Distribution of nitrate over sea-salt and soil derived particles — Implications from a field study

A method for determining the distribution of supermicrometer nitrate between size-segregated sea-salt and soil derived particles is presented. The analysis is based on field data from six measurements at a coastal site in southern Finland, and on a theoretical treatment taking into account the transfer of gaseous species onto particle surfaces and their subsequent reaction. Significant amounts of nitrate were found in both the particle types, with the fraction of nitrate associated with soil particles varying from 20–50% in the 1–2 m size to near 90% in particles larger than 10 m. Overall, the nitrate accumulation followed closely the relative abundances of these two particle types. Two overlapping modes in supermicron nitrate mass size distributions could be identified. The lower mode, associated with sea-salt, was located between the surface-area and volume distribution of sodium peaking at about 2–3 m of EAD. The upper mode peaked at 3–5 m and followed more closely the surface-area distribution of calcium in all samples. At our site, the accumulation of nitrate into both particle types was shown to be limited by an effective surface reaction rate rather than by gas-phase diffusion. This rate was estimated to be considerably larger for sea-salt particles. Strong evidence in support of the saturation of nitrate in sea-salt particles were obtained.     

Complex image method for calculating electric and magnetic fields produced by an auroral electrojet of finite length

The electromagnetic field due to ionospheric currents has to be known when evaluating space weather effects at the earths surface. Forecasting methods of these effects, which include geomagnetically induced currents in technological systems, are being developed. Such applications are time-critical, so the calculation techniques of the electromagnetic field have to be fast but still accurate. The contribution of secondary sources induced within the earth leads to complicated integral formulas for the field at the earths surface with a time-consuming computation. An approximate method of calculation based on replacing the earth contribution by an image source having mathematically a complex location results in closed-form expressions and in a much faster computation. In this paper we extend the complex image method (CIM) to the case of a more realistic electrojet system consisting of a horizontal line current filament with vertical currents at its ends above a layered earth. To be able to utilize previous CIM results, we prove that the current system can be replaced by a purely horizontal current distribution which is equivalent regarding the total (= primary + induced) magnetic field and the total horizontal electric field at the earths surface. The latter result is new. Numerical calculations demonstrate that CIM is very accurate and several magnitudes faster than the exact conventional approach.     

What about managerial geography?

A business school perspective to Corporate Geography is offered. The mission is to provide an executive with operational tools for the creation of wealth. A search for the tools is better initiated with manufacturers and retailers. Individuality among corporations and markets makes deductive theories hazardous, a fact shown by examples from IKEA, Scania and Volvo Truck. Case studies, classified by a competitive situation, are seen as a more practicable alternative. From a large number of cases typical patterns can be derived. Anomalies indicate substandard or outstanding behavior. Their explanation contributes to the executive tool set. A unified approach of the currently scattered pieces is propagated.     

A sophisticated lander for scientific exploration of Mars: scientific objectives and implementation of the Mars-96 Small Station

A mission to Mars including two Small Stations, two Penetrators and an Orbiter was launched at Baikonur, Kazakhstan, on 16 November 1996. This was called the Mars-96 mission. The Small Stations were expected to land in September 1997 (Ls approximately 178 degrees), nominally to Amazonis-Arcadia region on locations (33 N, 169.4 W) and (37.6 N, 161.9 W). The fourth stage of the Mars-96 launcher malfunctioned and hence the mission was lost. However, the state of the art concept of the Small Station can be applied to future Martian lander missions. Also, from the manufacturing and performance point of view, the Mars-96 Small Station could be built as such at low cost, and be fairly easily accommodated on almost any forthcoming Martian mission. This is primarily due to the very simple interface between the Small Station and the spacecraft. The Small Station is a sophisticated piece of equipment. With the total available power of approximately 400 mW the Station successfully supports an ambitious scientific program. The Station accommodates a panoramic camera, an alpha-proton-x-ray spectrometer, a seismometer, a magnetometer, an oxidant instrument, equipment for meteorological observations, and sensors for atmospheric measurement during the descent phase, including images taken by a descent phase camera. The total mass of the Small Station with payload on the Martian surface, including the airbags, is only 32 kg. Lander observations on the surface of Mars combined with data from Orbiter instruments will shed light on the contemporary Mars and its evolution. As in the Mars-96 mission, specific science goals could be exploration of the interior and surface of Mars, investigation of the structure and dynamics of the atmosphere, the role of water and other materials containing volatiles and in situ studies of the atmospheric boundary layer processes. To achieve the scientific goals of the mission the lander should carry a versatile set of instruments. The Small Station accommodates devices for atmospheric measurements, geophysical and geochemical studies of the Martian surface and interior, and cameras for descent phase and panoramic views. These instruments would be able to contribute remarkably to the process of solving some of the scientific puzzles of Mars.     

