Petrogenesis of lavas from the AMAR Valley and Narrowgate region of the FAMOUS Valley, 36°–37°N on the Mid-Atlantic Ridge

Basaltic lavas from the AMAR Valley and the Narrowgate region of the FAMOUS Valley on the Mid-Atlantic Ridge (36° to 37°?N) range in texture from aphyric to highly plagioclase phyric (>25% large plagioclase phenocrysts). Based on ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios, most of these lavas can be subdivided into two distinct, isotopically homogeneous, groups: Group I has lower ⁸⁷Sr/⁸⁶Sr (0.70288±1) and higher ¹⁴³Nd/¹⁴⁴Nd (0.51312±1) ratios; Group II has higher ⁸⁷Sr/⁸⁶Sr (0.70296±1) and lower ¹⁴³Nd/¹⁴⁴Nd (0.51309±2) ratios. Most Group II lavas are aphyric, whereas Group I lavas are primarily plagioclase phyric. Lavas from both groups show a wide range in incompatible element abundance ratios (e.g., Zr/Nb =6–29; (La/Sm)_n=0.6–1.7). Aphyric lavas have relatively constant Sc (40±1.5?ppm) abundances and CaO/Al₂O₃ ratios (0.80±0.02). Group I lavas are confined primarily to the AMAR rift valley floor whereas Group II lavas are found along the east and west marginal highs. We interpret the isotopic differences between the two groups as reflecting a temporal change in the upwelling mantle beneath this region of the Mid-Atlantic Ridge which is south of the Azore Islands. For each group, a petrogenetic model consistent with the geochemical data is multi-stage decompression melting of an initially enriched, homogeneous, mantle source region. If the early derived, incompatible-element enriched, melt increments are not always pooled with subsequent increments, the erupted magma batches may have the major element characteristics of melts derived by 10 to 20% melting, but with incompatible element abundance ratios reflecting the change from an enriched to depleted source during the incremental melting process. In this process an initially homogeneous source can generate primary magmas with the required range in incompatible element abundance ratios shown by each group. The nearly constant CaO/Al₂O₃ ratios and Sc contents of the aphyric lavas with decreasing Mg?? reflects subsequent polybaric fractionation of clinopyroxene, plagioclase and olivine over the pressure interval 8–6?kbar (24–18?km), followed by rapid transport to the surface and eruption. There is no geochemical evidence for a crustal magma chamber beneath this section of the Mid-Atlantic Ridge.     

In situ sampling reveals rapid uptake and depuration of polycyclic aromatic hydrocarbons by surf clams (Paphies subtriangulata) affected by the Rena oil spill

ABSTRACT

To investigate the uptake and depuration of polycyclic aromatic hydrocarbons associated with the Rena oil spill we sampled the surf clam Paphies subtriangulata at two open coast locations (6?km apart) just prior to oil coming ashore (7 October 2011), then at 1–3 week intervals for the next 4 months. Total polycyclic aromatic hydrocarbons (tPAH) increased at both sites from 1 to 96–124?µg?kg^?1 (wet weight) by 18 October before declining to low levels (<4?µg?kg^?1) by February 2012. Ongoing sampling throughout 2012–2014 included three additional sites to the north east (up to 30?km away) and a site 5?km to the south east revealing tPAH levels generally <10?µg?kg^?1 except in October 2013 where levels ranged between 39–45?µg?kg^?1 at all sites. A comparison of PAH component profiles with oil-contaminated beach sediment indicated that the high levels observed in surf clams between October–December 2011 were clearly associated with the Rena spill. However, the October 2013 peak had a PAH profile inconsistent with weathered Rena oil, suggesting an alternative source of contamination. Our results highlight the potential for P. subtriangulata as a PAH monitoring tool but recognise more study is needed to better quantify baseline levels and uptake and depuration dynamics.     

