Geochemical studies in the drainage basin of the Rio Vouga,Portugal. IV. Impact of land use on the hydrogeochemistry of natural waters in the Vouzela region

A hydrogeochemical study of the impact of land use on the composition of natural waters in the Vouzela region in northern Portugal was carried out during the summer of 1983. Water samples were collected from spring and major streams in the area and analyzed for major constituents and some trace elements. Analysis of variance and subsequent pairwise contrast tests demonstrated that waters from agricultural areas are significantly enriched in constiluents such as Na, K, Ca, Mg, Sr, Cl, SO₄, and NO₃. High concentrations of these ions in agricultural areas are the result of both the application of fertilizers and enhanced evaporation by the intensive irrigation of agricultural lands. Constitutents such as H₄SiO₄, HCO₃, F, and probably Li, which are typically related to mineral weathering, were not affected by land use. In waters from forested areas the concentration of most constituents was about 20% higher than in waters from uncultivated areas with mainly a grass cover. This reflects the difference in the evapotranspiration of these two vegetation types. The chemistry of the Rio Zela clearly reflects differences in land use in the Rio Zela valley.     

The relations between modulus of elasticity and temperature in the context of the experimental simulation of rock weathering by fire

Fires occur frequently in many biomes and generate high temperatures on the ground surface. There are many field examples of fire causing rock disintegration. The simulation of fire in the laboratory (using a furnace) and the monitoring of changes in rock modulus of elasticity (with a Grindosonic apparatus), reveal that different rocks respond differently to heating. Significant decreases in elasticity occur at temperatures as low as 200°C and granites display particularly marked reductions. Extended periods of heating are not required for significant reductions to occur. It is postulated that the degree of change in elasticity as a result of simulated fire is such that rock outcrops subjected to real fires are likely to be sufficiently modified as to increase their susceptibility to erosion and weathering processes.     

An experiment on reservoir representation schemes to improve hydrologic prediction: coupling the national water model with the HEC-ResSim

ABSTRACT

This study experiments with reservoir representation schemes to improve the ability to model active water management in the National Water Model (NWM). For this purpose, we developed an integrated water management model, NWM-ResSim, by coupling the NWM with HEC-ResSim, and two reservoir representation schemes are tested: simulation of reservoir operations and retrieval of scheduled operations. The experiments focus on a pilot reservoir domain in the Russian River basin – Lake Mendocino, California – and its contributing watershed. The evaluation results suggest that the NWM-ResSim improves the simulation performance of reservoir outflow from this managed reservoir over the NWM default level pool routing scheme. The degree of this improvement depends on the suitability of the operation guidance; the reservoir operations simulation scheme could have acceptable errors for the purposes of water resources management, but not for flood operations. Results of the retrieval scheme of scheduled operations demonstrated better performance for sub-daily flood operations.     

Building comparable global change vulnerability assessments: The vulnerability scoping diagram

Advancing vulnerability science depends in part on identifying common themes from multiple, independent vulnerability assessments. Such insights are difficult to produce when the assessments use dissimilar, often qualitative, measures. The Vulnerability Scoping Diagram is presented to facilitate the comparison of assessments with dissimilar measures. The diagram is illustrated with recent research on drought vulnerabilities, showing that common insights into vulnerability may emerge if independent research teams use a common structure for organizing information about exposure, sensitivity and adaptive capacity—even if the underlying measures differ between assessments. Broadly adopting this technique, which is grounded in the “Eight Steps” methodological protocol [Schröter, D., Polsky, C., Patt, A., 2005. Assessing vulnerabilities to the effects of global change: an eight step approach. Mitigation and Adaptation Strategies for Global Change 10(4), 573–595], will enable a vulnerability meta-analysis, the lessons from which may permit places to identify helpful adaptation or mitigation options without first having to conduct their own vulnerability assessments.     

Multiple phases of North African humidity recorded in lacustrine sediments from the Fazzan Basin, Libyan Sahara

The Fazzan Basin of south-west Libya is at present arid with less than 20 mm of rainfall per annum. However, regionally extensive limestones, lacustrine sands and coquina (fossiliferous carbonate rock) deposits show that the Fazzan Basin previously contained a large palaeolake, indicating that the climate in the past was more humid. Optically stimulated luminescence (OSL) dating techniques have been applied to key lacustrine deposits within the basin in an attempt to provide an internally consistent chronology for this humidity record. Results indicate that palaeolake sediments within the Fazzan Basin record a very long history of palaeohydrological change, ranging from present day arid conditions to humidity capable of sustaining a lake with an approximate area of 76,250 km². The existence of humid periods in mid oxygen isotope stage 5 and the early Holocene is confirmed. An older lacustrine event, tentatively correlated to oxygen isotope stage 11, is also recognized. In addition, evidence is presented for at least two humid phases beyond the age range over which the conventional OSL dating technique is applicable. This study demonstrates that OSL dating of palaeolake sediments within the Fazzan Basin offers the potential to provide a detailed record of North African humidity spanning several glacial–interglacial cycles.     

