P-waveform analysis for local subduction geometry south of Puget Sound,Washington

The local subduction geometry at a site south of Puget Sound in western Washington is investigated using teleseismicP-waveforms recorded on a three-component event triggered seismograph. The data are processed using source equalization deconvolution in order to isolate locally convertedP-to-S arrivals and stacked to improve the signal-to-noise ratio. Stable arrivals in the radial component indicate an oceanic Moho within the subducted slab at a depth of about 53 km beneath the station. Observed amplitude variations with azimuth in the radial data, as well as qualitative aspects of the tangential data, are used to establish a slab dip of 16° to the southeast. Our results are compatible with previous results from a site 60 km to the west, and further confirm a substantial warp in the regional geometry of the subducted Juan de Fuca plate.     

Fractal properties of simulated bed profiles in coarse-grained channels

Bed roughness characteristics in coarse-grained channels are fairly complex. A hierarchy of roughness elements can be observed, ranging from variable particle sizes and shapes and small-scale sedimentary structures, to large-scale bedforms such as riffle-pool sequences. The effects of these scales of roughness on the flow geometry still remain to be thoroughly investigated. The semivariogram has been suggested in the past as a means of quantifying bed roughness effects on streamflow, as well as for distinguishing between scales of roughness. However, field measurements are rather time-consuming. The low number of bed profiles measured in the field precludes the identification of generally applicable relationships between the statistical properties derived from the semivariograms (such as the Hausdorff dimensions and the scale of autocorrelation corresponding to each fractal band) and the bed configuration itself (geometrical and sedimentological properties). Simulation results of gravel-bed profiles are, therefore, presented in order to complement the original investigation of Robert (1988a). The simulation experiments, based on grain characteristics of sizes and shapes and on morphological properties of small-scale bedforms, yield very significant information on boundary roughness at the microscale and give insight into the interpretation of empirical semivariograms (derived from field measurements). Bed-material sorting, variable grain shapes, and height and spacing of cluster bedforms control the fractal dimensions obtained from the semivariograms, as well as the location of the break of slope and the range of the process.     

Ground variation of radon 222 for location of hidden structural features. Example of the south of France (Alpes Maritimes)

We report two examples from the south of the French Alps, showing that radon emanation monitored by alpha-sensitive film may be used to locate certain discrete structural features revealed in data collected by remote sensing from a satellite. The variations observed in our data, over a period of several months, are in accordance with atmospheric changes and might correlate with local seismic activity when the detectors are located directly above structural fractures and the magnitude of the seismic event is greater than 2.     

UPb zircon and rutile chronology of Archean greenstone formation and gold mineralization in the Val d'Or region, Quebec

UPb geochronology provides an absolute time framework for the evolution of the Sigma gold deposit and surrounding rocks at Val d'Or, southern Abitibi subprovince. The Bourlamaque batholith, the largest pluton in the area, gives a 2699.8 ± 1.0 Ma UPb zircon age. This pluton cuts the Val d'Or Formation which hosts the mineralization. A UPb zircon age of 2704.9 ± 1.1 Ma on a felsic volcanic rock, the Colombière “rhyolite”, 13 km east of the mine dates that formation. The gold-bearing quartz vein system at Sigma is hosted by andesites and two generations of porphyry intrusions, all metamorphosed to the greenschist facies. The oldest porphyry (“porphyritic diorite”) shows the same deformation as the volcanic rocks, and has a 2703.7 ± 2.5 Ma UPb zircon age. The porphyritic diorite and volcanic rocks are cut by feldspar-porphyry dykes which post-date regional folding and have a 2694.0 ± 2.2 Ma UPb zircon age.Regional greenschist metamorphism has been dated directly, with a UPb date of 2684 ± 7 Ma on rutile in the Colombière “rhyolite”. The mineralization and hydrothermal alteration in the mine are superimposed on the metamorphic minerals. Hydrothermal rutile, from an alteration halo around the veins in andesite, has a 2599 ± 9 Ma UPb age. Textural evidence clearly indicates that the wall-rock alteration and vein filling are contemporaneous, and hence the vein system and gold mineralization appear to have developed at least 80 m.y. after the formation and metamorphism of host greenstones.     

