Atrazine in a Stream-Aquifer System: Transport of Atrazine and Its Environmental Impact Near Ashland, Nebraska

Lincoln's municipal wellfield consists of 44 wells located adjacent to the Platte River near Ashland, Nebraska. The herbicide atrazine was monitored in the river and two transects of monitoring, wells. The amount of atrazine transported down the Platte River in 1989, 1990, and 1991 was shown to increase each year. Induced recharge from the Platte River results in movement of atrazine from the river into the aquifer. A 21-day lag time was determined for the movement of atrazine from the river to a transect of monitoring wells 10 feet West of the bank. The role that colloids play on the transport of atrazine was determined to be insignificant. A small percentage of atrazine found in the river was determined to come from rain water. The infiltration of agrichemical-contaminated river water was shown to significantly reduce the quality of raw water and finished water being produced by the adjacent aquifer.     

Seismic time‐lapse effects of solution salt mining – a feasibility study

This article addresses the question whether time‐lapse seismic reflection techniques can be used to follow and quantify the effects of solution salt mining. Specifically, the production of magnesium salts as mined in the north of the Netherlands is considered. The use of seismic time‐lapse techniques to follow such a production has not previously been investigated. For hydrocarbon production and CO₂ storage, time‐lapse seismics are used to look at reservoir changes mainly caused by pressure and saturation changes in large reservoirs, while for solution mining salt is produced from caverns with a limited lateral extent, with much smaller production volumes and a fluid (brine) replacing a solid (magnesium salt). In our approach we start from the present situation of the mine and then study three different production scenarios, representing salt production both in vertical and lateral directions of the mine. The present situation and future scenarios have been transformed into subsurface models that were input to an elastic finite‐difference scheme to create synthetic seismic data. These data have been analysed and processed up to migrated seismic images, such that time‐lapse analyses of intermediate and final results could be done. From the analyses, it is found that both vertical and lateral production is visible well above the detection threshold in difference data, both at pre‐imaging and post‐imaging stages. In quantitative terms, an additional production of the mine of 6 m causes time‐shifts in the order of 2 ms (pre‐imaging) and 4 ms (post‐imaging) and amplitude changes of above 20% in the imaged sections. A laterally oriented production causes even larger amplitude changes at the edge of the cavern due to replacement of solid magnesium salt with brine introducing a large seismic contrast. Overall, our pre‐imaging and post‐imaging time‐lapse analysis indicates that the effects of solution salt mining can be observed and quantified on seismic data. The effects seem large enough to be observable in real seismic data containing noise.     

The science of European marine reserves: Status,efficacy, and future needs

The ecologically and socio-economically important marine ecosystems of Europe are facing severe threats from a variety of human impacts. To mitigate and potentially reverse some of these impacts, the European Union (EU) has mandated the implementation of the Marine Strategy Framework Directive (MSFD) in order to achieve Good Environmental Status (GES) in EU waters by 2020. The primary initiative for achieving GES is the implementation of coherent networks of marine protected areas (MPAs). Marine reserves are an important type of MPA in which no extraction is allowed, but their usefulness depends upon a number of ecological, management, and political factors. This paper provides a synthesis of the ecological effects of existing European marine reserves and the factors (social and ecological) underlying their effectiveness. Results show that existing European marine reserves foster significant positive increases in key biological variables (density, biomass, body size, and species richness) compared with areas receiving less protection, a pattern mirrored by marine reserves around the globe. For marine reserves to achieve their ecological and social goals, however, they must be designed, managed, and enforced properly. In addition, identifying whether protected areas are ecologically connected as a network, as well as where new MPAs should be established according to the MSFD, requires information on the connectivity of populations across large areas. The adoption of the MSFD demonstrates willingness to achieve the long-term protection of Europe's marine ecosystems, but whether the political will (local, regional, and continent wide) is strong enough to see its mandates through remains to be seen. Although the MSFD does not explicitly require marine reserves, an important step towards the protection of Europe's marine ecosystems is the establishment of marine reserves within wider-use MPAs as connected networks across large spatial scales.     

