A constitutive law for thermo-plastic behaviour of rocks: an analogy with clays

Thermo-mechanical behaviour of rocks shows phenomenological similarities to that of clays. A visible decrease of strength and an increase in ductility at elevated temperatures are observed in drained conditions. In undrained conditions the strength decrease is even more dramatic and the ductile behaviour may turn into the brittle one, if a sufficient amount of water is present in the pores at the start of the process, or it is being released during heating by the decomposition of hydrous minerals. Applying a thermo-plasticity theory, major macroscopical characteristics of behaviour may be modelled. According to this theory, the elastic domain is postulated as temperature dependent, shrinking with temperature; heating may result in expansive or compactive volumetric irreversible strain depending on the confining stress. This theory is applied to the modelling of heat effects on local changes of permeability around a cylindrical nuclear waste container disposed off in deep clays, and in the numerical simulation of a mechanism initiating deep earthquakes.     

A thermo-plastic constitutive law for brittle-plastic behavior of rocks at high temperatures

Mechanical properties of rocks change under the influence of, temperature. Stress at the onset of yielding, ultimate strength, dilatancy, strain hardening and softening, and the confining pressure at brittle-ductile transition are all reduced by the increasing temperature. This study presents a framework of constitutive modeling of thermo-brittle-plastic behavior of rocks which encompasses these changes. The constitutive law is based on a thermo-plasticity theory first proposed for metals byPrager (1958). Two phenomenological mechanisms have been identified as central for the modeling: temperature dependence of the yield locus (thermal softening), and temperature dependence of the strain-hardening function (thermally enhanced ductility). Material parameters for two rocks, Carrara marble and Westerly granite, were determined on the basis of additional hypotheses. These parameters are used in numerical simulations of triaxial tests at different temperatures. The obtained stress-strain curves compare well to the experimental results. The changes with temperature in the stress at the onset of yielding are more accurately reproduced that the evolution of hardening or softening. Suggestions for possible improvements and future research directions are indicated.     

Biochronology and biochron boundaries: A real dilemma or a false problem? An example based on the Pleistocene large mammalian faunas from Italy

Reconstructing the Neogene-Quaternary biostratigraphy in continental environments and recognising ‘boundaries’ between successive mammalian faunal complexes is a problematic task. The definition and application of biochronology has been often tainted by references to and inferences from biostratigraphy. Actually, the discontinuities in the continental sedimentary record, environmental conditions, taphonomic and sampling biases are responsible for the fact that the stratigraphical order of the lowest and highest occurrences of fossil remains (stratigraphic datum) does not necessarily reflect the temporal order of actual first/last appearances of taxa (palaeobiological events) in time. Nonetheless, the first/last appearance bioevents (recorded by lowest/highest occurrences of fossil remains in fossiliferous levels of different continental stratigraphical successions) have been the principal foundation for establishing the biochronological setting of continental mammal faunas. Therefore, from a theoretical point of view, ‘boundaries’ should be defined by the oldest and/or youngest ‘historical occurrence’ of one or more taxa. What about an operational approach?Some examples of the Italian faunas are presented, focusing on the transition from the Villafranchian to the Galerian and from the Galerian to the Aurelian Land-Mammal Ages. The results obtained indicate the difficulty of defining a stable scheme that can be applied for correlation by the international scientific community.     

Reddening of dune sands—evidence from southeast India

Thin section, SEM, and TEM analyses have indicated that the red ‘teri’ sands of southeast India have formed from weathering in situ of coastal dune sands. The data does not support a detrital origin for the red sands. C¹⁴ dates indicate that dune deposition and weathering, to a maximum depth of 10 m, leading to the formation of a hematite, koalinite and illite rich matrix has taken place rapidly over the past 25,000 years. It is postulated that garnet was a major source of hematite (ferric oxide).     

Isotopic ages and tectono-metamorphic history of the metamorphic basement of North-Eastern Sardinia

New Rb/Sr and K/Ar data on minerals and whole-rocks from the metamorphic basement of Northeastern Sardinia are presented. A formation of augen gneiss of volcano-sedimentary origin yields a Rb/Sr whole-rock age of 441±33 m.y.; a Rb/Sr isochron age of 306±10 m.y. is found for the minerals separated from one of these samples. K/Ar measurements on micas also yield ages of 319–284 m.y. A banded migmatite which originated through a process of metamorphic differentiation was analysed by the Rb/Sr method. Six bands, treated as whole-rock samples, fit an isochron of 344±7 m.y. Biotite and plagioclase from one of these bands yield an isochron age of about 300 m.y.The radiometric results reported in this paper and all those previously published are discussed in order to investigate the tectono-metamorphic history of this important segment of the ancient Mediterranean basement. It is argued that in this area there is only indirect evidence of a Caledonian orogenic event (late orogenetic acidic magmatites emplaced 458-441 m.y. ago) while the main features of the metamorphic basement must be related to the Hercynian orogeny the climax of which can be fixed at about 340 m.y. The concordance of the ages of the separated minerals (310-300 m.y.) suggests that the metamorphic succession stayed above the specific critical temperatures for about 40 m.y., after which it was suddenly uplifted contemporaneous with the emplacement of the, essentially post-kinematic, Hercynian granitoids.     