Carboxylic monoacids in the air of mayombe forest (Congo): Role of the forest as a source or sink

In the tropical rain forests of the Congo during the dry season, from June to September 1987, carboxylic acid partial pressures (P _gas) in the air above the canopy, at ground level, and at the boundary layer, were estimated from water samples such as fog and rainwater. The concentrations of these acids were also measured in the sap of tree leaves. Tree leaves act as a sink or as a source if the acid P _gas is greater of lower than the acid concentrations in molecular form in sap. For each of these soluble gases, there is a value of P _gas where the exchange is nul. This is called the compensation point. Values of the compensation point for some tree leaves were evaluated according to Henry's law. Henry's law coefficients at ppm levels were redetermined for formic (HCOOH), acetic (CH₃COOH), propionic (CH₃CH₂COOH), and isobutyric (CH₃CH(CH₃)COOH) acids.By comparison of P _gas and compensation points, it is concluded that the forest was a potential source for these acids. The soil-or the litter-acts as a significant source of a carboxylic acid of C₃ or C₄ atoms in the aliphatic chain. This carboxylic acid, not yet fully characterized, could play an important role in the rain acidity in forested zones of the equatorial areas.The direct emission of these carboxylic acids by vegetation was the main source in the boundary layer above the forest. The average emissions were 3.1×10⁹, 7.8×10⁹, and 8.4×10⁹ molecules cm^-2 s^-1 for HCOOH, CH₃COOH, and CH₃CH₂COOH, respectively. The savanna is an exogenous source of HCOOH and CH₃CH₂COOH during moderately rainy days for 30% of the time. The ozonolysis of isoprene seems to be a small source of HCOOH.     

High-frequency sequences and their stacking patterns: sequence-stratigraphic evidence of high-frequency eustatic cycles

A hierarchy of interpreted eustatic cyclicity in siliciclastic sedimentary rocks has a pattern of superposed cycles with frequencies in the ranges of 9–10 m.y., 1–2 m.y., 0.1–0.2 m.y., and 0.01–0.02 m.y. (second- through fifth-order cyclicity, respectively). Stratigraphic units displaying this cyclicity include composite sequences, sequences, and parasequences. On the Exxon global cycle chart, fundamental third-order cycles (1–2 m.y. average duration) stack into related groups (second-order cycles: 9–10 m.y. duration). A much larger pattern (about 200 m.y.) is interpreted as tectonically controlled eustasy probably related to sea-floor spreading rates.

One and probably two higher orders of cyclicity (fourth-order: 0.1–0.2 m.y.; and fifth-order: 0.01–0.02 m.y.) are now observed in work with well logs, cores, and outcrops in areas of very rapid deposition. These frequencies are in the range of Milankovitch cycles, and may represent part of the Milankovitch hierarchy which has been widely interpreted for cyclical units in carbonate rocks.

High-frequency (fourth-order) sequences, which form at a 0.1–0.2 m.y. cyclicity, have all the stratal attributes of conventional sequences, including constituent parasequences and systems tracts, and play a dominant role controling reservoir, source, and sealing rock distribution. A consistent hierarchy of stratigraphy is observed. Parasequences (probable fifth-order cyclicity) stack into sets to form systems tracts in fourth-order sequences. Groups (sets) of fourth-order sequences are deposited between major third-order boundaries within third-order composite sequences. Sequences in these sets stack in prograding and backstepping patterns to form third-order lowstand, transgressive, and highstand sequence sets.

Third-order sequence boundaries are marked by greater basinward shifts in facies, by larger more widespread incised valleys, and by more extensive onlap than are fourth-order sequence boundaries. Third-order condensed sections commonly are widespread, faunally rich, and widely correlated biozone and mapping markers. Fourth-order sequence analysis helps to understand reservoir, source, and seal distribution at the play and prospect scale. An example from the Gulf of Mexico is discussed.     

Plio-Quaternary geodynamic evolution of a segment of the Peruvian Andean Cordillera located above the change in the subduction geometry: the Cuzco region

The Cuzco region, which is located above a change in subduction geometry, appears to be characterized by a variable Plio-Quaternary tectono-sedimentary evolution essentially located along the major fault system that separates the High Plateaux from the Eastern Cordillera. After the higher surface formation of the High Plateaux, a set of Neogene basins were filled by Miocene “ fluvio-torrential” series and by Plio-Pleistocene fluvio-lacustrine deposits. The Neogene series have been affected by compressional tectonic forces attributed to the Late Miocene. This compression is followed by roughly E-W trending syn-sedimentary extensional tectonics attributed to the Pliocene; it is related to reactivation of the pre-existing major faults, basin evolution, and volcanic activity concentrated along the faults. In the Early Pleistocene, fluvio-lacustrine deposits are affected by syn- and post-sedimentary compressional tectonism it is characterized by shortening that trends both N-S and E-W and produces folding and faulting of the sedimentary cover. Extensional tectonism trending roughly N-S has been taking place from the Middle Pleistocene to the Present; it is coeval with shoshonitic volcanic activity, and with sedimentation of fluvio-lacustrine terraces, torrential fans and moraines. Quaternary and active normal faults due to this tectonism, are located in a narrow zone more than 100 km-long between the High Plateaux and the Eastern Cordillera, and two 15 km-long fault sectors in the Eastern Cordillera. Characteristic Pleistocene scarps, 400 m or more high, are due to the cumulative normal offset, and there are also little scarps, with heights ranging between 2 and 20 m, which are related to Holocene fault reactivations. Recent fault reactivation on the Cuzco fault system, during the April 5, 1986 earthquake (m_b = 5.3), is due to the N-S trending extension. This state of stress, located at a mean elevation of roughly 3730 m, is generally homogeneous to different scales. The active Cuzco normal faults may be a consequence of adjustment between the compensated Western Cordillera and the undercompensated Eastern Cordillera, this latter being uplifted higher than its isostatic equilibrium due to compression acting on its eastern edge. The variation of the state of stress, during the Plio-Quaternary is in agreement with the variations of the compressional boundary forces. It may be explained by variation of the convergence rate or by the variation of pull-slab forces.     

