Stellar polarization and the structure of the magnetic field of our galaxy

The stellar polarization data have been examined using a new catalogue containing accurate stellar distances. On the assumption of a magnetic alignment hypothesis, correlations on the larger distance scale indicate the existence of a dominant regular magnetic field, although its characteristics are difficult to determine. Within 500 pc its direction is towardsl45° and beyond this towardsl60°, though it is clear that such a longitudinal model is too simple. There is also some evidence for an inclination of this field to the galactic plane. The distribution of the polarization vectors away from the galactic plane has been examined and it is proposed that the two largest loop structures, previously identified as Supernova remnants, are linked by the regular field. Incremental polarization maps have been produced but they show little correlation with the spiral structure. The polarization appears to be saturated at about 1 kpc from the Sun, which is explained as the result of an observational selection effect. On the smaller distance scales an autocorrelation analysis in different directions has revealed no obvious coherence in the irregular component on scales greater than 50 pc.     

Comparison of crude oils and their alteration products

A simple method is proposed for using gas Chromatographic data on the high molecular weight saturated fractions of crude oils to make comparisons of source materials, migration mechanisms and, in particular, alteration processes within reservoirs. The preferential loss of normal alkanes by bacterial attack on a light crude is one of several processes readily followed using this scheme.     

Formation of the Bencubbin polymict meteoritic breccia

The Bencubbin meteorite is a polymict breccia consisting of a host fraction of ~60% metal and ~40% ferromagnesian silicates and a selection of carbonaceous, ordinary and ‘enstatite’ chondritic clasts. Concentrations of 27 elements were determined by neutron activation in replicate samples of the host silicates and the ordinary and carbonaceous chondritic clasts; 12 elements were determined in the host metal. Compositional data for the ordinary chondrite clast indicate a classification of LL4 ± 1. Refractory element data for the carbonaceous chondrite clast indicate that it belongs to the CI-CM-CO clan; its volatile element abundances are intermediate between those of CM and CO chondrites. Abundances of nonvolatile elements in the silicate host are similar to those in the carbonaceous chondrite clast and in CM chondrites; the rare earths are unfractionated. We conclude that it is not achondritic as previously designated, but chondritic and that it is probably related to the CI-CM-CO clan; its volatile abundances are lower than those in CO chondrites. Oxygen isotope data are consistent with these classifications. Host metal in Bencubbin and in the closely related Weatherford meteorite has low abundances of moderately volatile siderophiles; among iron meteorite groups its nearest relative is group IIIF.We suggest that Bencubbin and Weatherford formed as a result of an impact event on a carbonaceous chondrite regolith. The impact generated an ‘instant magma’ that trapped and surrounded regolithic clasts to form the polymict breccia. The parent of this ‘magma’ was probably the regolith itself, perhaps mainly consisting of the so-called ‘enstatite’ chondrite materials. Accretion of such a variety of materials to a small parent body was probably only possible in the asteroid belt.     

The chemistry of orthophosphate uptake from seawater on to calcite and aragonite

The chemistry of orthophosphate uptake from synthetic seawater onto the surfaces of synthetic calcite, aragonite and low-magnesium biogenic calcite has been studied, in order to elucidate the kinetics of the process (generally believed to be the major control of dissolved reactive phosphate in carbonate-rich marine sediments). Our results differ from those obtained by others, who have studied orthophosphate uptake in low ionic strength solutions and at much higher supersaturations relative to apatite.In both ‘free drift’ and chemostat experiments, Mg and F have only a minor effect on the reaction rate. Even at constant solution composition the rate of orthophosphate uptake was found to decrease by 10⁶ over a two week period. The data from the ‘free drift’ experiments can be fitted to the Elovich equation. This indicates that the kinetics observed for this reaction can be explained by an exponential decrease in available surface reaction sites and/or a linear increase in the activation energy associated with chemisorption as the reaction proceeds.     

Amino acid composition of organic matter associated with carbonate and non-carbonate sediments

Amino acids comprise from 15 to 36% by weight of humic substances from carbonate and non-carbonate sediments. Humic and fulvic acids extracted from carbonate sediments are characterized by an amino acid composition consisting primarily of the acidic amino acids, aspartic and glutamic acid. Humic substances from non-carbonate sediments have a distinctly different amino acid composition consisting primarily of glycine and alanine. Amino acid analyses of various molecular weight fractions of fulvic acids extracted from carbonates show that lower molecular weight fractions have appreciably higher relative abundances of the acidic amino acids compared to higher molecular weight fractions. Based on typical values for carboxyl group content in humic substances, acidic amino acids may be a significant contributor of these functional groups. Carbonate surfaces appear to selectively adsorb aspartic acid-enriched organic matter while non-carbonates do not have this property.     

The formation and clay mineral reactions of melanoidins

Sugars and amino acids condense readily to form polymers known as melanoidins that closely resemble natural humic substances. In this study melanoidins are formed by reacting glucose with each of three amino acids: glutamic acid, valine and lysine. The basic amino acid, lysine, reacts with glucose at a much greater rate than either of the other two compounds. The chemical properties of the melanoidins are strongly influenced by the amino acid from which they are formed. The nitrogen contents, acidities and electrophoretic behavior of the polymers all reflect functional group distributions inherited from the amino acids. These chemical differences strongly influence the extent of association of the melanoidins with kaolinite and montmorillonite clay minerals. Laboratory simulations suggest that melanoidin formation may be favored in marine environments where basic amino acids should preferentially condense with sugars to form nitrogen-rich polymers that have a great affinity for clay mineral surfaces.     

Absolute spectrophotomery of comets 1973XII and 1975IX: II. Profiles of the Swan bands

Absolute spectrophotometric measurements of the Swan bands of two comets have been compared with computed synthetic spectra using modern Franck-Condon and Hönl-London factors, and varying rotational, vibrational, and electronic excitation temperatures. Rotational and vibrational temperatures were obtained for the comets. Although the electronic excitation temperature and the molecular column density cannot be separated, a relationship is found between these two quantities. A review is made of recent determinations of column densities for CN in comets.     

Galilean satellites: 1976 radar results

Radar observations of the Galilean satellites, made in late 1976 using the 12.6-cm radar system of the Arecibo Observatory, have yielded mean geometric albedos of 0.04 ± , 0.69 ± 0.17, 0.37 ± 0.09, and 0.15 ± 0.04, for Io, Europa, Ganymede, and Callisto, respectively. The albedo for Io is about 40% smaller than that obtained approximately a year earlier, while the albedos for the outer three satellites average about 70% larger than the values previously reported for late 1975, raising the possibility of temporal variation. Very little dependence on orbital phase is noted; however, some regional scattering inhomogeneities are seen on the outer three satellites. For Europa, Ganymede, and Callisto, the ratios of the echo received in one mode of circular polarization to that received in the other were: 1.61 ± 0.20 1.48 ± 0.27, and 1.24 ± 0.19, respectively, with the dominant component having the same sence of circularity as that transmitted. This behavior has not previously been encountered in radar studies of solar system objects, whereas the corresponding observations with linear polarization are “normal.” Radii determined from the 1976 radar data for Europa and Ganymede are: 1530 ± 30 and 2670 ± 50 km, in fair agreement with the results from the 1975 radar observations and the best recent optical determinations. Doppler shifts of the radar echoes, useful for the improvement of the orbits of Jupiter and some of the Galilean satellites, are given for 12 nights in 1976 and 10 nights in 1975.