Drained triaxial testing of shales: insight from the Opalinus Clay

Acta Geotechnica - The investigation of the mechanical behaviour of swelling claystones and shales is challenging because of their very low permeability and of their high sensitivity to changes in...     

Combining AHP and genetic algorithms approaches to modify DRASTIC model to assess groundwater vulnerability: a case study from Jianghan Plain,China

Accurate identification of vulnerability areas is critical for groundwater resources protection and management. The present study employed the modified DRASTIC model to assess the groundwater vulnerability of Jianghan Plain, a major farming area in central China. DRASTICL model was developed by incorporating the land use factor to the original model. The ratings and weightings of the selected parameters were optimized by analytic hierarchy process (AHP) method and genetic algorithms (GAs) method, respectively. A combined AHP–GAs method was proposed to further develop this methodology. The unity-based normalization process was employed to categorize the vulnerability maps into four types, such as very high (>0.75), high (0.5–0.75), low (0.25–0.5), and very low (<0.25). The accuracy of vulnerability mapping was validated by Pearson’s correlation coefficient between vulnerability index and the nitrate concentration in groundwater and analysis of variance F statistic. The results revealed that the modified DRASTIC model had a large improvement over the conventional model. The correlation coefficient increased significantly from 41.07 to 75.31% after modification. Sensitivity analysis indicated that the depth to groundwater with 39.28% of mean effective weight was the most critical factor affecting the groundwater vulnerability. The developed vulnerability model proposed in this study could provide important objective information for groundwater and environmental management at local level and innovation for international researchers.     

Assessment of regional karstification degree and groundwater sensitivity to pollution using hydrograph analysis in the Velka Fatra Mountains, Slovakia

Hydrograph analyses of groundwater depletion process in the spring were used for estimation of karstification degree and groundwater sensitivity to pollution in the whole catchment area. Differences of individual depletion hydrographs enable assessment of the anticipated extent of absorption, attenuation and self-purification processes during the groundwater penetration through the rock environment between its infiltration and its outflow in the spring. The method was applied in the SW part of the Velka Fatra Mountains (Slovakia) “Tlsta” hydrogeological structure. In total, 209 individual recession curves from 20 gauged springs were analyzed. Depending on characteristic groundwater depletion hydrographs with independent sub-regimes, categories of groundwater sensitivity to pollution were defined. Finally, resulting sensitivities to pollution were linked to lithostratigraphical units in the area.     

Retrieving of Land Surface Temperature Using Thermal Remote Sensing and GIS Techniques in Kandaihimmat Watershed,Hoshangabad, Madhya Pradesh

Remotely sensed thermal infrared (TIR) data have been widely used to retrieve land surface temperature (LST). LST is an important parameter in the studies of urban thermal environment and dynamics. In the study, an attempt has been made using LANDSAT 8 thermal imagery to compute LST and the associated land cover parameters viz; land surface emissivity (LSE), normalized difference vegetation index (NDVI), normalized difference built-up index (NDBI) and normalized difference water index (NDWI). Landsat 8 TIRS band 10 & 11 (thermal bands) during 21 Oct. 2016, 22 Nov.2016, 24 Dec. 2016 and 09 Jan. 2017 were processed for LST analysis. However, band 5 & band 4 of the imagery was processed for NDVI, band 6 & band 5 for NDBI and band 2 & band 5 for NDWI analysis. LST has been derived from both the bands 10 &11 and validated by in-situ observations on the date and time of satellite overpass from the study area. Band 10 derived LST have shown much temperature difference while comparing with the in-situ observations. However, LST derived from band 11 found similar & close to the in-situ measurements. Relationship between band 11 results and in-situ observed measurements were developed, which has showing a strong correlation with (r² = 0.991). Land surface emissivity were also evaluated which shows variation in different land cover surfaces like vegetation, settlement, forest cover and water body. The study has proven that land surface temperature derived from satellite band 11 is the actual surface temperature of the study area.     

Biogeochemical evaluation of Nannorrhops ritchiana： A Mg-flora from Khuzdar, Balochistan, Pakistan

Nannorrhops ritchiana （ Mazari Palm） is a distinctive flora growing in the Saharo-Sindian region. It is well distributed on the ultramafic soil, derived from the Bela Ophiolite in the Khuzdar District, Balochistan, Pakistan. Quantitative estimation of Ca, Mg, Fe and Ni in soil and plant ash has been carried out. The constituents of plant ash have been discussed in relation to soil chemistry, pH, climate, mobility, average abundance in plant ash and exclusion mechanism of the flora. Relationship among Ca, Mg, Fe and Ni has been established using scattergrams to evaluate the biogeochemistry of the plant. High contents of Mg and high coefficient of biological absorption allow it to be classed as Mg-flora. Both Ca and Fe appeared to be antagonistic to Mg. The metal assemblage of N. ritchiana nicely reflected the nature of the bed rock as being serpentinized ultramafic, and its corresponding soils. Good exclusion mechanism of N. ritchiana did not allow it to absorb high Ni from the soil. Relatively high concentrations of Ni in N. ritchiana from the Baran Lak area can be used to localize Ni-mineralization in the study area. Statistical analyses, such as minimum, maximum, mean, mode, median, standard deviations, and coefficient of correlation, were also made to improve raw geochemical data and interpretations.     

