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971.
Africa’s landscape is dominated by a manifold of second-order epeirogenic structures superimposed on a first-order bimodal topography. Bivariate regression analysis of Africa’s surface topography shows that this is a complexly folded surface with regionally elevated areas in southern and eastern Africa, and a topographically low northern and western Africa. The apparent spatial relationships between these features are analysed using anomaly correlation between surface topography and free-air gravity anomalies. Occurrences of positively correlated features between gravity and topography in Africa are found to be limited to second-order epeirogenic features. Geophysical modelling and geologic evidence indicate that Africa’s bimodal topography is genetically distinct from these second-order features, and linked to sources as deep as the sublithospheric mantle. The age, measured and modelled elevation of the bimodal topography require that topographic uplift of south-central Africa be episodic. We infer from our findings together with relative sea-level changes, that the near-bimodality of Africa’s topography is an ancient feature inherited at least from upper Paleozoic times. Our reconstructed paleotopography suggests that Africa was largely a low-lying continent dominated by its cratons, and that basement distribution disregards the present-day uplift patterns of Africa. 相似文献
972.
Ernst Zinner Sachiko Amari Ann Nguyen Robert M. Walker 《Geochimica et cosmochimica acta》2003,67(24):5083-5095
With a new type of ion microprobe, the NanoSIMS, we determined the oxygen isotopic compositions of small (<1μm) oxide grains in chemical separates from two CM2 carbonaceous meteorites, Murray and Murchison. Among 628 grains from Murray separate CF (mean diameter 0.15 μm) we discovered 15 presolar spinel and 3 presolar corundum grains, among 753 grains from Murray separate CG (mean diameter 0.45 μm) 9 presolar spinel grains, and among 473 grains from Murchison separate KIE (mean diameter 0.5 μm) 2 presolar spinel and 4 presolar corundum grains. The abundance of presolar spinel is highest (2.4%) in the smallest size fraction. The total abundance in the whole meteorite is at least 1 ppm, which makes spinel the third-most abundant presolar grain species after nanodiamonds (if indeed a significant fraction of them are presolar) and silicon carbide. The O-isotopic distribution of the spinel grains is very similar to that of presolar corundum, the only statistically significant difference being that there is a larger fraction of corundum grains with large 17O excesses (17O/16O > 1.5 × 10−3), which indicates parent stars with masses between 1.8 and 4.5 M⊙. 相似文献
973.
974.
Internal isochronous ice sheet layers, recorded by airborne ice-penetrating radar, were measured along an ice flowline across a large (>1 km high) subglacial hill in the foreground of the Transantarctic Mountains. The layers, dated through an existing stratigraphic link with the Vostok ice core, converge with the ice surface as ice flows over the hill without noticeable change to their separation with each other or the ice base. A two-dimensional ice flow model that calculates isochrons and particle flowpaths and accounts for ice flow over the hill under steady-state conditions requires net ablation (via sublimation) over the stoss face for the predicted isochrons to match the measured internal layers. Satellite remote sensing data show no sign of exposed ancient ice at this site, however. Given the lack of exposed glacial ice, surface balance conditions must have changed recently from the net ablation that is predicted at this site for the last 85,000 years to accumulation. 相似文献
975.
Negative connotations of invasive plants worldwide have implicated them as the bearers of unfavorable ecosystem change. We
contrasted 5-yr-old and 20-yr-oldPhragmites populations with pre-invasion areas occupied byTypha spp. andPanicum virgatum in an oligohaline tidal marsh of Chesapeake Bay. Peak live biomass was 3 times greater, while standing dead and litter was
twice as great in the 20-yr-oldPhragmites. It is this abundance of concentrated litter on the marsh surface of maturePhragmites populations that we implicate as encouraging the trapping of organic and mineral matter. The rate of vertical accretion in
20-yr-oldPhragmites populations is 3–4 mm yr−1 above the adjacent populations. By integrating the constant initial concentration and constant rate of supply models on individual210Pb cores, we estimate thatPhragmites populations require a minimum of 7-yr post-colonization to enhance rates of accretion in this system. In ligh of the considerable
loss of marsh habitat from relative sea-level rise, this finding contests the view that invasion creates strictly undesirable
change at the ecosystem level. 相似文献
976.
977.
E.C Todd 《Geochimica et cosmochimica acta》2003,67(5):881-893
The nature of the surface oxidation phase on pyrite, FeS2, reacted in aqueous electrolytes at pH = 2 to 10 and with air under ambient atmospheric conditions was studied using synchrotron-based oxygen K edge, sulfur LIII edge, and iron LII,III edge X-ray absorption spectroscopy. We demonstrate that O K edge X-ray absorption spectra provide a sensitive probe of sulfide surface oxidation that is complementary to X-ray photoelectron spectroscopy. Using total electron yield detection, the top 20 to 50 Å of the pyrite surface is characterized. In air, pyrite oxidizes to form predominantly ferric sulfate. In aqueous air-saturated solutions, the surface oxidation products of pyrite vary with pH, with a marked transition occurring around pH 4. Below pH = 4, a ferric (hydroxy)sulfate is the main oxidation product on the pyrite surface. At higher pH, we find iron(III) oxyhydroxide in addition to ferric (hydroxy)sulfate on the surface. Under the most alkaline conditions, the O K edge spectrum closely resembles that of goethite, FeOOH, and the surface is oxidized to the extent that no FeS2 can be detected in the X-ray absorption spectra. In a 1.667 × 10−3 mol/L Fe3+ solution with ferric iron present as FeCl3 in NaCl, the oxidation of pyrite is autocatalyzed, and formation of the surface iron(III) oxyhydroxide phase is promoted at low pH. 相似文献
978.