Ephemeral rollover points and clinothem evolution in the modern Po Delta based on repeated bathymetric surveys

Reconstructions of ancient delta systems rely typically on a two-dimensional (2D) view of prograding clinothems but may miss their three-dimensional (3D) stratigraphic complexity which can, instead, be best documented on modern delta systems by integrating high-resolution geophysical data, historical cartography, core data and geomorphological reconstructions offshore. We quantitatively compare three precisely positioned, high-resolution multi-beam bathymetry maps in the delta front and pro delta sectors (0.3 to 10 m water depth) of Po di Pila, the most active of the modern Po Delta five branches. By investigating the detailed morphology of the prograding modern Po Delta, we shed new light on the mechanisms that control the topset to foreset transition in clinothems and show the temporal and spatial complexity of a delta and its pro delta slope, under the impact of oceanographic processes. This study documents the ephemeral nature of the rollover point at the transition between sandy topset (fluvial, delta plain to mouth-bar) and muddy seaward-dipping foreset deposits advancing, in this case, in >20 m of water depth. Three multibeam surveys, acquired between 2013 and 2016, document the complexity in space and time of the topset and foreset regions and their related morphology, a diagnostic feature that could not be appreciated using solely 2D, even very high-resolution, seismic profiles. In addition, the comparison of bathymetric surveys gathered with one-year lapses shows the migration of subaqueous sand dunes on the clinothem topset, the formation of ephemeral cut-and-fill features at the rollover point (few m below mean sea level), the presence of collapse depressions derived by sagging of sediments and fluid expulsion (possibly induced by storm waves) on the foreset, and splays of sand likely reflecting gravity flows on the lower foreset. Though the modern Po Delta is anthropogenic in many respects, its subaqueous clinothem can be studied as a scale model for ancient clinothems that are less resolved geometrically and far less constrained chronologically.     

Copepod grazing during spring blooms: Does Calanus pacificus avoid harmful diatoms?

During late winter and spring of 2002 and 2003, 24, 2–3 day cruises were conducted to Dabob Bay, Washington State, USA, to examine the grazing, egg production, and hatching success rates of adult female Calanus pacificus and Pseudocalanus newmani. The results of the copepod grazing experiments for C. pacificus are discussed here. Each week, copepod grazing incubation experiments from two different depth layers were conducted. Grazing was measured by both changes in chlorophyll concentration and cell counts. In 2002, there was one moderate bloom consisting mainly of Thalassiosira spp. in early February, and a larger bloom in April comprised of two Chaetoceros species and Phaeocystis sp. Similarly, in 2003, there were two blooms, an early one dominated by Thalassiosira spp., and a later one consisting of Chaetoceros spp. and Thalassiosira spp. Clearance rates on individual prey species, as calculated by cell counts, showed that C. pacificus are highly selective in their feeding, and may have much higher clearance rates on individual taxa than rates calculated from bulk chlorophyll disappearance. During weeks of high phytoplankton concentration, the copepods generally ate phytoplankton. However, they often rejected the most abundant phytoplankton species, particularly certain Thalassiosira spp., even though the rejected prey were often of the same genus and similar size to the preferred prey. It is speculated that this avoidance may be related to the possible deleterious effects that certain of these diatom species have on the reproductive success of these copepods. During weeks of medium to low phytoplankton concentration, the copepods selectively ate certain species of phytoplankton, and often had high electivity for microzooplankton. The selection mechanism must consist of active particle rejection most likely based on detection of surface chemical properties, since the diatoms that were selected were of the same genus, nearly the same size, and at lower numerical abundance than those cells that were avoided. The grazing choices made by these copepods may have important consequences for the overall ecosystem function within coastal and estuarine systems through changes in the transfer efficiency of energy to higher trophic levels.     

Copepod grazing during spring blooms: Can Pseudocalanus newmani induce trophic cascades?

During late winter and spring of 2002 and 2003, 24 two- to three-day cruises were conducted to Dabob Bay, Washington State, USA, to examine the grazing, egg production, and hatching success rates of adult female Calanus pacificus and Pseudocalanus newmani. Here, we discuss the results of our grazing experiments for P. newmani. Each week, we conducted traditional microzooplankton dilution experiments and “copepod dilution” experiments, each from two different layers. Grazing was measured by changes in chlorophyll concentration and direct cell counts. Clearance rates on individual prey species, as calculated by cell counts, showed that Pseudocalanus are highly selective in their feeding, and may have much higher grazing rates on individual taxa than calculated from bulk chlorophyll disappearance. The grazing rates of the copepods, however, are typically an order of magnitude lower than the grazing rates of the microzooplankton community, or the growth rates of the phytoplankton. P. newmani ingested diatoms, but, at certain times fed preferentially on microzooplankton, such as ciliates, tintinnids, and larger dinoflagellates. Removal of the microzooplankton may have released the other phytoplankton species from grazing pressure, allowing those species’ abundance to increase, which was measured as an apparent “negative” grazing on those phytoplankton species. The net result of grazing on some phytoplankton species, while simultaneously releasing others from grazing pressure resulted in bulk chlorophyll-derived estimates of grazing which were essentially zero or slightly negative; thus bulk chlorophyll disappearance is a poor indicator of copepod grazing. Whether copepods can significantly release phytoplankton from the grazing pressure by microzooplankton in situ, thus causing a trophic cascade, remains to be verified, but is suggested by our study.