华南花岗岩暗色微粒包体矿物组成及微结构研究

对来自华南多个花岗岩体的暗色微粒包体样品进行了系统的矿物组成和微结构研究,发现包体中不管是造岩矿物还是副矿物,均存在新、老两个不同世代;包体的微结构大部分情况下也不是“火成结构”,而是以熔融结构为主,并且常多种结构共存,揭示包体是岩石部分熔融的残余物而并非来自岩浆的结晶。不同包体或同一包体从中心到边缘的矿物组成与微结构的差异,反映原岩部分熔融程度的不同,揭示其处于不同的演化阶段。     

ELA-ICP-MS U–Pb zircon geochronology of regional volcanism hosting the Bajo de la Alumbrera Cu–Au deposit: implications for porphyry-related mineralization

ELA-ICP-MS U–Pb zircon geochronology has been used to show that the porphyritic intrusions related to the formation of the Bajo de la Alumbrera porphyry Cu–Au deposit, NW Argentina, are cogenetic with stratigraphically well-constrained volcanic and volcaniclastic rocks of the Late Miocene Farallón Negro Volcanic Complex. Zircon geochronology for intrusions in this deposit and the host volcanic sequence show that multiple mineralized porphyries were emplaced in a volcanic complex that developed over 1.5 million years. Volcanism occurred in a multi-vent volcanic complex in a siliciclastic intermontane basin. The complex evolved from early mafic-intermediate effusive phases to a later silicic explosive phase associated with mafic intrusions. Zircons from the basal mafic-intermediate lavas have ages that range from 8.46±0.14 to 7.94±0.27 Ma. Regionally extensive silicic explosive volcanism occurred at ~8.0 Ma (8.05±0.13 and 7.96±0.11 Ma), which is co-temporal with intrusion of the earliest mineralized porphyries at Bajo de la Alumbrera (8.02±0.14 and 7.98±0.14 Ma). Regional uplift and erosion followed during which the magmatic-hydrothermal system was probably unroofed. Shortly thereafter, dacitic lava domes were extruded (7.95±0.17 Ma) and rhyolitic diatremes (7.79±0.13 Ma) deposited thick tuff blankets across the region. Emplacement of large intermediate composition stocks occurred at 7.37±0.22 Ma, shortly before renewed magmatism occurred at Bajo de la Alumbrera (7.10±0.07 Ma). The latest porphyry intrusive event is temporally associated with new ore-bearing magmatic-hydrothermal fluids. Other dacitic intrusions are associated with subeconomic deposits that formed synchronously with the mineralized porphyries at Bajo de la Alumbrera. However, their emplacement continued (from 7.10± 0.06 to 6.93±0.07 Ma) after the final intrusion at Bajo de al Alumbrera. Regional volcanism had ceased by 6.8 Ma (6.92±0.07 Ma). The brief history of the volcanic complex hosting the Bajo de la Alumbrera Cu–Au deposit differs from that of other Andean provinces hosting porphyry deposits. For example, at the El Salvador porphyry copper district in Chile, magmatism related to Cu mineralization was episodic in regional igneous activity that occurred over tens of millions of years. Bajo de la Alumbrera resulted from the superposition of multiple porphyry-related hydrothermal systems, temporally separated by a million years. It appears that the metal budget in porphyry ore deposits is not simply a function of their longevity and/or the superposition of multiple porphyry systems. Nor is it a function of the duration of the associated cycle of magmatism. Instead, the timing of processes operating in the parental magma body is the controlling factor in the formation of a fertile porphyry-related ore system.Electronic Supplementary Material Electronic supplementary material to this paper can be obtained by using the Springer Link server located at Editorial handling: N. White     

Origin of LateTriassic high-Mg adakitic granitoid rocks from the Dongjiangkou area,Qinling orogen,central China: Implications for subduction of continental crust

The origin of high-Mg adakitic granitoids in collisional orogens can provide important information about the nature of the lower crust and upper mantle during the orogenic process. Late-Triassic high-Mg adakitic granite and its mafic enclaves from the Dongjiangkou area, the Qinling orogenic belt, central China, were derived by partial melting of subducted continental crust and underwent interaction with the overlying mantle wedge peridotite. Adakitic affinity of the different facies of the Dongjiangkou granite body are: high Sr, Ba, high La/Yb and Sr/Y, low Y,Yb, Yb/Lu and Dy/Yb, and no significant Eu anomalies, suggesting amphibole + garnet and plagioclase-free restite in their source region. Evolved Sr-Nd-Pb isotopic compositions [(⁸⁷Sr/⁸⁶Sr)_i = 0.7050 to 0.7055,ε_Nd(t) = –6.6 to –3.3; (²⁰⁶Pb/²⁰⁴Pb)_i = 17.599 to 17.799, (²⁰⁷Pb/²⁰⁴Pb)_i = 15.507 to 15.526, (²⁰⁸Pb/²⁰⁴Pb)_i = 37.775 to 37.795] and high K₂O, Rb, together with a large variation in zircon Hf isotopic composition (ε_Hf(t) = ?9.8 to + 5.0), suggest that the granite was derived from reworking of the ancient lower continental crust. CaO, P₂O₅, K₂O/Na₂O, Cr, Ni, Nb/Ta, Rb/Sr and Y increase, and SiO₂, Sr/Y and Eu/Eu* decrease with increasing MgO, consistent with interaction of primitive adakitic melt and overlying mantle peridotite. Zircons separated from the host granites have U-Pb concordia ages of 214 ± 2 Ma to 222 ± 2 Ma, compatible with exhumation ages of Triassic UHP metamorphic rocks in the Dabie orogenic belt. Mafic microgranular enclaves and mafic dykes associated with the granite have identical zircon U-Pb ages of 220 Ma, and are characterized by lower SiO₂, high TiO₂, Mg# and similar evolved Sr-Nd-Pb isotopic composition. Zircons from mafic microgranular enclaves (MMEs) and mafic dykes also show a large variation in Hf isotopic composition with ε_Hf(t) between ?11.3 and + 11.3. It is inferred that they were formed by partial melting of enriched mantle lithosphere and contaminated by the host adakitic granite magma.In combination with the regional geology, high-Mg# adakitic granitoid rocks in the Dongjiangkou area are considered to have resulted from interaction between subducted Yangtze continental crust and the overlying mantle wedge. Triassic continental collision caused detachment of the Yangtze continental lithosphere subducted beneath the North China Craton, at ca. 220 Ma causing asthenosphere upwelling and exhumation of the continental crust. Triassic clockwise rotation of the Yangtze Craton caused extension in the Dabie area which led to rapid exhumation of the subducted continental lithosphere, while compression in the Qinling area and high-P partial melting (amphibole ± garnet stability field) of the subducted continental crust produced adakitic granitic magma that reacted with peridotite to form Mg-rich hybrid magma.     

