Age of the Vishnyakovskoe deposit of rare-metal pegmatites (East Sayan): U-Pb geochronological study of manganotantalite

The U-Pb age of the manganotantalite from rare-metal pegmatites of the Vishnyakovskoe deposit (East Sayan Belt) has been assessed at 1838 ± 3 Ma. The acquired data indicate the pegmatites of this deposit and associated granites of the Sayan complex belong to the postcollision South Siberian igneous belt (1.88–1.84 Ga), which stretches along the southwestern frame of the Siberian Craton by more than 2500 km, from the Yenisei Ridge to the Aldan Shield. Formation of this igneous belt is related to joining (starting from about 1.9 Ga BP) of the series of continental microplates and island arcs to the Siberian Craton; this led to final stabilization of the craton at about 1.8 Ga BP.     

Europium retention onto clay minerals from 25 to 150 °C: Experimental measurements, spectroscopic features and sorption modelling

The sorption of Eu(III) onto kaolinite and montmorillonite was investigated up to 150 °C. The clays were purified samples, saturated with Na in the case of montmorillonite. Batch experiments were conducted at 25, 40, 80 and 150 °C in 0.5 M NaClO₄ solutions to measure the distribution coefficients (Kd) of Eu as a trace element (<10⁻⁶ mol/L) between the solution and kaolinite. For the Na-montmorillonite, we used Kd results from a previous study [Tertre, E., Berger, G., Castet, S., Loubet, M., Giffaut, E., 2005. Experimental study of adsorption of Ni²⁺, Cs⁺ and Ln³⁺ onto Na-montmorillonite up to 150 °C. Geochim. Cosmochim. Acta69, 4937-4948] obtained under exactly the same conditions. The number and nature of the Eu species sorbed onto both clay minerals were investigated by time resolved laser fluorescence spectroscopy (TRLFS) in specific experiments in the same temperature range. We identified a unique inner-sphere complex linked to the aluminol sites in both clays, assumed to be AlOEu²⁺ at the edge of the particles, and a second exchangeable outer-sphere complex for montmorillonite, probably in an interlayer position. The Kd values were used to adjust the parameters of a surface complexation model (DLM: diffuse layer model) from 25 to 150 °C. The number of Eu complexes and the stoichiometry of reactions were constrained by TRLFS. The acidity constants of the amphoteric aluminol sites were taken from another study [Tertre, E., Castet, S., Berger, G., Loubet, M., Giffaut, E. Acid/base surface chemistry of kaolinite and Na-montmorillonite at 25 and 60 °C: experimental study and modelling. Geochim. Cosmochim. Acta, in press], which integrates the influence of the negative structural charge of clays on the acid/base properties of edge sites as a function of temperature and ionic strength. The results of the modelling show that the observed shift of the sorption edge towards low pH with increasing temperature results solely from the contribution of the AlOEu²⁺ edge complexes. Finally, we successfully tested the performance of our model by confronting the predictions with experimental Kd data. We used our own data obtained at lower ionic strength (previous study) or higher suspension density and higher starting concentration (TRLFS runs, this study), as well as published data from other experimental studies [Bradbury, M.H., Baeyens, B., 2002. Sorption of Eu on Na and Ca-montmorillonite: experimental investigations and modeling with cation exchange and surface complexation. Geochim. Cosmochim. Acta66, 2325-2334; Kowal-Fouchard, A., 2002. Etude des mécanismes de rétention des ions U(IV) et Eu(III) sur les argiles: influence des silicates. Ph.D. Thesis, Université Paris Sud, France, 330p].     

A minimalistic approach for evapotranspiration estimation using the Prophet model

ABSTRACT

This study aimed to evaluate the potential of the recently introduced Prophet model for estimating reference evapotranspiration (ETo). A comparative study was conducted for benchmarking the model results with support vector regression (SVR) and temperature-based empirical models (Thornthwaite and Hargreaves) in southern Japan. The performance of the Prophet, SVR and temperature-based empirical models was evaluated by Nash–Sutcliffe efficiency (NSE) and coefficient of determination (R²). The results indicate that temperature-based Prophet and SVR models have greater accuracy than the empirical models. The Prophet model with sole input of relative humidity, sunshine hours or windspeed showed acceptable accuracy (NSE > 0.80; R² > 0.80), while SVR models with similar inputs showed greater errors. Accuracy improved with increasing number of input parameters, giving excellent performance (NSE > 0.95; R² > 0.95) with all input parameters. Hence, the Prophet model is a new promising approach for modelling ETo with limited input variables.     