Petrogenesis of late stage magmatism at Hold with Hope, East Greenland

The Myggbukta caldera complex and a swarm of basic dykes constitute the latest Tertiary magmatism in the Hold with Hope region, East Greenland. The Sr and Nd isotope ratios of these rocks show coherent variations which extend to high ⁸⁷Sr/⁸⁶Sr and low ¹⁴³Nd/¹⁴⁴Nd values and require a contribution from continental lithosphere. Broad correlations with major element differentiation indices suggest that the continental component was incorporated during magmatic differentiation thereby favouring a crustal contamination process. Trace element concentrations are strongly correlated with isotopic compositions but display ranges for many incompatible elements which extend beyond likely crustal contaminant compositions. This is readily modelled by AFC processes in which the dominant cause of trace element enrichment is the concentration effect of fractional crystallisation rather than the composition of the contaminant. The simplest such models still require unrealistically high degrees of fractional crystallisation to explain the ten-fold enrichment of some trace elements. This can be overcome if the primary magmas entering the crust already had highly variable trace element compositions. Such variability is readily achieved if melts from different parts of the melting column escape without thorough homogenization. An AFC model which incorporates variability in parental magma composition is then able to simulate the range of compositions observed at Hold with Hope. This carries the implication that the variations observed are more readily attributed to changes in uncontaminated parental magma than to variations in the composition or amount of contaminant. Received: 5 March 1998 / Accepted: 16 June 1998     

Coarsening kinetics of the exsolution microstructure in alkali feldspar

Actinolite, hornblende and biotite coexisting in greenschist mafic metagreywackes have been analysed with the electron microprobe to obtain information on their chemical relationship during metamorphism. As in some other parts of the world, the two calcic amphiboles coexist in the greenschist facies because of a miscibility gap between them which is observed under conditions of low-pressure regional metamorphism; it is thought that the two amphiboles are in equilibrium, or at least that the actinolite participated in hornblendeforming reactions. Contact metamorphism by granitic intrusives of these metagreywackes has converted them to hornblende hornfelses with the assemblage hornblende, andesine, quartz, biotite±cummingtonite; the hornblendes of the hornfelses are found to have compositions between actinolite and hornblende of the greenschists, and frequently show fine exsolution lamellae of cummingtonite as a result of oversaturation in this component. The distribution of Fe-Mg between hornblende and biotite changes from the greenschist to the hornblende hornfels facies, and the K _D is probably dependent on Al^VI in the hornblende.     

Transmission electron microscope study of the domain structures associated with the b-, c-, d-, e- and f-reflections in plagioclase feldspars

Ten specimens of plagioclase feldspars (An₁₀₀ to An₂₅) have been examined by transmission electron microscopy using dark field and direct lattice imaging. The specimens are classified into two groups: (i) those that have been quenched from the melt (synthetic An₁₀₀, An₉₅, An₆₆ and An₅₀) and (ii) those that have been cooled relatively slowly (An₉₄, An₇₇, An₇₅, An₅₂, An₃₂ and An₂₆). The observed contrast is interpreted in detail using the two-beam dynamical theory of electron diffraction contrast. The fault vectors of the antiphase boundaries (APBs) observed in An₁₀₀ and An₇₇ are determined. Direct resolution of the sublattice and superlattice in specimens of intermediate composition (An₇₅ to An₂₅) indicates that the superlattice is not a regular array of out-of-step faults and is probably due to a simple sinusoidal distortion of the structure. Only three specimens (An₁₀₀, An₇₇ and An₅₀) exhibited a single structural type. All the remaining specimens consisted of intergrowths of two structural types. The structural type present in any particular specimen depends upon its An-content and thermal history. The rate of transformation from any structural type to a lower-temperature structural type appears to decrease with decreasing An-content.     

Pleistocene sediments,soils and landscape evolution at Stebbing,Essex

Pleistocene sediments and soils exposed at Stebbing in central Essex, England are described, analysed and interpreted. The sand and gravel units above Eocene London Clay and Upper Pliocene Red Crag are shown to be a high level member of the Kesgrave Formation, with a surface immediately beneath that of the Westland Green Gravels, which are tentatively assigned to the Pre-Pastonian ‘a’ Stage of the British Quaternary succession. The rubified, argillic soil developed in the surface of these fluvial deposits is a composite of the Valley Farm and Barham Soils and displays micromorphological evidence of several phases of clay illuviation, gleying and clay coating disruption. Originally truncated and buried beneath Anglian gelifluction deposits, cover sand and till, the soil has been exhumed in most places by subsequent erosion. The full succession, however, is preserved within large gulls that formed by periglacial cambering prior to this erosion. More recent loess incorporation and pedogenesis have modified the exhumed soil and the materials within the gulls.