Biogeochemical evaluation of Nannorrhops ritchiana : A Mg-flora from Khuzdar, Balochistan, Pakistan

Nannorrhops ritchiana (Mazari Palm) is a distinctive flora growing in the Saharo-Sindian region. It is well distributed on the ultramafic soil, derived from the Bela Ophiolite in the Khuzdar District, Balochistan, Pakistan. Quantitative estimation of Ca, Mg, Fe and Ni in soil and plant ash has been carried out. The constituents of plant ash have been discussed in relation to soil chemistry, pH, climate, mobility, average abundance in plant ash and exclusion mechanism of the flora. Relationship among Ca, Mg, Fe and Ni has been established using scattergrams to evaluate the biogeochemistry of the plant. High contents of Mg and high coefficient of biological absorption allow it to be classed as Mg-flora. Both Ca and Fe appeared to be antagonistic to Mg. The metal assemblage ofN. ritchiana nicely reflected the nature of the bed rock as being serpentinized ultramafic, and its corresponding soils. Good exclusion mechanism ofN. ritchiana did not allow it to absorb high Ni from the soil. Relatively high concentrations of Ni inN. ritchiana from the Baran Lak area can be used to localize Ni-mineralization in the study area. Statistical analyses, such as minimum, maximum, mean, mode, median, standard deviations, and coefficient of correlation, were also made to improve raw geochemical data and interpretations.     

Effect of trace metals on halophilic and mixed cultures in anaerobic treatment

Trace metals are known to stimulate the activity of anaerobic methanogenic bacteria involved in the degradation of organic matter. The objective of this research was to investigate the effect of three trace metals, iron, nickel and cobalt on the activity of halophilic methanogens, digester sludge and a mixed culture of halophilic bacteria and digester sludge, at various salt concentrations. Iron slightly stimulated both initial and maximum specific methanogenic activity (SMA) of halophilic methanogens at all salt concentrations. Iron addition was also able to increase both initial and maximum SMA of the mixed culture. Iron could not stimulate either initial or maximum SMA of digester sludge at salt concentrations of more than 10 g/L. Adding cobalt showed no benefit on the initial and maximum SMA of halophilic methanogens. A slight increase in the initial SMA was observed in mixed culture when cobalt was injected to the system containing sodium concentrations of 10–30 g/L. At salt concentrations above 40 g/L, cobalt could stimulate the maximum SMA of mixed culture. No benefits were found when cobalt was added to the digester sludge at sodium concentrations higher than 20 g/L. Nickel was observed to increase the initial SMA of digester sludge at all salt concentrations, and the maximum SMA of mixed culture at salt concentrations of 30–50 g/L.     

The use of heavy metal concentrations and dendrochronology in the reconstruction of sediment accumulation, Ma a Panew River Valley, southern Poland

Heavy metal concentrations were investigated in overbank sediments of the Mala Panew River, southern Poland. Samples were collected from seven vertical profiles located within channel infills of a 20th century floodplain at three sites, each up to 50 m wide. In each profile, 15–24 samples were collected and analysed for Ba, Cd, Cu, Pb, and Zn. Sequential extraction of these elements was carried out in the 0.063-mm fraction of selected samples. Additionally, the age of the oldest trees growing close to the profiles has been used to estimate the initiation of sediment accumulation there. Ba, Cu, and Pb, which occur mostly in less mobile, moderately reducible, and residual fractions, were used for sediment dating. Zn and Cd, which in 50–75% occur in the mobile exchangeable fraction, were not suitable for dating. Correlation of Ba, Cu, and Pb concentrations in vertical profiles with changes in the load of effluents discharged to the river showed abrupt changes in the thickness of the strongly polluted sediments across the floodplains. A comparison of the relative changes between heavy metal peaks in sediments of similar age in the different profiles suggests a variable rate of downward metal migration. In general, none of the heavy metals investigated seems to have been mobilised within the stratigraphic layers above the water table. In layers located at stratigraphically lower levels, the Zn and Cd peaks seem to migrate several centimetres to several decimetres down in the profile. In profiles inundated for several weeks every year, Zn and Cd, as well as the relatively less mobile Ba, Cu, and Pb, have migrated downward by several decimetres. The investigation shows that frequent fluctuations of the water table have blurred the original depositional metal patterns of metal concentrations within a period of less than 40 years.     

A Comprehensive Review on Microalgae-Based Biorefinery as Two-Way Source of Wastewater Treatment and Bioresource Recovery

In the past few years, microalgae have gained huge recognition from the scientific community due to their potential applications in the production of a broad array of bio-based products varying from biofuels to nanoparticles. Due to their elevated growth rate, high tolerance to various types of abiotic stresses, and complex metabolic capacity, microalgae can be used as promising tools for the attainment of a circular bioeconomy. Moreover, they can simply utilize nutrients from wastewater for biorefinery purposes, resulting in resource recovery coupled with wastewater treatment. However, due to their sub-optimal yields and high production costs, microalgae-based bio-products have not yet been commercialized. This review provides insights into the employment of microalgae as an efficient bioresource for the treatment of wastewater with simultaneous enactment as a biorefinery to produce biofuels, biochar, bioplastic, fertilizers, and other high-value bioproducts. Furthermore, the application of microalgal nanoparticles in wastewater treatment and prospects for genetic modification of microalgae for enhanced biorefinery capabilities have also been briefly highlighted.     

REE geochemistry of core sediments of Cauvery delta,India for provenance studies

Acta Geochimica - The rare earth element (REE) geochemical composition of sediments from two cores were used to investigate the provenances of the Late Pleistocene to Holocene sediments of Cauvery...