Stable (C,O) and radiogenic (Sr,Nd) isotopes of carbonates as indicators of magmatic and post-magmatic processes of phoscorite-series rocks and carbonatites from Catalão I,central Brazil

The Late-Cretaceous Catalão I contains stockworks of thin dykes of phoscorite-series rocks, which can be subdivided into P1 (olivine-bearing, phoscorites) and P2/P3 (olivine-lacking, nelsonites). Dolomite carbonatites (DC) are intimately associated with nelsonites, as pockets and dykes. The P2 apatite nelsonite, the P3 magnetite nelsonite, and, to a lesser extent DC, host the Catalão I niobium mineralization. C–O isotopes signatures in carbonates reveal several distinct magmatic and post-magmatic processes. Limpid carbonates with stable isotopic mantle-like composition show Rayleigh fractionation and are interpreted as primary, while those with brittle-turbid aspect, and higher oxygen isotope composition, probably underwent recrystallization by interaction with H₂O-rich fluids. A group of samples shows higher oxygen compositions and lower carbon values, which could be explained by degassing of carbonatite magma during cooling. A degassing pattern, parallel to magmatic degassing but at higher oxygen and lower carbon compositions, observed in carbonate veins, may indicate degassing of fracture filling fluids. Furthermore, C–O isotopes of carbonate from monazite-bearing carbonatite have a positive correlation, indicating a distinct, late-stage carbo-hydrothermal event. Though the Catalão I nelsonites and phoscorites are of igneous origin, they underwent several post-magmatic events, which sometimes overprinted partially or entirely the magmatic isotope signature.     

Interindividual variability and ontogenetic effects on Mg and Sr incorporation in the planktonic foraminifer Globigerinoides sacculifer

In order to investigate the interindividual and ontogenetic effects on Mg and Sr incorporation, magnesium/calcium (Mg/Ca) and strontium/calcium (Sr/Ca) ratios of cultured planktonic foraminifera have been determined. Specimens of Globigerinoides sacculifer were grown under controlled physical and chemical seawater conditions in the laboratory. By using this approach, we minimised the effect of potential environmental variability on Mg/Ca and Sr/Ca ratios. Whereas temperature is the overriding control of Mg/Ca ratios, the interindividual variability observed in the Mg/Ca values contributes 2-3 °C to the apparent temperature variance. Interindividual variability in Sr/Ca ratios is much smaller than that observed in Mg/Ca values. The variability due to ontogeny corresponds to −0.43 mmol/mol of Mg/Ca ratio per chamber added. This translates into an apparent decrease of ∼1 °C in Mg/Ca-based temperature per ontogenetic (chamber) stage. No significant ontogenetic effect is observed on Sr incorporation. We conclude that the presence of a significant ontogenetic effect on Mg incorporation can potentially offset Mg/Ca-based temperature reconstructions. We propose two new empirical Mg/Ca-temperature equation based on Mg/Ca measurements of the last four ontogenetic (chamber) stages and whole foraminiferal test: Mg/Ca = (0.55(±0.03) − 0.0002(±4 × 10⁻⁵) MSD) e^0.089T and, Mg/Ca = (0.55(±0.03) − 0.0001(±2 × 10⁻⁵) MSD) e^0.089T, respectively, where MSD corresponds to the maximum shell diameter of the individual.     

Evolution in the provenance of a tectonically controlled Plio–Pleistocene alluvial system between the Variscan Iberian Massif and the Atlantic margin, Portugal

Geochemical and mineralogical data from a Pliocene to Pleistocene alluvial sequence are integrated to access the factors that control rare earth elements (REE) geochemistry and the evolution and spatial differences in provenance. The studied alluvial system is situated in a tectonic active setting at the contact between the Variscan Massif, with several Paleozoic and Precambrian units that support a coastal range, and the Atlantic margin. REE and HREE abundances are generally higher in swamp-lake than in floodplain sediments. The majority of the REE in floodplain sediments is hosted by Y and Th-bearing minerals and illite; in swamp-lake sediments is also probable an association with organic matter. The high Gd/Yb, Eu/Eu* and kaolinite content in older sediments suggest that during the earlier phases provenance was mainly from the hinterland (weathered granitic rocks and its sediment cover). The subsequent illite (Mg-rich) clay assemblages and REE patterns indicate mainly lateral input from the eastern basin edge (Palaeozoic and Precambrian metapelitic rocks). These sediments tend to have lower Gd/Yb and La/Sm than their source rocks. The analysis of the chemical index of alteration (CIA) indicates that although a north-directed fluvial axis existed at that time the “mature” basin edge units found to the south (Silurian) had a limited role in supplying sediments. This shift in provenance is attributed to the uplift of the coastal range. Afterwards, the contribution of recycled Cretaceous and Cenozoic sedimentary units increased progressively. This is demonstrated by the increase is SiO₂/TiO₂, CIA and kaolinite/illite when the climatic conditions are expected to have become less chemically aggressive.     

