Growth mechanisms and geochemistry of carbonate concretions from the Cambrian Wheeler Formation (Utah,USA)

Carbonate concretions provide unique records of ancient biogeochemical processes in marine sediments. Typically, they form in organic‐rich mudstones, where a significant fraction of the bicarbonate required for carbonate precipitation is supplied from the decomposition of organic matter in the sediments. As a result, carbonates that comprise concretions are usually characterized by broad ranges in δ¹³C and include values that are significantly depleted relative to seawater. This article reports results from a physical, petrographic and geochemical analysis of 238 concretions from the Wheeler Formation (Cambrian Series 3), Utah, USA, which are unusual in several respects. Most prominently, they formed in organic‐poor mudstones (total organic carbon = 0·1 to 0·5%) and are characterized by a narrow range of δ¹³C that onlaps the range of contemporaneous seawater values. Subtle centre to edge trends in δ¹³C demonstrate that concretion precipitation was initiated by local chemical gradients set up by microbial activity in the sediments, but was sustained during growth by a large pool of inorganic bicarbonate probably derived from alkaline bottom waters. The large inorganic pool appears to have been important in facilitating rapid precipitation of the concretion matrix, which occurred via both displacive and replacive carbonate precipitation during early diagenesis. Stable isotope data from cogenetic pyrite (δ³⁴S) and silica (δ¹⁸O) phases provide insight into the evolution of biogeochemical processes during concretion growth, and suggest that concretions were formed almost entirely during sulphate reduction, with only minor modification thereafter. Concretions of the Wheeler Formation appear to represent an end‐member system of concretion formation in which rapid growth was promoted by ions supplied from sea‐water. As such, they offer insight into the spectrum of processes that may influence the growth of carbonate concretions in marine sediments.     

Searching for Added Value in Simulating Climate Extremes with a High-Resolution Regional Climate Model over Western Canada

We evaluate the capacity of a regional climate model to represent observed extreme temperature and precipitation events and also examine the impact of increased resolution, in an effort to identify added value in this respect. Two climate simulations of western Canada (WCan) were conducted with the Canadian Regional Climate Model (version 4) at 15 (CRCM15) and 45?km (CRCM45) horizontal resolution driven at the lateral boundaries by data from the European Centre for Medium-range Weather Forecasts (ECMWF) 40-year Reanalysis (ERA-40) for the period 1973–1995. The simulations were evaluated using the spline-interpolated dataset ANUSPLIN, a daily observational gridded surface temperature and precipitation product with a nominal resolution of approximately 10?km. We examine a range of climate extremes, comprising the 10th and 90th percentiles of daily maximum (TX) and minimum (TN) temperatures, the 90th percentile of daily precipitation (PR90), and the 27 core Climate Daily Extremes (CLIMDEX) indices.

Both simulations exhibit cold biases compared with observations over WCan, with the bias exacerbated at higher resolution, suggesting little added value for temperature overall. There are instances, however, of regional improvement in the spatial pattern of temperature extremes at the higher resolution of CRCM15 (e.g., the CLIMDEX index for the annual number of days when TX?>?25°C). The high-resolution simulations also reveal similarly localized features in precipitation (e.g., rain shadows) that are not resolved at the 45?km resolution. With regard to precipitation extremes, although both simulations generally display wet biases, CRCM15 features a reduced bias in PR90 in all seasons except winter. This improvement occurs despite the fact that spatial and interannual variability of PR90 in CRCM15 is significantly overestimated relative to both CRCM45 and ANUSPLIN. We posit that these characteristics are the result of demonstrable differences between corresponding topographical datasets used in the gridded observations and CRCM, the resulting errors propagated to physical variables tied to elevation and the beneficial effect of subsequent spatial averaging. Because topographical input is often discordant between simulations and gridded observations, it is argued that a limited form of spatial averaging may contribute added value beyond that which has already been noted in previous studies with respect to small-scale climate variability.     

The need for national deep decarbonization pathways for effective climate policy

Constraining global average temperatures to 2 °C above pre-industrial levels will probably require global energy system emissions to be halved by 2050 and complete decarbonization by 2100. In the nationally orientated climate policy framework codified under the Paris Agreement, each nation must decide the scale and method of their emissions reduction contribution while remaining consistent with the global carbon budget. This policy process will require engagement amongst a wide range of stakeholders who have very different visions for the physical implementation of deep decarbonization. The Deep Decarbonization Pathways Project (DDPP) has developed a methodology, building on the energy, climate and economics literature, to structure these debates based on the following principles: country-scale analysis to capture specific physical, economic and political circumstances to maximize policy relevance, a long-term perspective to harmonize short-term decisions with the long-term objective and detailed sectoral analysis with transparent representation of emissions drivers through a common accounting framework or ‘dashboard’. These principles are operationalized in the creation of deep decarbonization pathways (DDPs), which involve technically detailed, sector-by-sector maps of each country’s decarbonization transition, backcasting feasible pathways from 2050 end points. This article shows how the sixteen DDPP country teams, covering 74% of global energy system emissions, used this method to collectively restrain emissions to a level consistent with the 2 °C target while maintaining development aspirations and reflecting national circumstances, mainly through efficiency, decarbonization of energy carriers (e.g. electricity, hydrogen, biofuels and synthetic gas) and switching to these carriers. The cross-cutting analysis of country scenarios reveals important enabling conditions for the transformation, pertaining to technology research and development, investment, trade and global and national policies.

Policy relevance

In the nation-focused global climate policy framework codified in the Paris Agreement, the purpose of the DDPP and DDPs is to provide a common method by which global and national governments, business, civil society and researchers in each country can communicate, compare and debate differing concrete visions for deep decarbonization in order to underpin the necessary societal and political consensus to design and implement short-term policy packages that are consistent with long-term global decarbonization.