Bacteria—particle interactions in turbid estuarine environments

A study of the distribution of bacteria in relation to particle concentration and type was conducted over a spring-neap tidal cycle in the Tamar Estuary, southwest England. Three groups of bacteria were recognized: free-living; those attached to permanently suspended particles; and those attached to particles which undergo tidally controlled resuspension and sedimentation. The total activity and the activity of all three groups of bacteria increase in the turbidity maximum region. The bacteria associated with the permanently suspended particles, which have a larger mean size and organic carbon content than those in the resuspended sediments, contribute the major part of this increased activity. This is a significant finding as it had been previously thought that the increase in bacterial activity at the turbidity maximum was due to bacteria attached to resuspended sediments. However, resuspension still plays an important role because the increase in bacterial activity is consistently coincident with the turbidity maximum.     

Planetary migration in a planetesimal disk: why did Neptune stop at 30 AU?

We study planetary migration in a gas-free disk of planetesimals. In the case of our Solar System we show that Neptune could have had either a damped migration, limited to a few AUs, or a forced migration up to the disk's edge, depending on the disk's mass density. We also study the possibility of runaway migration of isolated planets in very massive disk, which might be relevant for extra-solar systems. We investigate the problem of the mass depletion of the Kuiper belt in the light of planetary migration and conclude that the belt lost its pristine mass well before that Neptune reached its current position. Therefore, Neptune effectively hit the outer edge of the proto-planetary disk. We also investigate the dynamics of massive planetary embryos embedded in the planetesimal disk. We conclude that the elimination of Earth-mass or Mars-mass embryos originally placed outside the initial location of Neptune also requires the existence of a disk edge near 30AU.     

华南花岗岩暗色微粒包体成因研究

通过对暗色微粒包体的空间分布和形态特征以及包体矿物学、显微结构和岩石化学组成等方面的研究成果,在花岗岩“原地重熔”成因模型的基础上,建立了包体演化与熔渣演化的关系模型,证实包体的前身是捕虏体,后者代表从盖层落入岩浆中的岩块,包体则是岩块部分熔融后的残余物。不同类型、不同形态、不同基性度的包体,代表了岩石原地熔融过程中不同阶段的产物,富云包体反映了熔渣演化的最后阶段,在此基础上的进一步熔融即与寄主岩浆混成一体,完成了从岩石到岩浆的整个演化过程。     

The use of tracers to assess leakage from the sequestration of CO2 in a depleted oil reservoir,New Mexico,USA

Geological sequestration of CO₂ in depleted oil reservoirs is a potentially useful strategy for greenhouse gas management and can be combined with enhanced oil recovery. Development of methods to estimate CO₂ leakage rates is essential to assure that storage objectives are being met at sequestration facilities. Perfluorocarbon tracers (PFTs) were added as three 12 h slugs at about one week intervals during the injection of 2090 tons of CO₂ into the West Pearl Queen (WPQ) depleted oil formation, sequestration pilot study site located in SE New Mexico. The CO₂ was injected into the Permian Queen Formation. Leakage was monitored in soil–gas using a matrix of 40 capillary adsorbent tubes (CATs) left in the soil for periods ranging from days to months. The tracers, perfluoro-1,2-dimethylcyclohexane (PDCH), perfluorotrimethylcyclohexane (PTCH) and perfluorodimethylcyclobutane (PDCB), were analyzed using thermal desorption, and gas chromatography with electron capture detection. Monitoring was designed to look for immediate leakage, such as at the injection well bore and at nearby wells, and to develop the technology to estimate overall CO₂ leak rates based on the use of PFTs. Tracers were detected in soil–gas at the monitoring sites 50 m from the injection well within days of injection. Tracers continued to escape over the following years. Leakage appears to have emanated from the vicinity of the injection well in a radial pattern to about 100 m and in directional patterns to 300 m. Leakage rates were estimated for the 3 tracers from each of the 4 sets of CATs in place following the start of CO₂ injection. Leakage was fairly uniform during this period. As a first approximation, the CO₂ leak rate was estimated at about 0.0085% of the total CO₂ sequestered per annum.