A conceptual and numerical model for groundwater management: a case study on a coastal aquifer in southern Tuscany, Italy

Ongoing hydrogeological research aims to develop a correct management model for the Plio-Pleistocene multi-aquifer system of the Albegna River coastal plain (southern Tuscany, Italy); overexploitation of this aquifer for irrigation and tourism has caused seawater intrusion. The conceptual model is based on field and laboratory data collected during the 1995–2003 period. Meteoric infiltration and flows from the adjoining carbonate aquifer recharge the aquifer. Natural outflow occurs through a diffuse flow into the sea and river; artificial outflow occurs through intensive extraction of groundwater from wells. Water exchanges in the aquifer occur naturally (leakage, closing of aquitard) and artificially (multiscreened wells). The aquifer was represented by a three-dimensional finite element model using the FEFLOW numerical code. The model was calibrated for steady-state and transient conditions by matching computed and measured piezometric levels (February 1995–February 1996). The model helped establish that seawater intrusion is essentially due to withdrawals near the coast during the irrigation season and that it occurs above all in the Osa-Albegna sector, as well as along the river that at times feeds the aquifer. The effects of hypothetical aquifer exploitation were assessed in terms of water budget and hydraulic head evolution.     

Triassic stratigraphy,facies and evolution of the Arabian shelf in the northern United Arab Emirates

This study provides a reconstruction of the Late Permian and Triassic depositional history of the Arabian shelf in the northern United Arab Emirates based on facies analysis and foraminiferal biostratigraphy. The presented data show that sedimentation occurred in three major sequences. From the Late Permian to Olenekian carbonates and evaporites were deposited in restricted lagoons and tidal flats. After a hiatus, sedimentation resumed and continued until the Late Ladinian/Carnian, leading to the deposition of a carbonate platform dominated by peritidal dolostones. A period of shelf exposure and erosion, spanning from the Carnian to Norian, was followed by the third major sequence with sedimentation into the Early Jurassic. During this third depositional sequence sedimentation changed from pure carbonate into mixed carbonate–siliciclastic deposits. This transition reflects the global regression of the sea in the Late Triassic (Triasina hantkeni Zone) and the increased erosion of large parts of the Arabian hinterland. A comparison of the evolution of the Arabian shelf in the study area with chronostratigraphic reference schemes for the Arabian Plate reveals remarkable differences in the distribution of Middle and Upper Triassic sequences. These are most likely the result of poor biostratigraphic control on previously studied formations in the region.     

Calibration and validation of rockfall modelling at regional scale: application along a roadway in Mallorca (Spain) and organization of its management

The Tramuntana range, in the northwestern sector of the island of Mallorca (Balearic Islands, Spain), is frequently affected by rockfalls which have caused significant damage, mainly along the road network. In this work, we present the procedure we have applied to calibrate and validate rockfall modelling in this region, using 103 cases of the available detailed rockfall inventory (630 rockfall events collected since the eighteenth century). We have exploited STONE (Guzzetti et al. 2002), a GIS-based rockfall simulation software which computes 2D and 3D rockfall trajectories starting from a DTM and maps of the dynamic rolling friction coefficient and of the normal and tangential energy restitution coefficients. The appropriate identification of these parameters determines the accuracy of the simulation. To calibrate them, we have selected 40 rockfalls along the range which include a wide variety of outcropping lithologies. Coefficients values have been changed in numerous attempts in order to select those where the extent and shape of the simulation matched the field mapping. Best results were summarized with the average statistical values for each parameter and for each geotechnical unit, determining that mode values represent more precisely the data. Initially, for the validation stage, 10 well-known rockfalls exploited in the calibration phase have been selected. Confidence tests have been applied to their modelling results taking into account not only the success but also the mistakes. The best accuracy is obtained when the rockfall has a preferential trajectory and worse results when the rockfall follows two or more trajectories. Additionally, the greater the rockfall runout length, the less precise the simulation is. We have further validated the calibrated parameters along the Ma-road (111 km), the main transportation corridor in the range, using 63 rockfall events that occurred during the past 18 years along the road. Of the rockfalls where source areas were properly identified, 81.5 % are well represented by STONE modelling, as the travel paths and the depositional areas are successfully ascertained. Results of the analysis have been used by the Road Maintenance Service of Mallorca to assess hazard and risk posed by rockfall at regional scale to design the road management plan.     

Cosmo-SkyMed X-band SAR data for classification of ice-free areas and glacier facies on Potter Peninsula,King George Island Antarctica

The climate change phenomena have been influencing terrestrial and glacial ecosystems around the planet. Maritime Antarctica is especially sensitive to these climate variations and over the last 50 years increasing global air temperatures have caused extensive glacial retreat. The objective of this study is to evaluate the potential use of the SAR technology in monitoring the surface dynamics of the Potter Peninsula, King George Island, maritime Antarctica. An image generated by the SAR satellite COSMO-SkyMed, obtained on 2 February 2011, was used to extract the backscattering values of targets on the surface for further processing and classification, using a supervised statistic classifier of maximum likelihood for the determination of the surface classes. The average backscattering of water bodies presented high similarity, which made its separation unattainable. On the other hand, the surface classes’ bare ice and wet snow over the glacier presented distinct average backscattering values, which allowed an efficient and precise classification using only this parameter. The classification process showed satisfactory results for periglacial environments, presenting high fidelity to the field data.     