Back to the future: reflections and directions of South African marine bioinvasion research

Biological invasions continue to increase around the world, with impacts on many coastal marine systems. Here we review the South African marine invasion literature which, despite the field being relatively new, has grown to have significant presence in both the local and international arenas. Of the 79 papers reviewed, 70% focused on the establishment and spread of alien species, with modes of transport and introduction largely overlooked. An emphasis was also apparent towards field studies, in particular survey work, with few experimental studies. The overwhelming majority of papers focused on a single species, the Mediterranean mussel Mytilus galloprovincialis, reflecting the scale of this invasion and the tractable nature of rocky shores as study systems. With the exception of this one species, the impacts of marine alien species have rarely been quantified. We suggest that future research extends the taxonomic coverage of present work and develops a better understanding of the mechanisms of introduction, establishment and spread of marine alien species. Through an experimental approach, the drivers of altered ecological patterns and processes resulting from invasions should be addressed, providing insight into associated impacts. This approach will maintain the local applicability and international relevance of South African marine invasion research.     

The quaternary glacial history of the Lahul Himalaya,northern India

This paper presents the first glacial chronology for the Lahul Himalaya, Northern India. The oldest glaciation, the Chandra Glacial Stage, is represented by glacially eroded benches at altitudes greater than 4300 m above sea-level. This glaciation was probably of a broad valley type. The second glaciation, the Batal Glacial Stage, is represented by highly weathered and dissected lateral moraines, which are present along the Chandra valley and some of its tributaries. This was an extensive valley glaciation. The third major glaciation, the Kulti Glacial Stage, is represented by well-preserved moraines in the main tributary valleys of the Chandra valley. This represents a less extensive valley glaciation. Two minor glacial advances, the Sonapani I and II, are represented by small sharp-crested moraines, which are within a few hundred metres or few kilometres of the present-day glaciers. The change in style and extent of glaciation is attributed to an increase in aridity throughout the Quaternary, due either to global climatic change or uplift of the Pir Panjal mountains to the south of Lahul, which restricted the northward penetration of the south Asian summer monsoon. © 1996 John Wiley & Sons, Ltd.     

Difficulties in separating hurricane induced effects from natural benthic succession: Hurricane Isabel,a case study from Eastern Virginia,USA

Hurricane Isabel reached the Eastern seaboard of North America on 18 September 2003 causing estimated damage >3 billion US dollars and the death of ∼50 people. Isabel is considered to be one of the most significant tropical cyclones to affect Virginia, since the Chesapeake Potomac Hurricane of 1933 and Hurricane Hazel in 1954. A study of the temporal changes in the benthic fauna pre- and post-hurricane was conducted on an intertidal sandflat within the dynamic barrier island system near Wachapreague, Eastern Virginia. Replicate sediment cores were collected 3 weeks before Isabel made landfall and further samples were collected on 5 occasions over the following 20 months. An immediate effect of Isabel was a doubling in the number of species, a significant increase in invertebrate species diversity (H′) and a rise in opportunistic species and deposit feeders, but a non-significant increase in the total number of organisms. Changes in infauna occurred such that by the end of the study there were significantly increased numbers of species, faunal abundances and community diversity measures, as compared with pre-hurricane samples, suggesting a potentially positive medium-term effect of this hurricane perturbation. The most notable direct effects of the hurricane were on the relative abundances of feeding guilds with a reduction in interface feeders from 87% pre-hurricane to 64% post-hurricane, and an increase in surface deposit feeders from 7% pre-hurricane to 20% post-hurricane. The study highlights potential problems in interpreting post-perturbation data when insufficient pre-perturbation data exist.     

The mid-depth circulation of the northwestern tropical Atlantic observed by floats