E. J. Palin M. T. Dove S. A. T. Redfern C. I. Saniz-Díaz W. T. Lee 《Physics and Chemistry of Minerals》2003,30(5):293-304
As part of a wider study of the nature and origins of cation order–disorder in micas, a variety of computational techniques
have been used to investigate the nature of tetrahedral and octahedral ordering in phengite, K2
[6](Al3Mg)[4](Si7Al)O20(OH)4. Values of the atomic exchange interaction parameters J
n
used to model the energies of order–disorder were calculated. Both tetrahedral Al–Si and octahedral Al–Mg ordering were studied
and hence three types of interaction parameter were necessary: for T–T, O–O and T–O interactions (where T denotes tetrahedral
sites and O denotes octahedral sites). Values for the T–T and O–O interactions were taken from results on other systems, whilst
we calculated new values for the T–O interactions. We have demonstrated that modelling the octahedral and tetrahedral sheets
alone and independently produces different results from modelling a whole T–O–T layer, hence justifying the inclusion of the
T–O interactions. Simulations of a whole T–O–T layer of phengite indicated the presence of short-range order, but no long-range
order was observed.
Received: 8 August 2002 / Accepted: 14 February 2003
Acknowledgements The authors are grateful to EPSRC (EJP) and the Royal Society (CIS) for financial support. Monte Carlo simulations were performed
on the Mineral Physics Group's Beowulf cluster and the University of Cambridge's High Performance Computing Facility. 相似文献
979.
Gregory K. Druschel Robert J. Hamers George W. Luther III Jillian F. Banfield 《Aquatic Geochemistry》2003,9(2):145-164
The oxidation kinetics of trithionate (S3O62-
) and tetrathionate (S4O
6
2-
) with hydroxyl radicals (OH*) have been investigated in systems analogous to acid mine drainage (AMD) environments. The discovery of hydroxyl radical
(OH*) formation on pyrite surfaces (Borda et al., 2003) suggests hydroxyl radicals may affect the oxidation kinetics of intermediate
sulfur species such as tetrathionate. Cyclic voltammetry experiments in acidic solutions indicate that the reaction of S4O
6
2-
with OH* goes through an unknown intermediate, tentatively assigned as S3O
4
n-
. An outer-sphere electron transfer mechanism for the reaction of S4O
6
2-
with OH* to form S3O
4
n-
is proposed based on experimental results. Oxidation rates for trithionate and tetrathionate in the presence of Fenton's
reagent (which forms hydroxyl radicals) are too fast to be directly measured using UV-Vis spectrophotometry, electrochemical,
or stop-flow spectrophotometry methods. Competitive reaction kinetics within the context of the Haber—Weiss mechanism suggests
that the rate constant for the oxidation of trithionate and tetrathionate with OH* is in excess of 108 M-1 sec-1. 相似文献
980.
Beryllium isotope concentrations were determined in monthly rainfall collections at three sites across New Zealand (36 to 45° S), from October 1996 to November 1998. At the northern sites of Leigh (near Auckland) and Gracefield (near Wellington), 7Be and 10Be concentrations are relatively constant at 1.2 to 1.4 × 107 atoms kg−1 rain and 2.1 to 2.6 × 107 atoms kg−1 rain, respectively. These concentrations correspond to annual flux rates of ∼15 and ∼27 × 109 atoms m−2 y−1, respectively. At the southern site of Dunedin, concentrations are similar to those at the northern sites, but flux rates are significantly lower at ∼ 9 and ∼19 × 109 atoms m−2 y−1, respectively, because of lower average rainfall east of the Southern Alps mountain range. These results are broadly similar to those reported by Brown et al. (1989) and Knies et al. (1994) for rain from midlatitude sites in the USA sampled from 1986 to 1994. Mean 7Be/10Be ratios for New Zealand (0.47 to 0.61) are, however, significantly lower than for the USA (0.69 to 0.78), due in part to the addition of 10Be from re-suspended dust. Subtraction of the dust component increases the New Zealand 7Be/10Be ratios to 0.70 (Leigh), 0.65 (Gracefield) and 0.50 (Dunedin). The adjusted results provide evidence for transfer of older stratospheric air to the troposphere in late-spring-summer, an effect which is strongest in the north. The overall reduction of 7Be/10Be from north to south implies an increase in residence time from ∼ 80 to ∼100 d for Be isotopes in the atmosphere above New Zealand. 相似文献