Conducting Slug Tests in Mini‐Piezometers

Slug tests performed using mini‐piezometers with internal diameters as small as 0.43 cm can provide a cost effective tool for hydraulic characterization. We evaluated the hydraulic properties of the apparatus in a laboratory environment and compared those results with field tests of mini‐piezometers installed into locations with varying hydraulic properties. Based on our evaluation, slug tests conducted in mini‐piezometers using the fabrication and installation approach described here are effective within formations where the hydraulic conductivity is less than 1 × 10^?3 cm/s. While these constraints limit the potential application of this method, the benefits to this approach are that the installation, measurement, and analysis is cost effective, and the installation can be completed in areas where other (larger diameter) methods might not be possible. Additionally, this methodology could be applied to existing mini‐piezometers previously installed for other purposes. Such analysis of existing installations could be beneficial in interpreting previously collected data (e.g., water‐quality data or hydraulic head data).     

Interaction of an antecedent fluvial system with early normal fault growth: Implications for syn‐rift stratigraphy,western Corinth rift (Greece)

Continental ‘overfilled’ conditions during rift initiation are conventionally explained as due to low creation of accommodation compared with sediment supply. Alternatively, sediment supply can be relatively high from the onset of rifting due to an antecedent drainage system. The alluvial Lower Group of the western Plio–Pleistocene Corinth rift is used to investigate the interaction of fluvial sedimentation with early rifting. This rift was obliquely superimposed on the Hellenide mountain belt from which it inherited a significant palaeorelief. Detailed sedimentary logging and mapping of the well‐exposed syn‐rift succession document the facies distributions, palaeocurrents and stratigraphic architecture. Magnetostratigraphy and biostratigraphy are used to date and correlate the alluvial succession across and between fault blocks. From 3·2 to 1·8 Ma, a transverse low sinuosity braided river system flowed north/north‐east to east across east–west‐striking active fault blocks (4 to 7 km in width). Deposits evolved downstream from coarse alluvial conglomerates to fine‐grained lacustrine deposits over 15 to 30 km. The length scale of facies belts is much greater than, and thus not directly controlled by, the width of the fault blocks. At its termination, the distributive river system built small, stacked deltas into a shallow lake margin. The presence of a major antecedent drainage system is supported by: (i) a single major sediment entry point; (ii) persistence of a main channel belt axis; (iii) downstream fining at the scale of the rift basin. The zones of maximum subsidence on individual faults are aligned with the persistent fluvial axis, suggesting that sediment supply influenced normal fault growth. Instead of low accommodation rate during the early rift phase, this study proposes that facies progradation can be controlled by continuous and high sediment supply from antecedent rivers.     

Groundwater science in water-utility operations: global reflections on current status and future needs

The relevance of groundwater science to water-utility operations is analysed from a broad international perspective, identifying key concerns and specific opportunities for the future. The strategic importance worldwide of water utilities assuming the role of lead stakeholders for integrated groundwater resource management, recognizing their often considerable technical know-how and highly significant data holdings, is emphasized. Concurrently, the utilities themselves will need an ever-closer appreciation of groundwater-system behaviour if they are to manage efficiently their water-supply and wastewater operations.     

Methylmercury Bioaccumulation in an Urban Estuary: Delaware River,USA

Spatial variation in mercury (Hg) and methylmercury (MeHg) bioaccumulation in urban coastal watersheds reflects complex interactions between Hg sources, land use, and environmental gradients. We examined MeHg concentrations in fauna from the Delaware River estuary, and related these measurements to environmental parameters and human impacts on the waterway. The sampling sites followed a north to south gradient of increasing salinity, decreasing urban influence, and increasing marsh cover. Although mean total Hg in surface sediments (top 4 cm) peaked in the urban estuarine turbidity maximum and generally decreased downstream, surface sediment MeHg concentrations showed no spatial patterns consistent with the examined environmental gradients, indicating urban influence on Hg loading to the sediment but not subsequent methylation. Surface water particulate MeHg concentration showed a positive correlation with marsh cover whereas dissolved MeHg concentrations were slightly elevated in the estuarine turbidity maximum region. Spatial patterns of MeHg bioaccumulation in resident fauna varied across taxa. Small fish showed increased MeHg concentrations in the more urban/industrial sites upstream, with concentrations generally decreasing farther downstream. Invertebrates either showed no clear spatial patterns in MeHg concentrations (blue crabs, fiddler crabs) or increasing concentrations further downstream (grass shrimp). Best-supported linear mixed models relating tissue concentration to environmental variables reflected these complex patterns, with species specific model results dominated by random site effects with a combination of particulate MeHg and landscape variables influencing bioaccumulation in some species. The data strengthen accumulating evidence that bioaccumulation in estuaries can be decoupled from sediment MeHg concentration, and that drivers of MeHg production and fate may vary within a small region.     