A comprehensive analysis of velocity data from subsurface floats in the northwestern tropical Atlantic at two depth layers is presented: one representing the Antarctic Intermediate Water (AAIW, pressure range 600–1050 dbar), the other the upper North Atlantic Deep Water (uNADW, pressure range 1200–2050 dbar). New data from three independent research programs are combined with previously available data to achieve blanket coverage in space for the AAIW layer, while coverage in the uNADW remains more intermittent. Results from the AAIW mainly confirm previous studies on the mean flow, namely the equatorial zonal and the boundary currents, but clarify details on pathways, mostly by virtue of the spatial data coverage that sets float observations apart from e.g. shipborne or mooring observations. Mean transports in each of five zonal equatorial current bands is found to be between 2.7 and 4.5 Sv. Pathways carrying AAIW northward beyond the North Brazil Undercurrent are clearly visible in the mean velocity field, in particular a northward transport of 3.7 Sv across 16°N between the Antilles islands and the Mid-Atlantic Ridge. New maps of Lagrangian eddy kinetic energy and integral time scales are presented to quantify mesoscale activity. For the uNADW, mean flow and mesoscale properties are discussed as data availability allows. Trajectories in the uNADW east of the Lesser Antilles reveal interactions between the Deep Western Boundary Current (DWBC) and the basin interior, which can explain recent hydrographic observations of changes in composition of DWBC water along its southward flow.     

Mixed terrigenous—Carbonate sedimentation in the Hispaniola—Caicos turbidite basin

Sedimentation in the 9500 km², 4100 m deep Hispaniòla—Caicos Basin is dominated by turbidity currents. Carbonate turbidites originate from the Bahama Islands, Great Inagua and Caicos at the north end of the basin. Mixed carbonate—non-carbonate flows come from Hispaniola and perhaps Cuba. Most flows originate on insular slopes rather than in shallow water. The relatively low CaCO₃ content of hemipelagic sequences throughout the entire basin reveals that the influence of non-carbonate Hispaniola—Cuba sources is widespread.The basin was sampled with closely spaced piston cores. Sand-layer isopach and frequency maps reveal four or five major basin entry points for turbidity currents. Flow size is proportional to the size of source areas. Average volumes of flows originating from Hispaniola—Cuba, the largest source, are 10⁹ m³. This compares to an average flow volume of 10⁶ m³ for flows derived from the smallest source area, the Southeastern Caicos Bank. Measures of turbidity-current activity, such as thickness and frequency, change in a regular fashion away from each entry point. Average lutite thickness (combining hemipelagic and turbiditic lutite) are greatest near the basin entry points. On the abyssal plain occupying the south half of the basin, Bouma turbidite sedimentary structure sequences tend to be complete. However, on the Caicos Fan, the sedimentary structure sequences in turbidites are characterized by missing or repeated units. Six radiocarbon dates of two widespread presumed pelagic units in the basin yielded younger dates in stratigraphically older positions. The reversed dates are assumed to reflect storm erosion of older sediment on adjacent insular shelves.Consideration of a north—south reflection seismic profile over the basin indicates that the present sediment regimen has pertained through much of the Neogene. The coherence, convergence and termination of reflections in the seismic section are consistent with and tend to confirm conclusions based on the core study regarding the greater extent and volume of sediment deposits derived from the Hispaniola source area.     

A nonlinear stability analysis of convection in a generalized incompressible fluid

Abstract

We establish a nonlinear stability result for convection in a generalized incompressible fluid. Both numerical calculations and an asymptotic analysis are carried out. The linear and nonlinear results are shown to be very close in both cases, implying that the region of possible subcritical instabilities is very small.

During this work I was supported by a research studentship awarded by the Science and Engineering Council of the United Kingdom.     

Bioconcentration factors for petroleum hydrocarbons, PAHs, LABs and biogenic hydrocarbons in the blue mussel

Bioconcentration factors (K_bc) for petroleum hydrocarbons, PAHs, LABs and biogenic hydrocarbons in Mytilus edulis were measured in field experiments using time-integrating water samplers. Seven deployments at five sites gave lipid weight K_bcs for total hydrocarbons ranging from 0.99 × 10⁶ to 3.1 × 10⁶ (mean 1.6 × 10⁶)—a narrower range than has been obtained previously. Bioconcentration factors for the PAHs were similar to those for total hydrocarbons where the major hydrocarbon source was oil. However, at other sites the factors for PAHs were an order of magnitude lower than those for petroleum and for hydrocarbons originating from algae. Compositional profiles for the linear alkyl benzenes (LABs) suggested that these compounds were assimilated primarily from the dissolved phase, despite their greater abundance on particles.