Correction of tree ring stable carbon isotope chronologies for changes in the carbon dioxide content of the atmosphere

Tree-ring stable carbon isotope ratios (δ¹³C) often display a decline over the industrial period (post-AD1850) that is only partly explained by changes in the isotopic ratio of carbon dioxide (CO₂) and may represent a response to increased atmospheric concentrations of CO₂ (ca). If this is not addressed, reconstructions using long tree-ring stable isotope chronologies calibrated using the modern period, for which meteorological records are available, may be compromised. We propose a correction procedure that attempts to calculate the δ¹³C values that would have been obtained under pre-industrial conditions. The correction procedure uses nonlinear (loess) regression but the magnitude of the adjustment made is restricted by two logical constraints based on the physiological response of trees: first, that a unit increase in ca cannot result in more than the same unit increase in the internal concentration of CO₂ (ci), and second, that increases in water-use efficiency as a result of an increase in ca are limited to maintaining a constant ci/ca ratio. The first constraint allows retention of a falling trend in δ¹³C, which exceeds that which could logically be attributed to a passive response to rising ca. The second constraint ensures that any increase in δ¹³C, reflecting a change in water-use efficiency beyond maintenance of a constant ci/ca, is not removed. The procedure is tested using ‘pseudoproxies’, to demonstrate the effect of the correction on time-series with different shapes, and data from three sites in Finland and Norway. Two of the time-series retain a significant trend after correction, and in all three cases the correction improves the correlation with local meteorological measurements.     

Changes in Nutrient and Carbon Availability and Temperature as Factors Controlling Bacterial Growth in the Northern Baltic Sea

The effects of inorganic nutrient (N and P) and glucose C treatments on bacterial growth were followed for 3 days in natural surface and deep water bacterial samples during the main post-spring bloom stages of phytoplankton growth in the northern Baltic Sea. In addition, the importance of photochemical degradation of dissolved organic matter on bacterial growth was investigated vertically (0.1–2.0 m) and spatially, in a salinity gradient from river mouth to open sea. Bacterial production was consistently C limited in the surface layer, with N or both N and P as the secondary limiting nutrients from spring to early summer and in late summer, respectively. In deep water, bacterial growth showed combined temperature and C limitation, and in spring, this also appeared to be true with surface samples. The effect of 1-day sunlight pre-treatment varied from no effect up to a 44% production increase, with clear bacterial production responses only being seen at the surface (10 cm depth). The implications of bacterial C limitation for the structure and function of the surface plankton ecosystem, including its CO₂ exchange with the atmosphere are discussed.     

A consideration of some hidden hydromorphic effects on the fines of glacial tills in the Kuhmo-Suomussalmi area, eastern Finland

The silt and clay-size (minus 0.063 mm) fractions of 766 samples of glacial tills from the Kuhmo-Suomussalmi area in eastern Finland were analyzed for 8 trace and minor elements (Co, Cr, Cu, Mn, Ni, Pb, Zn, Fe) by AAS after hot 7 mol/I HNO, dissolution treatment. The results were treated statistically. Threshold values were calculated separately for those tills overlying gneissic basement on the one hand and greenstone belt on the other. The results show that the overall element levels for the metals in the area are lower than elsewhere in Finland by a factor which varies between 1 and 46. The reason for the differences may be the absence of preglacial weathering material in the till fines which elsewhere enhance element levels. Marked differences in the element levels over each bedrock subunit show up in the overlying tills. Correlation, regression and factor analyses show that the elements have high mutual correlations suggestive of hydromorphic alteration, even though the macroscopically hydromorphic samples were omitted from the statistical analyses. The effect is weak, however, and does not suppress the primary correlation, which results in the emergence of two factors in factor analysis of the geochemical data of the greenstone belt tills, the Co-Cr-Cu-Mn-Ni-Fe and Pb-Zn factors, the latter corresponding to one of the two known types of mineralization encountered in the underlying bedrock.     

Magnetic and Electric Fields Produced in the Sea During Geomagnetic Disturbances

— To understand geomagnetic effects on systems with long conductors it is necessary to know the electric field those systems experience. For surface conductors such as power systems and pipelines this can easily be calculated from the magnetic field variations at the surface using the surface impedance of the earth. However, for calculating the electric fields in pipelines and submarine cables at the seafloor it is necessary to take account of the attenuating effect of the conducting seawater. Assuming that the fields are vertically propagating plane waves, we derive the transfer functions between the electric and magnetic fields at the seafloor and the magnetic field variations at the sea surface. These transfer functions are then used, with surface magnetic field data, to determine the power spectra of the seafloor magnetic and electric fields in a shallow sea (depth 100 m) and in the deep ocean (depth 5 km) for different values of the Kp magnetic activity index. For the period range considered (2 min to 3 hrs) the spectral characteristics of the seafloor magnetic and electric fields for a 100 m deep sea are very similar to those of the surface fields. For the deep ocean the seafloor spectra show a faster decrease in spectral density with increasing frequency compared to the surface fields. The results obtained are shown to be consistent with seafloor observations. Assessment of the seafloor electric fields produced by different levels of geomagnetic activity can be useful in the design of the power feed equipment for submarine cables and cathodic protection for undersea pipelines.