Biogenic silica from the BDP93 drill site and adjacent areas of the Selenga Delta, Lake Baikal, Siberia

Biogenic silica contents of sediments on the lower Selenga Delta and Buguldeika saddle in Lake Baikal show distinct fluctuations that reflect changes in diatom productivity, and ultimately, climate. The pattern of the upper 50 m of the section, dating from about 334 ka, is similar to that of the marine oxygen-isotope record, increasingly so as the younger sediments become progressively finer grained and less locally derived with time. The last two interglaciations are marked by biogenic silica abundances similar to those of the Holocene. The equivalent of marine oxygen-isotope stage 3 is distinctly intermediate in character between full glacial and full interglacial biogenic silica values. Following near-zero values during the last glacial maximum, biogenic silica began to increase at about 13 ka. The rise in biogenic silica to Holocene values was interrupted by an abrupt decrease during Younger Dryas time, about 11 to 10 14C ka.     

Zur Struktur der Niederschläge. III

Zusammenfassung Die an acht Stationen von der Polar-bis zur Tropenzone vermessene Struktur des Niederschlags wird hauptsächlich durch die atmosphärische Schichtung und die geographische Lage bestimmt. Dabei treten für die einzelnen Stationen charakteristische Schwankungen auf, die sich z. B. in der Anzahl der Tropfen für die verschiedenen Größengruppen oder in der Breite der Spektren zeigen. Stau- und Labilitätsregen unterscheiden sich deutlich. Für Karlsruhe lassen sich aus den in zeei Jahren gemessenen Daten die Unterschiede von Jahreszeit zu Jahreszeit ableiten. Intensive Regen sind mit Labilität und hoher Temperatur gekoppelt und fehlen deshalb in der Polarzone vollständig. Sie treten außerdem nur bei breiten Spektren auf und sind nur in der Tropenzone an hohe Tropfenzahlen gebunden. Zwischen einem idealen Regen und den tatsächlich vermessenen ergeben sich infolge der immer vorhandenen verschieden großen Tropfen (Spektrum) Unterschiede. Aus der gemessenen Struktur des Regens läßt sich die Radarreflektibilität berechnen. Sie weicht ebenfalls infolge der Spektrenbreite erheblich vom idealen Regen ab und schwankt von Station zu Station. Dabei ist es gleichgültig, ob der mittlere Tropfendurchmesser, die Spektrenbreite, der Wassergehalt oder die Intensität des Regens als Parameter gewählt werden. Ganz allgemein ist die Intensität der vermessenen Regen bis um den Faktor 5 kleiner als die eines entsprechenden idealen Regens. SchließLich gibt der zeitliche Ablauf der einzelnen Regen Beispiele für die Zunahme der Schwankung aller Parameter mit größer werdender Intensität des Regens und für die Schwierigkeit, aus Radarbeobachtungen sicher die Intensität der zu erwartenden Niederschläge vorherzusagen.

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Summary The structure of precipitation, which has been measured at eight stations distributed from the polar to the tropic zone, is mainly determined by the atmospheric stratification and by the geographical situation. Characteristic variations could be found at the different stations, which show up in the number of drops within the various classes of drop sizes or in the range of the spectrum. Rains caused by barrage or by lability are distinctly different. For Karlsruhe one can derive seasonal variations from the data collected in two years. Intense rains are combined with lability and high temperature and, therefore, are absent in the polar zone. Besides this they appear only with broad spectra and are bound to large numbers of drops only in the tropics. Between an ideal rainfall and a really measured one there are always differences on account of the drops of different sizes which always appear (spectrum). From the observed structure of a rain one can derive its radar-reflectivity. Owing to the range of the spectrum it deviates largely from the reflectivity of the ideal rain, too, and differs from station to station. All this does not depend on whether one selects the mean drop diameter, the range of the spectrum, the water contents or the intensity of the rain as parameter. Generally, the intensity of the observed rain is up to five times smaller than the intensity of the corresponding ideal rain. Finally, the temporal progress of the single rains presents examples of the increase of the variation of all parameters with increasing intensity of the rain, and of the difficulty to predict correctly the intensity of the expected precipitation from radar observations.

