Talc mineralisation associated with soft hematite ore, Gongo Soco deposit, Minas Gerais, Brazil: petrography, mineral chemistry and boron-isotope composition of tourmaline

Talc mineralisation occurs as hematite–talc schist between soft hematite ore and dolomitic itabirite at Gongo Soco, Quadrilátero Ferrífero of Minas Gerais, Brazil. The hematite–talc schist and soft hematite have a prominent tectonic foliation of tabular hematite. Tabular hematite without preferential orientation is superimposed on the tectonic foliation. The talcose schist is enriched in F and has a constant Fe/S ratio. Electron-microprobe analyses indicate trace amounts of S in different generations of hematite. The whole-rock Fe/S ratio possibly represents sulfate S from hematite-hosted fluid inclusions. Fluid inclusions in foliation-overprinting hematite and chlorite geothermometry from talcose rocks suggest, respectively, temperatures from <200°C to ~300°C. Tourmaline, a rarely observed mineral in the hematite–talc schist, belongs to the alkali group and falls in the dravite compositional field. Boron-isotope determinations of tourmaline crystals, using secondary ion mass spectrometry, vary from −20‰ to −12‰ δ¹¹B. This compositional isotopic range and the tourmaline chemical composition suggest a meta-evaporitic origin. A non-marine evaporitic setting is the most likely source of acidic, highly oxidising fluids, which resulted in the abundant F-bearing talc and the presence of otherwise immobile Ti in hematite. Oxidising brines were channelled along shear zones and converted dolomitic itabirite into the Gongo Soco soft hematite and the talc mineralisation. The latter is envisaged as the hydrothermal wall-rock alteration of dolomitic itabirite, which gave rise to the soft hematite ore.     

Benthic nitrate biogeochemistry affected by tidal modulation of Submarine Groundwater Discharge (SGD) through a sandy beach face, Ria Formosa, Southwestern Iberia

To investigate both the role of tides on the timing and magnitude of Submarine Groundwater Discharge (SGD), and the effect on benthic nitrogen biogeochemistry of nitrate-enriched brackish water percolating upwards at the seepage face, we conducted a study of SGD rates measured simultaneously with seepage meters and mini-piezometers, combined with sets (n = 39) of high resolution in-situ porewater profiles describing NH₄⁺, NO₃⁻, Si(OH)₄ and salinity distribution with depth (0–20 cm). Sampling took place during two consecutive spring tidal cycles in four different months (November 2005, March, April and August 2006) at a backbarrier beach face in the Ria Formosa lagoon, southern Portugal. Our results show that the tide is one of the major agents controlling the timing and magnitude of SGD into the Ria Formosa. Intermittent pumping of brackish, nitrate-bearing water at the beach face through surface sediments changed both the magnitudes and depth distributions of porewater NH₄⁺ and NO₃⁻ concentrations. The most significant changes in nitrate and ammonium concentrations were observed in near-surface sediment horizons coinciding with increased fraction of N in benthic organic matter, as shown by the organic C:N ratio. On the basis of mass balance calculations executed on available benthic profiles, providing ratios of net Ammonium Production Rate (APR) to Nitrate Reduction Rate (NRR), coupled to stoichiometric calculations based on the composition of organic matter, potential pathways of nitrogen transformation were speculated upon. Although the seepage face occasionally contributes to reduce the groundwater-borne DIN loading of the lagoon, mass balance analysis suggests that a relatively high proportion of the SGD-borne nitrogen flowing into the lagoon may be enhanced by nitrification at the shallow (1–3 cm) subsurface and modulated by dissimilatory nitrate reduction to ammonium (DNRA).     