Polar Compounds from the Dissolution of Weathered Diesel

Hydrocarbon and nonhydrocarbon components dissolving in water from fresh diesel and field samples of highly weathered diesel (spilled up to 50 years ago) from two sites were investigated. The fresh and weathered diesels were equilibrated with water using a slow-stirring method, and the product and equilibrated aqueous water samples analyzed by a range of analytical procedures. The water phase equilibrated with weathered diesels had higher total dissolved organics concentrations (96 and 8.6 mg/L at the two sites) compared to the water phase equilibrated with fresh diesel (average of 3.4 mg/L). Compound class characterization of dissolved organics in water from the weathered diesel showed that polar components were a significant compound class (98% and 42% at the two sites) and appeared largely as an unresolved complex mixture (UCM) in the total ion chromatograms (TICs). Identification of 1-adamantanol in the polar fraction of both weathered diesel samples (3.6 and 0.3 μg/L at the two sites) suggested that at least some of the associated polar components are from a petroleum source. The analysis of total petroleum hydrocarbons (TPH) is aimed at measuring only dissolved carbon and hydrogen-containing compounds, and dissolved polar compounds present as a UCM are often assumed to be from natural organic matter (NOM) and removed. This may result in a gross underestimation of the total soluble organic material in water associated with weathered diesels. In addition, the risk posed by these fuel-derived polar compounds is unknown.     

A two-dimensional probabilistic acute human-health risk assessment of insecticide exposure after adult mosquito management

Ultra-low-volume (ULV) aerosol applications of insecticides are used to manage high densities of adult mosquitoes. We used two-dimensional probabilistic risk assessment methodologies to evaluate three pyrethroid insecticides (phenothrin, resmethrin, and permethrin), pyrethrins, and two organophosphate insecticides (malathion and naled), applied by truck-mounted ULV sprayer. Piperonyl butoxide, a synergist commonly used in pyrethroid and pyrethrins formulations, was also assessed. The objective of our study was to evaluate probabilistically if a deterministic human-health risk assessment of mosquito insecticides was sufficiently conservative to protect human-health. Toddlers and infants were the highest risk groups while adult males were the lowest risk group assessed in this study. Total acute exposure ranged from 0.00003 to 0.0003 mg/kg day⁻¹ for the chemicals and subgroups assessed examining inhalation, dermal, oral, and hand-to-mouth exposure. We used the risk quotient (RQ) method for our risk assessment, which is calculated by dividing the total potential exposure for each subgroup and chemical by its ingestion toxic endpoint value (RfD). Mean RQs ranged from 0.000004 to 0.034 for all subgroups and chemicals, with none exceeding the RQ level of concern. Naled had the highest RQs of any chemical assessed while PBO had the lowest. Sensitivity analysis demonstrated that the exposure from inhalation and deposition contributed the largest variance to the model output. Results support the findings of previous studies that the risks from adult mosquito management are most likely negligible, and that the human-health deterministic risk assessment is most likely sufficiently conservative.     

A study of tides and currents in Cook Strait, New Zealand

Greater Cook Strait (GCS) lies between the North and the South Islands of New Zealand. Its location at the convergence of the Pacific and Indo-Australian tectonic plates leads to interesting bathymetry with an adjacent shallow shelf and deep ocean trench as well as numerous crossing faults and complex shoreline geometry. Our purpose in this study is to examine tides and currents in GCS and, in particular, identify the major forcing mechanisms for the residual currents. Toward this end, we use an unstructured-grid numerical model to reproduce the tides and currents, verify these results with observations and then use the model to separate the various forcing mechanisms. The physical forcing includes nonlinear generation from tides and tidal currents, differences in sea level between the Pacific Ocean and Tasman Sea boundaries, density variations, wind stress and river discharge into GCS. Each of these mechanisms is important in different areas.