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Résumé La structure des précipitations de 8 stations échelonnées de la zone polaire aux tropiques est déterminée en majeure partie par la stratification atmosphérique et la position géographique de la station d'observations elle-même. On constate cependant pour chaque station des variations caractéristiques qui se signalent par exemple dans le nombre de gouttes des différents groupes de grosseur ou dans la largeur du spectre. Les pluies de barrage ou d'instabilité sont nettement différentes les unes des autres. Ainsi, pour Karlsruhe, on peut déduire les différences saisonnières des deux seules années d'observations. Les pluies de forte intensité sont liées à de l'instabilité et à de hautes températures. Elles manquent de ce fait totalement dans la zone polaire. Elles ne se rencontrent en outre que pour de larges spectres de gouttes et ne sont liées à de grands nombres de gouttes que dans la zone tropicale. Par suite du fait que les gouttes ont toujours des grandeurs différentes (spectre des gouttes) on constate toujours des différences entre une pluie idéale et celle qui est effectivement mesurée. On peut calculer la réflexion radar en partant de la structure mesurée de la pluie. Elle s'éloigne également de façon sensible de celle d'une pluie idéale par suite de la largeur du spectre des gouttes et varie de station à station. Dans ce cas, il est indifférent que l'on choisisse comme paramètre le diamètre moyen des gouttes, la largeur du spectre, la contenance en eau du nuage ou l'intensité de la pluie. D'une manière toute générale, l'intensité mesurée de la pluie est jusqu'à 5 fois plus faible que celle d'une pluie idéale correspondante. Enfin, l'évolution dans le temps des différentes chutes de pluie donne des exemples de l'augmentation des variations de tous les paramètres avec l'augmentation de l'intensité de la pluie et de la difficulté de prévoir avec précision l'intensité des précipitations au moyen d'observations faites au radar.

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Mit 23 Abbildungen     

Primitive island arc and oceanic lavas from the hunter ridge-hunter fracture zone. Evidence from glass,olivine and spinel compositions

Summary At its southernmost end, the main spreading centre of the North Fiji Basin is propagating into arc crust of the poorly-known Hunter Ridge. We define nine magmatic groups from major element glass chemistry and olivine and spinel compositions in samples dredged from twenty six sites in this area by the R/V Academician A. Nesmeyanov in 1990. These include groups of boninites, island arc tholeiites (IAT), mid-ocean ridge basalts (MORB), enriched mid-ocean ridge basalts (E-MORB), olivine porphyritic andesites and basaltic andesite and Na-rhyolites. Primitive lavas containing highly forsteritic olivine phenocrysts are common in all the groups, except for the rhyolites.We report over 100 glass analyses for dredged rocks from this region, and about 300 olivine-spinel pairs for representatives of all the magmatic groups identified, except the Na-rhyolites.The MORB in this region are probably produced at the propagating spreading centre in the southern part of the North Fiji Basin. Juxtaposition of shallow, hot MORB-source diapirs supplying the MORB in this area, and the sub-arc damp, refractory upper mantle beneath the Hunter Ridge, provides suitable petrogenetic conditions to produce a range of magma types, from island arc tholeiites through to high-Ca boninites. The latter were recovered in eleven dredges.The E-MORB lavas recovered from the extreme southern margin of the North Fiji Basin are shown to be essentially identical to those dredged from adjacent older South Fiji Basin crust. It is hypothesized that the former were either scraped off the South Fiji Basin crust during an episode of oblique subduction that may have generated the Hunter Ridge during the last 5 Myr, or alternatively, that slices of the South Fiji Basin crust were trapped and incorporated into the North Fiji Basin as the subduction zones fronting the Vanuatu arc stepped or propagated southward.

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Primitive Inselbogen- und ozeanische Laven von Hunter Rücken und der Hunter BruchZone: die Bedeutung der Zusammensetzung von Glas, Olivin und Spinell

Zusammenfassung Das spreading centre des Nord-Fidschi-Beckens setzt sich an seinem südlichsten Ende in die Inselbogen-Kruste des noch wenig bekannten Hunter-Rückens fort.Wir definieren 9 magmatische Gruppen auf der Basis der Hauptelement-Zusammensetzung von Gläsern und der Zusammensetzung von Olivin und Spinell in Proben die das Forschungsschiff R/V Akademiker A. Nesmeyanov von 26 Stellen im Jahr 1990 aufgesammelt hat. Zu diesen gehören Gruppen von Boniniten, Inselbogentholeiiten (IAT), Basalten zentralozeanischer Rücken (MORB), angereicherte zentralozeanische Rücken (E-MORB), Olivin-porphyritische Andesite und basaltische Andesite, sowie Na-Rhyolite. Primitive Laven mit Olivinkristallen, die reich an Forsterit-Komponenten sind, kommen in allen diesen Gruppen, mit Ausnahme der Rhyolite, vor.Wir legen über 100 Glas-Analysen von Gesteinen aus diesem Gebiet vor und über 300 Olivin-Spinell-Paare für Vertreter aller der hier identifizierten magmatischen Gruppen, mit Ausnahme der Natriumrhyolite.Die MORB in diesem Gebiet sind wahrscheinlich an dem aktiven Spreading Center im Südteil des Nord-Fidschi-Beckens entstanden. Das nebeneinander Vorkommen von seichten heißen MORB-Quellen Diapiren, die MORB in diesem Gebiet erzeugen, und der Sub-Inselbogen, wasserhaltige, refraktäre obere Mantel unter dem Hunter Rücken führen zu geeigneten petrogenetischen Bedingungen für die Entstehung einer Vielfalt von Magmatypen, von Inselbogentholeiiten bis zu sehr Kalziumreichen Boniniten. Die letzteren wurden in 11 Dredge-Proben gefunden.Die E-MORS Laven, die aus dem extremen Südteil des Nord-Fidschi-Beckens entnommen wurden, sind im wesentlichen mit jenen identisch, die aus der benachbarten älteren Kruste des Süd-Fidschi-Beckens stammen. Es wird vermutet, daß die letzteren entweder aus dem Süd-Fidschi-Becken während einer Episode obliger Subduktion, die in den letzten 5 Millionen Jahren zur Entstehung des Hunter Ridge geführt hat, abgeschert wurden, oder auch daß Teile der Kruste des Süd-Fidschi-Beckens in das Nord-Fidschi-Becken inkorporiert wurden als Subduktionszonen gegenüber dem Vanuato-Bogen sich nach Süden fortbewegten.