Evaluation of an ensemble of regional climate model simulations over South America driven by the ERA-Interim reanalysis: model performance and uncertainties

The capability of a set of 7 coordinated regional climate model simulations performed in the framework of the CLARIS-LPB Project in reproducing the mean climate conditions over the South American continent has been evaluated. The model simulations were forced by the ERA-Interim reanalysis dataset for the period 1990–2008 on a grid resolution of 50 km, following the CORDEX protocol. The analysis was focused on evaluating the reliability of simulating mean precipitation and surface air temperature, which are the variables most commonly used for impact studies. Both the common features and the differences among individual models have been evaluated and compared against several observational datasets. In this study the ensemble bias and the degree of agreement among individual models have been quantified. The evaluation was focused on the seasonal means, the area-averaged annual cycles and the frequency distributions of monthly means over target sub-regions. Results show that the Regional Climate Model ensemble reproduces adequately well these features, with biases mostly within ±2 °C and ±20 % for temperature and precipitation, respectively. However, the multi-model ensemble depicts larger biases and larger uncertainty (as defined by the standard deviation of the models) over tropical regions compared with subtropical regions. Though some systematic biases were detected particularly over the La Plata Basin region, such as underestimation of rainfall during winter months and overestimation of temperature during summer months, every model shares a similar behavior and, consequently, the uncertainty in simulating current climate conditions is low. Every model is able to capture the variety in the shape of the frequency distribution for both temperature and precipitation along the South American continent. Differences among individual models and observations revealed the nature of individual model biases, showing either a shift in the distribution or an overestimation or underestimation of the range of variability.     

Interactive effects of environmental variability and human impacts on the long-term dynamics of an Amazonian floodplain lake and a South Atlantic coastal lagoon

Human activities are exposing freshwater ecosystems to a wide range of stressors, whose direct and indirect effects can be alleviated or exacerbated through interactive effects with dynamic environmental drivers. This study used long-term data from two Neotropical lacustrine freshwater systems (Batata Lake, an Amazonian floodplain lake and Imboassica lagoon, an Atlantic coastal lagoon) subjected to different kinds of environmental fluctuations (i.e., flood pulse and sandbar opening) and anthropogenic impacts (i.e., siltation and eutrophication). Our objective was to determine whether the effects of human perturbations are contingent on modifications of important biotic and abiotic characteristics through environmental variability. For both ecosystems, environmental variability consistently interacted with anthropogenic perturbations to alter most of the variables analyzed, such as nutrient dynamics, chlorophyll-a concentration, zooplankton and benthic invertebrate species richness, and temporal community stability, which indicates that interactive effects between environmental variability and anthropogenic perturbations may impact a myriad of ecosystem properties. Furthermore, the nature of these interactive effects was highly dependent on the variable considered and on the ecosystem analyzed. For example, at Imboassica lagoon, sandbar openings interacted synergistically with trophic state to increase the phosphorus concentration in the water column. At Batata Lake, flooding generally alleviated the negative effects of siltation on species richness by both diluting inorganic suspended material concentration and by promoting local recruitment from the regional species pool. Such results indicate that our ability to understand and predict the outcome of anthropogenic impacts on inland aquatic systems can be hampered if we consider human stressors as “static” phenomena disconnected from dynamic interactions with major local environmental drivers.     

Two Brazilian archaeological sites investigated by GPR: Serrano and Morro Grande

The application of the ground penetrating radar (GPR) at two archaeological sites, Serrano and Morro Grande, situated in Araruama County, Rio de Janeiro, Brazil, aids the study of a prehistoric indigenous culture, associated with the “Tupinambá” that inhabited the region during prehistoric times.The archaeological remains of the study area are mainly characterized by pottery artifacts for several uses, including funerary urns, which were buried within layers of sand and clay. Several profiles were acquired using a RAMAC system, with a 200 and 400 MHz frequency antennae. At the Serrano site, the profiles were acquired around some partially exposed pottery shards, due to sand exploitation. The resultant profiles provided a response model to guide the interpretation of new profiles acquired at other sites in the area, which present similar characteristics.The results showed the great importance of the dielectric permittivity contrast which exists between the targets and the host media, in order for possibly significant features to be identified in radar data.     