Structure of the marine atmospheric boundary layer during two cold air outbreaks of varying intensities: GALE 86

Aircraft, surface, upper air and satellite measurements have been used to observe the evolution and growth of the convective Marine Atmospheric Boundary Layer (MABL) offshore of North Carolina in close proximity to the Gulf Stream, during the intense cold air outbreak of 28 January 1986 and the moderate event of 12 February 1986, as part of the Genesis of Atlantic Lows Experiment (GALE). Air mass modification processes, driven primarily by the ocean-atmosphere exchanges of surface turbulent sensible and latent heat fluxes, caused the overlying air mass to warm and moisten as it advected over the warmer waters of the eastern United States continental shelf. Maximum observed near-surface total heat fluxes were 1045 and 811 W·m^–2 over the core of the Gulf Stream, for 28 January and 12 February 1986, respectively. The observed changes in the overlying air mass occurred almost instantaneously as the ambient flow traversed different underlying SST conditions.The turbulent structure showed a buoyancy-dominated MABL below approximately 0.8z/h. However, shear was also observed to be an important production term above 0.8z/h and below 0.1z/h for the 28 January 1986 event. Dissipation of turbulent kinetic energy was the dominant destruction term in the budgets, but vertical transport of energy was a strong contributor below 0.5z/h, above which this term became a source of turbulent energy. Additionally, the normalized standard deviations of the horizontal velocity components showed a near-equal contribution to the turbulence, while the vertical velocity components displayed the characteristic mid-layer maximum profile observed for a convective, well-mixed boundary layer.     

The Batu Hijau porphyry copper-gold deposit, Sumbawa Island, Indonesia

The Batu Hijau porphyry Cu---Au deposit lies in southwest Sumbawa Island, Indonesia. It is a world-class porphyry Cu deposit in an island are setting, and is typical of this deposit type in most features, including igneous association, morphology, hydrothermal alteration and mineralisation style.The region was not previously recognised as a porphyry Cu province; disseminated Cu sulphides were first recognised in float samples in southwest Sumbawa in 1987. Associated stream sediment sampling identified a broad area of anomalous Au and Cu in an area of greater than 5 km² around Batu Hijau, including 169 ppb Au in BLEG samples and 580 ppm Cu in stream silts 1 km from the deposit. Mineralisation in bedrock at surface contains > 0.1 wt % Cu and > 0.1 ppm Au over an area of 0.6 km × 1.2 km, including a zone 300 m × 900 m containing > 0.3 wt % Cu. Areas with elevated Mo (> 30 ppm) form a distinctive annulus around this Cu-rich zone.Batu Hijau mineralisation is hosted in a tonalite intrusive complex, and diorite and metavolcanic wallrocks. There are no post-mineralisation igneous intrusions or breccia pipes within the deposit. The main tonalite intrusion forms a stock in the centre of the deposit, where it generally displays intensely pervasive potassic (biotite with magnetite-quartz) alteration and hosts most of the higher grade mineralisation. Younger tonalite dykes intruding the centre of this stock are generally less altered and mineralised than the older tonalite.The core zone of potassic alteration grades outward into extensive propylitic alteration (chlorite-epidote), with both variably overprinted by widespread fracture controlled intermediate argillic alteration (sericite-chlorite), and minor phyllic (sericite-pyrite) and sodic (albite) alteration. Argillic (sericite-kaolinite) and advanced argillic (kaolinite-alunite-pyrophyllite) assemblages occur near surface.Copper and Au grades within the orebody show a positive correlation with quartz stockwork intensity, although disseminated Cu sulphides are also common. Chalcopyrite and bornite are the principle hypogenal minerals, with minor chalcocite. Oxidation extends to a depth of 5 m to 85 m below surface across the deposit, and is underlain by weak supergene mineralisation. Drill testing of the deposit down to 650 m below surface reveals a single cylindrical to conical orebody of 334 million tonnes grading 0.8 wt % Cu and 0.69 gm per tonne Au; the depth extent of mineralisation is unknown.