Uranium(6+) sorption on montmorillonite: Experimental and surface complexation modeling study

Sorption interactions with montmorillonite and other clay minerals in soils, sediments, and rocks are potentially important mechanisms for attenuating the mobility of U(6+) and other radionuclides through the subsurface environment. Batch experiments were conducted (in equilibrium with atmospheric % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% acbiGaiWiG-bfadaWgaaWcbaacbaGaa43qaiaa+9eadaWgaaqaaiaa% +jdaaWqabaaaleqaaaaa!400D!\[P_{CO_2 } \])to determine the effects of varying pH (2 to 9), solid-mass to solution-volume ratio (M/V = 0.028 to 3.2 g/L), and solution concentration (2 × 10^–7 and 2 × 10^–6 M ²³³U) on U(6+) sorption on SAz-1 montmorillonite. The study focused on U(6+) surface complexation on hydroxylated edge sites as the sorption mechanism of interest because it is expected to be the predominant sorption mechanism at pHs typical of natural waters (pH 6 to 9). Thus, the experiments were conducted with a 0.1 M NaNO₃ matrix to suppress ion-exchange between U(6+) in solution and interlayer cations. The results show that U(6+) sorption on montmorillonite is a strong function of pH, reaching a maximum at near-neutral pH (6 to 6.5) and decreasing sharply towards more acidic or more alkaline conditions. A comparison of the pH-dependence of U(6+) sorption with that of U(6+) aqueous speciation indicates a close correspondence between U(6+) sorption and the predominance field of U(6+)-hydroxy complexes. At high pH, sorption is inhibited due to formation of aqueous U(6+)-carbonate complexes. At low pH, the low sorption values indicate that the 0.1 M NaNO₃ matrix was effective in suppressing ion-exchange between the uranyl (UO₂ ²⁺) species and interlayer cations in montmorillonite. At pH and carbonate concentrations typical of natural waters, sorption of U(6+) on montmorillonite can vary by four orders of magnitude and can become negligible at high pH.The experimental results were used to develop a thermodynamic model based on a surface complexation approach to permit predictions of U(6+) sorption at differing physicochemical conditions. A Diffuse-Layer model (DLM) assuming aluminol (>AlOH) and silanol (>SiOH) edge sites and two U(6+) surface complexation reactions per site effectively simulates the complex sorption behavior observed in the U(6+)-H₂O-CO₂-montmorillonite system at an ionic strength of 0.1 M and pH > 3.5. A comparison of model predictions with data from this study and from published literature shows good agreement and suggests that surface complexation models based on parameters derived from a limited set of data could be useful in extrapolating radionuclide sorption over a range of geochemical conditions. Such an approach could be used to support transport modeling by providing a better alternative to the use of constant K _d s in transport calculations.     

Calculated profiles of H I lines of interest for solar plasma electric field measurements

We present calculated Stark-polarized line profiles for a number of H i lines observed in the visible and infrared emission spectrum of solar prominences and other limb activity. For use in measurements of possible electric fields in these structures, we also calculate curves giving the difference in line width between the 1/2 (I ± Q) profiles as a function of electric-field intensity. Our calculations take into account magnetic fields in these structures, and incorporate typical observed values of Doppler broadening. These calculations explicitly consider the H i fine structure neglected in previous work, and thus are more accurate in the range of low to intermediate electric-field intensity likely to be encountered in solar plasmas (E < 10³ V cm^–1). Our results enable us to compare behavior when E and B are parallel, or perpendicular. We draw particular attention to the high electric-field sensitivity of the transitions between high levels such as 12–8 and 15–9 in H i, observed in prominences at wavelengths around 11. Their sensitivity is roughly an order of magnitude larger than that of the high Paschen-series lines used in solar plasma electric field studies so far.     

On the dynamical equation of a spherical radiating shell

The thermomechanical oscillations of a radiating spherical shell are studied. With a reasonable choice of parameters this simple model reproduces the behaviour of X-ray bursters and recurrent novae. Different hypotheses on the radiation pressure are introduced and the problem is studied at the classical and post-newtonian levels.     

Where are the broad lines in Seyfert 2s?

The unified model for Seyfert 2s postulates that these galaxies are in fact normal Seyfert ls whose innermost regions are hidden from a direct view by an opaque torus. Galaxies seen from a line-of-sight within the opening angle of this torus have the central continuum source and the Broad Line Region unobstructed, and are classified as Seyfert 1/QSO. In Seyfert 2s, on the other hand, periscopic views of the hidden nucleus may be obtained through scattering of the nuclear light in the extranuclear regions. If this model is correct, the Blue and Featureless Continuum observed in many Seyfert 2s is simply a mirror image of the obscured nucleus. In this case, the light from the Broad Line Region must also be reflected towards the observer. Seyfert 2s should therefore exhibit broad lines in their spectrum, which, by definition, they do not! In this contribution we examine this issue and the complications it brings to the basic unification picture of Seyfert galaxies. We fail to find a consistent explanation for this question in the framework of the unified model. An alternative modified-unified model for Seyfert 2s is proposed.