Future change of climate in South America in the late twenty-first century: intercomparison of scenarios from three regional climate models

Regional climate change projections for the last half of the twenty-first century have been produced for South America, as part of the CREAS (Cenarios REgionalizados de Clima Futuro da America do Sul) regional project. Three regional climate models RCMs (Eta CCS, RegCM3 and HadRM3P) were nested within the HadAM3P global model. The simulations cover a 30-year period representing present climate (1961–1990) and projections for the IPCC A2 high emission scenario for 2071–2100. The focus was on the changes in the mean circulation and surface variables, in particular, surface air temperature and precipitation. There is a consistent pattern of changes in circulation, rainfall and temperatures as depicted by the three models. The HadRM3P shows intensification and a more southward position of the subtropical Pacific high, while a pattern of intensification/weakening during summer/winter is projected by the Eta CCS/RegCM3. There is a tendency for a weakening of the subtropical westerly jet from the Eta CCS and HadRM3P, consistent with other studies. There are indications that regions such of Northeast Brazil and central-eastern and southern Amazonia may experience rainfall deficiency in the future, while the Northwest coast of Peru-Ecuador and northern Argentina may experience rainfall excesses in a warmer future, and these changes may vary with the seasons. The three models show warming in the A2 scenario stronger in the tropical region, especially in the 5°N–15°S band, both in summer and especially in winter, reaching up to 6–8°C warmer than in the present. In southern South America, the warming in summer varies between 2 and 4°C and in winter between 3 and 5°C in the same region from the 3 models. These changes are consistent with changes in low level circulation from the models, and they are comparable with changes in rainfall and temperature extremes reported elsewhere. In summary, some aspects of projected future climate change are quite robust across this set of model runs for some regions, as the Northwest coast of Peru-Ecuador, northern Argentina, Eastern Amazonia and Northeast Brazil, whereas for other regions they are less robust as in Pantanal region of West Central and southeastern Brazil.     

The P-y Response of Laterally Loaded Flexible Piles in Residual Soil

This paper describes the main features related to lateral displacements with depth after successive lateral loading–unloading cycles applied to the top of reinforced-concrete flexible bored piles embedded in naturally bonded residual soil. The bored piles under study have a cylindrical shape, with 0.40-m in diameter and 8.0-m in length. Both bored piles types (P1 and P2) include an embedded steel pipe section in their center as longitudinal steel reinforcements: pile type P1 has another 16 steel rods as steel reinforcement to concrete while pile type P2 has no further steel reinforcement. Pile type P1 has three times as much stiffness (EI) and four and a half times the plastic moment (M_y) than pile type P2. A similar load–displacement performance was observed at initial loads as for small displacements of both piles. At this initial loading stage, the response of the reinforced concrete piles is a function of the soil characteristics and of a linear elastic pile deformation. During this stage, piles can even be understood as probes for evaluating soil reactions. For larger horizontal displacements, after the concrete section starts undergoing large deformations, approaching the ultimate bending moment, pile behavior and consequently the load–displacement relation starts to diverge for both piles. For pile P1 the values of relevant lateral displacements are extended to about 2.5-m in depth, while for pile P2 lateral displacements are mostly constrained to about 2.0-m in depth. Measurements of horizontal displacements of pile P1 against depth recorded with a slope indicator show that, after unloading, lateral loads at distinct stages (small and near failure loads), exhibits a much higher elastic phase of the system response. An analytical fitting model of soil reaction is proposed based on the measured displacements from slope indicator. The integration of a continuous model proposed for the soil reaction agrees fairly well with the measured displacements up to moments close to plastic limit. Results of load–displacement show that the stiffer pile (P1) was able to mobilize twice as much lateral load compared to pile P2 for a service limit displacement of about 20 mm. The paper shows results that enable the isolation of the structural variable through real scale pile load tests, thus granting understanding of its importance and enabling its quantitative visualization in examples of piles embedded in residual soil sites.