Inferring the Location of Twitter Messages Based on User Relationships

User interaction in social networks, such as Twitter and Facebook, is increasingly becoming a source of useful information on daily events. The online monitoring of short messages posted in such networks often provides insight on the repercussions of events of several different natures, such as (in the recent past) the earthquake and tsunami in Japan, the royal wedding in Britain and the death of Osama bin Laden. Studying the origins and the propagation of messages regarding such topics helps social scientists in their quest for improving the current understanding of human relationships and interactions. However, the actual location associated to a tweet or to a Facebook message can be rather uncertain. Some tweets are posted with an automatically determined location (from an IP address), or with a user‐informed location, both in text form, usually the name of a city. We observe that most Twitter users opt not to publish their location, and many do so in a cryptic way, mentioning non‐existing places or providing less specific place names (such as “Brazil”). In this article, we focus on the problem of enriching the location of tweets using alternative data, particularly the social relationships between Twitter users. Our strategy involves recursively expanding the network of locatable users using following‐follower relationships. Verification is achieved using cross‐validation techniques, in which the location of a fraction of the users with known locations is used to determine the location of the others, thus allowing us to compare the actual location to the inferred one and verify the quality of the estimation. With an estimate of the precision of the method, it can then be applied to locationless tweets. Our intention is to infer the location of as many users as possible, in order to increase the number of tweets that can be used in spatial analyses of social phenomena. The article demonstrates the feasibility of our approach using a dataset comprising tweets that mention keywords related to dengue fever, increasing by 45% the number of locatable tweets.     

Spurious shifts in the pattern of diurnal variation of sea level pressure of reanalysis datasets

The main purpose of this work is to report the presence of spurious discontinuities in the pattern of diurnal variation of sea level pressure of the three reanalysis datasets from: the National Centers for Environmental Prediction (NCEP) and National Center for Atmospheric Science (R1), the NCEP and Department of Energy (R2), and the European Centre for Medium Range Weather Forecasting (ERA-40). Such discontinuities can be connected to the major changes in the global observing system that have occurred throughout reanalyses years. In the R1, the richest period in discontinuities is 1956–1958, coinciding with the start of modern radiosonde observation network. Rapid increase in the density of surface-based observations from 1967 also had an important impact on both R1 and ERA-40, with larger impact on R1. The reanalyses show discontinuities in the 1970s related to the assimilation of radiances measured by the Vertical Temperature Profile Radiometer and TIROS-N Operational Vertical Sounders onboard satellites. In the ERA-40, which additionally assimilated Special Sensor Microwave/Imager data, there are discontinuities in 1987–1989. The R1 also presents further discontinuities, in 1988–1993 likely connected to replacement/introduction of NOAA-series satellites with different biases, and to the volcanic eruption of Mount Pinatubo in June 1991, which is known to have severely affected measurements of infrared radiances for several years. The discontinuities in 1996–1998 might be partially connected to change in the type of radiosonde, from VIZ-B to VIZ-B2. The R2, which covers only satellite era (1979-on), shows discontinuities mainly in 1992, 1996–1997, and 2001. The discontinuities in 1992 and 2001 might have been caused by change in the satellite measurements and those in 1996–1997 by some changes in land-based observations network.     

Simulation of rainfall anomalies leading to the 2005 drought in Amazonia using the CLARIS LPB regional climate models

The meteorological characteristics of the drought of 2005 in Amazonia, one of the most severe in the last 100 years were assessed using a suite of seven regional models obtained from the CLARIS LPB project. The models were forced with the ERA-Interim reanalyses as boundary conditions. We used a combination of rainfall and temperature observations and the low-level circulation and evaporation fields from the reanalyses to determine the climatic and meteorological characteristics of this particular drought. The models reproduce in some degree the observed annual cycle of precipitation and the geographical distribution of negative rainfall anomalies during the summer months of 2005. With respect to the evolution of rainfall during 2004–2006, some of the models were able to simulate the negative rainfall departures during early summer of 2005 (December 2004 to February 2005). The interannual variability of rainfall anomalies for both austral summer and fall over northern and southern Amazonia show a large spread among models, with some of them capable of reproducing the 2005 observed negative rainfall departures (four out of seven models in southern Amazonia during DJF). In comparison, all models simulated the observed southern Amazonia negative rainfall and positive air temperature anomalies during the El Nino-related drought in 1998. The spatial structure of the simulated rainfall and temperature anomalies in DJF and MAM 2005 shows biases that are different among models. While some models simulated the observed negative rainfall anomalies over parts of western and southern Amazonia during DJF, others simulated positive rainfall departures over central Amazonia. The simulated circulation patterns indicate a weaker northeasterly flow from the tropical North Atlantic into Amazonia, and reduced flows from southern Amazonia into the La Plata basin in DJF, which is consistent with observations. In general, we can say that in some degree the regional models are able to capture the response to the forcing from the tropical Atlantic during the drought of 2005 in Amazonia. Moreover, extreme climatic conditions in response to anomalous low-level circulation features are also well captured, since the boundary conditions come from reanalysis and the models are largely constrained by the information provided at the boundaries. The analysis of the 2005 drought suggests that when the forcing leading to extreme anomalous conditions is associated with both local and non-local mechanisms (soil moisture feedbacks and remote SST anomalies, respectively) the models are not fully capable of representing these feedbacks and hence, the associated anomalies. The reason may be a deficient reproduction of the land–atmosphere interactions.     