     

Experimental silicate mineral/melt partition coefficients for beryllium and the crustal Be cycle from migmatite to pegmatite

Partition coefficients (D_Be^mineral/melt) for beryllium between hydrous granitic melt and alkali feldspars, plagioclase feldspars, quartz, dark mica, and white mica were determined by experiment at 200 MPa H₂O as a function of temperature (650-900°C), activity of Be in melt (trace levels to beryl saturation), bulk composition, and thermal run direction. At trace levels, Be is compatible in plagioclase of An₃₁ (1.84 at 700°C) and muscovite (1.35 at 700°C) but incompatible in biotite (0.39-0.54 from 650-800°C), alkali feldspar (0.38-0.19 from 680-850°C), quartz (0.24 at 800°C), and albite (0.10 at 750°C). The partition coefficients are different at saturation of the melt in beryl: lower in the case of plagioclase of An₃₁ (0.89 at 700°C), muscovite (0.87 at 700°C), biotite (0.18-0.08 from 675-800°C), alkali feldspar (0.18-0.14 from 680-700°C), and quartz (0.17-0.08 from 750-800°C), but higher in the case of albite (0.37 at 750°C).With other data sources, these new partition coefficients were utilized to track, first, the distribution of Be between aluminous quartzofeldspathic source rocks and their anatectic melts, and second, the dispersion or concentration of Be in melt through igneous crystal fractionation of different magma types (e.g., S-type, I-type) up to beryl-saturated granitic pegmatites and, finally, into their hydrothermal aureoles. Among the rock-forming minerals, cordierite, calcic oligoclase, and muscovite (in this order) control the fate of Be because of the compatibility of Be in these phases. In general, beryl-bearing pegmatites can arise only after extended crystal fractionation of large magma batches (to F, fraction of melt remaining, ≤0.05); granitic magmas that originate from cordierite-bearing protoliths or that contain large modal quantities of calcic oligoclase will not achieve beryl saturation at any point in their evolution.     

Stable isotope (O and C) and pollen trends in eastern Lake Erie,evidence for a locally-induced climatic reversal of Younger Dryas age in the Great Lakes basin

A cool period from about 11000 to 10 500 BP (11 to 10.5 ka) is recognized in pollen records from the southern Great Lakes area by the return of Picea and Abies dominance and by the persistence of herbs. The area of cooling appears centred on the Upper Great Lakes. A high-resolution record (ca. 9 mm/y) from a borehole in eastern Lake Erie reveals, in the same time interval, this pollen anomaly, isotope evidence of meltwater presence (a — 3 per mil shift in ¹⁸O and a +1.1 per mil shift in ¹³C), increased sand, and reduced detrital calcite content, all suggesting concurrent cooling of Lake Erie. The onset of cooling is mainly attributed to the effect of enhanced meltwater inflow on the relatively large upstream Main Lake Algonquin during the first eastward discharge of glacial Lake Agassiz. Termination of the cooling coincides with drainage of Lake Algonquin, and is attributed to loss of its cooling effectiveness associated with a substantial reduction in its surface area. It is hypothesized that the cold extra inflow effectively prolonged the seasonal presence of lake ice and the period of spring overturn in Lake Algonquin. The deep mixing would have greatly increased the thermal conductive capacity of this extensive lake, causing suppression of summer surface lakewater temperatures and reduction of onshore growing-degree days. Alternatively, a rapid flow of meltwater, buoyed on sediment-charged (denser) lakewater, may have kept the lake surface cold in summer. Other factors such as wind-shifted pollen deposition and possible effects from the Younger Dryas North Atlantic cooling could have contributed to the Great Lakes climatic reversal, but further studies are needed to resolve their relative significance.Contribution to Climo Locarno — Past and Present Climate Dynamics; Conference September 1990, Swiss Academy of Sciences — National Climate ProgramGeological Survey of Canada Contribution 58 890