     

Origins of high pH mineral waters from ultramafic rocks, Central Portugal

This paper reviews the geochemical, isotopic (²H, ¹⁸O, ¹³C, ³H and ¹⁴C) and numerical modelling approaches to evaluate possible geological sources of the high pH (11.5)/Na–Cl/Ca–OH mineral waters from the Cabeço de Vide region (Central-Portugal). Water–rock interaction studies have greatly contributed to a conceptual hydrogeological circulation model of the Cabeço de Vide mineral waters, which was corroborated by numerical modelling approaches. The local shallow groundwaters belong to the Mg–HCO₃ type, and are derived by interaction with the local serpentinized rocks. At depth, these type waters evolve into the high pH/Na–Cl/Ca–OH mineral waters of Cabeço de Vide spas, issuing from the intrusive contact between mafic/ultramafic rocks and an older carbonate sequence. The Cabeço de Vide mineral waters are supersaturated with respect to serpentine indicating that they may cause serpentinization. Magnesium silicate phases (brucite and serpentine) seem to control Mg concentrations in Cabeço de Vide mineral waters. Similar δ²H and δ¹⁸O suggest a common meteoric origin and that the Mg–HCO₃ type waters have evolved towards Cabeço de Vide mineral waters. The reaction path simulations show that the progressive evolution of the Ca–HCO₃ to Mg–HCO₃ waters can be attributed to the interaction of meteoric waters with serpentinites. The sequential dissolution at CO₂ (g) closed system conditions leads to the precipitation of calcite, magnesite, amorphous silica, chrysotile and brucite, indicating that the waters would be responsible for the serpentinization of fresh ultramafic rocks (dunites) present at depth. The apparent age of Cabeço de Vide mineral waters was determined as 2790 ± 40 a BP, on the basis of ¹⁴C and ¹³C values, which is in agreement with the ³H concentrations being below the detection limit.     

North Atlantic Oscillation sensitivity to the El Niño/Southern Oscillation polarity in a large-ensemble simulation

A large ensemble modeling experiment with the Melbourne University General Circulation Model is presented. Thirty 17-year-long independent simulations were performed. All integrations were forced by the same observed sea surface temperatures, obtained from the Atmospheric Model Intercomparison Project II. The simulations were analyzed to assess the sensitivity of the North Atlantic Oscillation (NAO) to the El Niño/Southern Oscillation (ENSO) polarity. The results show signals of the ENSO phases both in the mean strength of the NAO as well as in its internal variability. During the cold ENSO phase, the probability density function of the NAO index presents a small but positive mean value, whereas it is negative during the warm ENSO phase. Also, the NAO variability associated with each ENSO phase shows a different behavior: during the warm phase the probability density function of the NAO index presents a larger variance and suggests a bimodality, whereas no bimodality is suggested in the cold phase.     

Clay minerals from the sedimentary cover from the Northwest Iberian shelf

The Northern Iberian margin is a typical example of a continental margin subjected to seasonal highly energetic regime (waves and tides) and receiving inputs of continental sediments via riverine discharges. The principal goal of this study has been to use clay minerals as indicators of sedimentary dynamics in the open shelf system. The distributions of clay mineral in the top layer of the sedimentary cover are shown to be related to their continental sources, but also reflect the influences of winter storms and longshore currents in determining the pathways of sediment transport.The mineralogical composition of the material issuing from the rivers is very similar to the general mineralogical composition of the fine fractions of the seabed sediments. Those deposits that are directly influenced by riverine discharges have higher contents of kaolinite (>20%), whereas those that are not have higher contents of illite (>80%). The available data indicate no significant quantities of terrigenous particles are being discharged from the Spanish rias. Therefore, we conclude that physical processes are controlling the clay mineral distributions and that, despite contributions from the Minho River, the main source of fine detrital particles to the shelf region is the Douro River discharge. These particles settle on the middle shelf, below the 60 m isobath. During storm events these particles are re-suspended and advected northwards to the Galician shelf or into deeper domains. Thus the distributions of the clays indicate there is a net transport of fine sediments both northwards and off-shelf.