Climate change impact on precipitation for the Amazon and La Plata basins

We analyze the local and remote impacts of climate change on the hydroclimate of the Amazon and La Plata basins of South America (SA) in an ensemble of four 21st century projections (1970–2100, RCP8.5 scenario) with the regional climate model RegCM4 driven by the HadGEM, GFDL and MPI global climate models (GCMs) over the SA CORDEX domain. Two RegCM4 configurations are used, one employing the CLM land surface and the Emanuel convective schemes, and one using the BATS land surface and Grell (over land) convection schemes. First, we find considerable sensitivity of the precipitation change signal to both the driving GCM and the RegCM4 physics schemes (with the latter even greater than the first), highlighting the pronounced uncertainty of regional projections over the region. However, some improvements in the simulation of the annual cycle of precipitation over the Amazon and La Plata basins is found when using RegCM4, and some consistent change signals across the experiments are found. One is a tendency towards an extension of the dry season over central SA deriving from a late onset and an early retreat of the SA monsoon. The second is a dipolar response consisting of reduced precipitation over the broad Amazon and Central Brazil region and increased precipitation over the La Plata basin and central Argentina. An analysis of the relative influence on the change signal of local soil-moisture feedbacks and remote effects of Sea Surface Temperature (SST) over the Niño 3.4 region indicates that the former is prevalent over the Amazon basin while the latter dominates over the La Plata Basin. Also, the soil moisture feedback has a larger role in RegCM4 than in the GCMs.     

Environmental issues in urban groundwater systems: a multidisciplinary study of the Paranhos and Salgueiros spring waters,Porto (NW Portugal)

This study presents the results of a multidisciplinary approach, using hydrogeochemical, isotopic and ecotoxicological analyses, performed to assess the nature and suitability for use of Paranhos and Salgueiros spring waters (Porto city, NW Portugal). Based on the surface activities located along the course of the springs, 23 water samples were collected. All the samples were analysed for major element concentrations. The isotopic techniques employed included δ²H, δ¹⁸O and ³H. Standard acute bioassays with Daphnia magna were also performed. The hydrogeochemical analyses showed a nitrate and sulphate-enriched composition for these groundwaters, resulting mainly from urban drainage and sewer leakage. In the ecotoxicological analyses, no significant mortality was observed in any of the tests performed. The results obtained in this study suggest that Porto urban groundwater could be suitable for irrigation uses.     

Climatic simulations of the eastern Andes low-level jet and its dependency on convective parameterizations

The South American low level jet (SALLJ) of the Eastern Andes is investigated with Regional Climate Model version 3 (RegCM3) simulations during the 2002–2003 austral summer using two convective parameterizations (Grell and Emanuel). The simulated SALLJ is compared with the special observations of SALLJEX (SALLJ Experiment). Both the Grell and Emanuel schemes adequately simulate the low level flow over South America. However, there are some intensity differences. Due to the larger (smaller) convective activity, the Emanuel (Grell) scheme simulates more intense (weaker) low level wind than analysis in the tropics and subtropics. The objectives criteria of Sugahara (SJ) and Bonner (BJ) were used for LLJ identification. When applied to the observations, both criteria suggest a larger frequency of the SALLJ in Santa Cruz, followed by Mariscal, Trinidad and Asunción. In Mariscal and Asunción, the diurnal cycle indicates that SJ occurs mainly at 12 UTCs (morning), while the BJ criterion presents the SALLJ as more homogenously distributed. The concentration into two of the four-times-a-day observations does not allow conclusions about the diurnal cycle in Santa Cruz and Trinidad. The simulated wind profiles result in a lower than observed frequency of SALLJ using both the SJ and BJ criteria, with fewer events obtained with the BJ. Due to the stronger simulated winds, the Emanuel scheme produces an equal or greater relative frequency of SALLJ than the Grell scheme. However, the Grell scheme using the SJ criterion simulates the SALLJ diurnal cycle closer to the observed one. Although some discrepancies between observed and simulated mean vertical profiles of the horizontal wind are noted, there is large agreement between the composites of the vertical structure of the SALLJ, especially when the SJ criterion is used with the Grell scheme. On an intraseasonal scale, a larger southward displacement of SALLJ in February and December when compared with January has been noted. The Grell and Emanuel schemes simulated this observed oscillation in the low-level flow. However, the spatial pattern and intensity of rainfall and circulation anomalies simulated by the Grell scheme are closer to the analyses than those obtained with the Emanuel scheme.