghost crab Ocypode cursor on sandy beaches of a tropical island in the Cabo Verde archipelago,Eastern Central Atlantic

The spatial distribution of the ghost crab Ocypode cursor was determined for beaches on eastern Boa Vista Island, Cabo Verde Archipelago. The main objectives were to analyse the across-shore distribution by means of burrow counts and to identify preferential zones and spatial segregation. Six beaches were investigated using 20 across-shore beach transects. It was demonstrated that ghost crabs occur throughout the entire intertidal zone, with higher densities in a 9–13 m band above the waterline. There was an exponential relationship between the carapace length of captured crabs and the diameter of their burrows. Mean burrow diameter was correlated with burrow density and increased linearly with distance from the waterline, although small burrows, representing individuals smaller than the median size, occurred across the beach. Burrow diameter and depth were positively correlated, with larger holes indicating larger crabs and deeper burrows. Deeper burrows were more common in the upper intertidal zone. These results are similar to those described for ghost crab populations elsewhere and contribute to an understanding of the ecology of the species in the local context.     

A poly-ε-caprolactone based biofilm carrier for nitrate removal from water

Nitrate removal from water has been accomplished by heterotrophic biofilms using organic carbon as a source of reducing power. To overcome the natural limitation in organic carbon in water, a poly-ε-caprolactone based biofilm carrier that serves simultaneously as a biofilm carrier and as a source of organic carbon was developed and tested in the present work. The feasibility of the new biofilm carrier for nitrate removal from water was evaluated in a packed bed reactor. The combination of size and structure provided a carrier element having high surface area and void volume, 1,170 m²/m³ and 67 %, respectively. A maximum denitrification rate of 4.4 mg N–NO₃ ^?/(L.h) (9.2 mg N–NO₃ ^?/(m².h)) was achieved in the packed bed reactor at 20 °C and pH 7.0. Main advantages of the biofilm carrier developed in the present work are its mechanical stability in water even after biofilm formation and controlled release of organic carbon by enzymatic reactions. The proposed biotechnology to remove nitrate from groundwater is robust and easy to operate.